Association of subsurface radon changes in Alaska and the northeastern United States with earthquakes

Changes of radon concentration in the ground have been reported to correlate with seismic activity in many places over widely varying distances from the earthquake epicenters, sometimes over 100's and occasionally over 1000's of km depending on the magnitude M of the earthquakes. For proper use of such correlations in forecasting the location and size of impending earthquakes, it would be useful to establish a relation between M and the maximum distance x_M at which radon can be significantly altered by preseismic effects.We have monitored radon in the ground continuously at Blue Mountain Lake, NY starting Dec. 3. 1975 and at three locations in Alaska—Icy Bay, Yakataga, and Sand Point (starting Nov. 12, 1979; March 5, 1980; and June 29, 1980 respectively). Sample correlations from visual examination of the recent radon record and tentative use of a proposed scaling relation show a number of possible earthquake-related signals at these locations. The data are compatible with scaling relations that were derived from two separate models of premonitory elastic strains. In this work x_M = 10^0.48M, where x_M is in units of km and M ≥ 3. Since tilt and strain signals correlate similarly with magnitude and distance, it is likely that most earthquake-related radon signals are mechanically induced.     

Seismic Q for the lithosphere of the Montenegro region (Yugoslavia): frequency,depth and time windowing effects

The availability of accelerometric data for the Montenegro earthquake of 15th April 1979 makes it possible to investigate seismic Q of the lithosphere in that region, in particular, its dependence on frequency, on the depth reached by seismic waves, and on the length of time windows in which signals are processed. Two different spectral methods, S phase energy ratio and coda envelope decay, are applied, respectively, to direct and scattered shear waves. Similar results are obtained using different portions of the recordings, i.e., coda waves for the envelope decay fit and the S wave train, with a significant duration of ～ 10 s, for the energy ratios. The same apparent Q (Q ～ 40 f, where f is the frequency expressed in Hz) that is found for other neighbouring central Mediterranean regions (e.g., Ancona, on the central Italian Adriatic coast; Valnerina, in the central Apennines; Irpinia, in the southern Apennines) is also found for the southern Yugoslavian coast, in the band 1–25 Hz up to a maximum range of ～ 120 km from the focus. This strong frequency dependence is probably connected with the type of small-scale heterogeneity and the same geological age and level of tectonic activity peculiar to all these seismotectonic areas.In order to compare the apparent Q of the whole S wave train, ～ 10 s long, with the (intrinsic) apparent Q of the single direct S wave (usually 1 s or less), the maximum entropy method is applied in the energy spectrum computation for shorter wave trains. The use of shorter time windows does not reveal any significant variation in the tendency of Q to increase linearly with frequency as the length of the time window containing the sample of the S waves decreases. This seems to indicate that scattering-dependent Q is generally inseparable from intrinsic Q in the lithosphere when estimates based on variations with distance of the seismic signal spectrum are used. While the type of linear growth with frequency does not seem to undergo any variations (it remains of the Q = qf type), the data show there are a considerable decrease in the coefficient of proportionality Q with decreasing duration of the window of S waves analysed, probably as a result of variations in seismic attenuation with depth.     

Evolution of polycyclic alkanes in the Espirito Santo Basin

The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C₂₇ 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.     

Carbonate platform depositional sequences, Upper Cretaceous, south-central Pyrenees (Spain)

The Upper Cretaceous (Cenomanian-Maastrichtian) of the south-central Pyrenees shows five carbonate platform sequences where the major parameters are tectonism, relative sea-level fluctuations and inherited depositional profile. Depositional geometries and basin analysis permit an understanding of the depositional history.Five depositional sequences have been recognized: (1) The Santa Fe sequence (Middle-Upper Cenomanian), a ramp to a skeletal rimmed shelf with an escarpment bypass margin. The lower boundary is an angular unconformity and the upper one records a sea-level drop. The platform location of the margin was determined by a listric normal fault. (2) An abrupt sea-level rise drowned the former platform. The Congost sequence (Turonian-Lower Coniacian), a distally steepened ramp with erosional distal deep slope. The depositional model was largely controlled by pre-existing basin morphology. Cessation of platform development was due to a relative sea-level drop. (3) The Sant Corneli sequence (Upper Coniacian-Lower Santonian), a mixed terrigenous-skeletal homoclinal ramp with upright margin, deep slope and dysaerobic basin. The slope results from the backstepping by 24 km of the previous margin and gentle basin tilting. The platform margin remained more or less at the same position, and relief between platform and slope increased indicating continuous relative sea-level rise. The upper boundary is an angular unconformity at the platform margin produced by an abrupt sea-level rise and platform drowning, and by listric normal faulting. (4) The Vallcarga sequence (Upper Santonian-Campanian), a distal-steepened skeletal homoclinal ramp, erosional escarpment and turbidite basin, which corresponds to the Mesozoic maximum marine expansion. A listric normal fault created two depositional areas: a more or less flat footwall block with a north-northwest prograding carbonate ramp.     

On granitoid emplacement and related structures. A review

Granitoid magmas are emplaced at the upper crust under a complex interaction of gravitational processes and horizontal tectonics. Natural intrusive bodies show a wide variety of structural patterns that must be strongly related with their dynamic history of ascent and emplacement. Comparisons of natural structural patterns with experimental and numerical models are necessary to interpret in a coherent fashion the emplacement mechanism involved.From natural, experimental, numerical and theoretical considerations one can reach important conclusions on the problem of ascent and final emplacement of granitoid magmas in the Earth's crust. The present paper reviews the principal emplacement mechanisms referred to in the literature; that is, doming, diapirism, ballooning, stoping, cauldron subsidence and dike propagation.Dike propagation is the most effektive process in magma transport from deep zones in the crust and upper mantle. Extensional fractures for dike propagation and magma ascent can be developed at depth in the crust according to the modern dike propagation theory. In orogenic domains, magmas reach the upper crust through narrow channels or dikes and are accumulated in a final reservoir in the form of a discordant supracrustal pluton or a ballooning pluton if, during emplacement, any regional deformation acts simultaneously.

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Zusammenfassung Die Intrusion granitischer Magmen in die obere Krust ist das Ergebnis eines komplexen Zusammenspiels von schwerkraftbedingten Prozessen und horizontalen, tektonichen Bewegungen. Die gro\e Vielfalt tektonischer Strukturen von granitischen Plutonen spiegelt die Geschichte der Dynamik, ihres Aufstieges und ihrer Platznahme wider. Um den jeweils vorhandenen Intrusionsmechanismus zusammenhängend deuten zu können, sind Vergleiche der natürlichen, tektonischen Elemente mit experimentellen und numerischen Modellen notwendig. Hieraus lassen sich gegebenenfalls weitreichende Schlüsse zum Problem des Aufstiegs und der endgültigen Platznahme der Magmen in der Erkruste ziehen.In dieser Arbeit werden die wesentlichen Aufstiegsmechanismen von Magmen aus der Literatur diskutiert. Im Einzelnen sind dieses: Aufwölbung, Diapirismus, Aufweitung, Abbau, Kraterbildung und Gangentwicklung.Das Vordringen von Gängen ist der wirksamste Proze\ des Magmentransports aus tieferen Zonen der Kruste und des oberen Mantels. Ausdehnungsklüfte lassen sich als Ursache für das Vordringen von Gängen und den Magmenaufstieg nach der heutigen Theorie über die Entwicklung von Gängen in der tiefen Kruste herleiten. In orogenen Zonen erreichen Magmen die obere Erdkruste durch enge Kanäle oder Gänge und reichern sich dort auch in Form eines dikordanten, subkrustalen oder aufgweiteten Plutons an, wenn gleichzeitig mit der Platznahme regionaltektonische Deformationen ablaufen.

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Resumen Los magmas graníticos se emplazan en la corteza superior bajo una compleja interaccion entre procesos gravitatorios y tectónica horizontal. Los cuerpos intrusivos naturales muestran una amplia variedad de patrones estructurales que pueden estar directamente relacionados con la dinámica de ascenso y emplazamiento. Para explicar de forma cohérente el mecanismo de emplazamiento implicado en un plutón es necesario establecer comparaciones entre patrones estructurales de plutones y modelos experimentales y numéricos.A partir de consideraciones naturales, experimentales, numéricas y teóricas, se pueden extraer importantes conclusiones sobre el problema del ascenso y emplazamiento de magmas en la corteza. En este trabajo se revisan los principales mecanismos de emplazamiento referidos en la literatura; es decir, doming, diapirismo, ballooning, stoping, cauldron subsidence y propagación de diques.Propagación de diques es el proceso más efectivo en el transporte de magmas desde zonas profundas en la corteza y manto superior. De acuerdo con la moderna teoría de propagación de diques, las fracuras extensionales pueden producirse en profundidad en la corteza. En dominios orogénicos, los magmas alcanzan la corteza superior a través de estrechos canales o diques y se acumulan en un reservorio final, bien en forma de plutones discordantes supracrustales, o bien en la forma de un »ballooning pluton« si durante el emplazamiento actûa alguna deformación regional.

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Kinetics of reactions between aqueous sulfates and sulfides in hydrothermal systems

The rates of chemical reactions between aqueous sulfates and sulfides are essentially identical to sulfur isotopic exchange rates between them, because both the chemical and isotopic reactions involve simultaneous oxidation of sulfide-sulfur atoms and reduction of sulfate-sulfur. The rate of reaction can be expressed as a second order rate law: R = k·[∑SO₄^2?]·[∑S^2?], where R is the overall rate, k is the rate constant and [∑SO₄^2?] and [∑S^2?] are molal concentrations. We have computed the rate constants from the available experimental data on the partial exchange of sulfur isotopes between aqueous sulfates and sulfides using the rate law established by us: $\text{ln(}\text{α}{}^{\mathrm{e}}\text{? α}\text{α}{}^{\mathrm{e}}\text{? α}{}^0\text{) = ? kt([∑SO}{}_4{}^{\mathrm{2?}}\text{] + [∑S}{}^{\mathrm{2?}}\text{])}$, where t is time and α⁰, α, and α^e are, respectively, the fractionation factors at t = 0 (the initial condition), at the end of experiment, and at equilibrium. The equilibrium fractionation factor can be expressed as: $\text{1000 ln α}{}^{\mathrm{e}}\text{=}\text{6.463 × 10}{}^6\text{T}{}^2\text{+ 0.56 (±.5)}$ (T in Kelvin).The rate constants are strongly dependent on T and pH, but not in as simple a manner as suggested by Igumnov (1976). Our rate constants in Na-bearing hydrothermal solutions decrease by 1 order of magnitude with an increase in pH by 1 unit at pH's less than ~3, remain constant in the pH range of ~4 to ~7, and again decrease at pH >7. The activation energy for the reaction also depends on pH: 18.4 ± 1 kcal/mole at pH = 2, 29.6 ± 1 kcal/mole at pH = 4 to 7, and between 40 and 47 kcal/mole at pH around 9. The observed pH dependence of the rate constant and of the activation energy can be best explained by a model involving thiosulfate molecules as reaction intermediates, in which the intramolecular exchange of sulfur atoms in thiosulfates becomes the rate determining step.The rate constants obtained in this study were used to compute the changes in the isotopic fractionation factors between aqueous sulfates and sulfides during cooling of fluids. Comparisons with data of coexisting sulfate-sulfide minerals in hydrothermal deposits, suggest that simple cooling was not a likely mechanism for coprecipitation of sulfate and sulfide minerals at temperatures below 350°C. Mixing of sulfide-rich solutions with sulfate-rich solutions at or near the depositional sites is a more reasonable process for explaining the observed fractionation.The degree of attainment of chemical equilibrium between aqueous sulfates and sulfides in a hydrothermal system, and the applicability of a_O2-pH type diagrams to mineral deposits, depends on the ∑S content and the thermal history of the fluid, which in turn is controlled by the flow rate and the thermal gradient in the system.The rates of sulfate reduction by non-bacterial processes involving a variety of reductants are also dependent on T, pH, [∑SO₄^2?], and [∑S^2?], and appear to be fast enough to become geochemically important at temperatures above about 200°C.     

Frequency relationship for seismic Qβ of central southern Italy from accelerograms for the Irpinia earthquake (1980)

The frequency dependence of Q_β for seismic waves in a distance range with a maximum of 150 km from the epicentre of the Irpinia earthquake of November 23, 1980 has been sought using displacement spectral ratios computed from strong-motion accelerograms recorded in the region. The method has been applied to calculate the behaviour of Q_β as a function of frequency in the band 0.1–25 Hz, and to investigate whether azimuthal variations appear in seismic Q_β for the lithosphere in central southern Italy. The same result is obtained using data from stations in western south Italy as using data from eastern south Italy, namely,

$\text{Q}{}_{\mathrm{\beta }}\text{(f) = 40f (}\text{Hz}\text{)}$

The linear relationship suggest that apparent Q_β depends more on the scale of heterogeneity of the lithosphere, affecting reflection and scattering mechanisms, than on intrinsic energy losses related to the anelasticity of the materials through which the seismic waves propagate.The existence of a peak in Q_β^?1 has been investigated in the low-frequency band (0.1–2.5 Hz) using a higher resolution power. A stable result in this low-Q_β zone is not possible on the basis of the available data: only in six Q_β(f) profiles does an evident minimum exist, between 0.2 and 1 Hz, while in nine cases the curves are monotonically increasing from the lowest observable frequencies; a further nine cases appear of uncertain interpretation.     

Granulite-amphibolite facies metasediments from the Serre (Calabria,Southern Italy): their protoliths and the processes controlling their chemistry

In the northwestern Serre, a near continuous section through the Palaeozoic lower continental crust crops out. This paper deals with granulite facies metasedimentary rocks of this section. Fifty-five chemical analyses (major elements, Sc, V, Cr, Co, Ni, Rb, Sr, Y, Nb and Ba) are given. Chemical data indicate that the original sedimentary sequence was made up of arenites in the lower part and mainly Fe and Mg rich pelites in the upper part. The metapelites experienced anatexis and removal of some melt, whereas the meta-arenites suffered only incipient anatexis and became dehydration granulites. The various rock types display an overall relatively low K/Rb ratio due mainly to the stability of K- and Rb-retaining phases. A weighted mean composition of the fragment of the lower continental crust outcropping in the Serre has been established by integrating the chemical data for metasediments (55 analyses), metabasites (92 analyses) and dioritic and tonalitic gneisses (10 analyses) with the field data. This composition compared to the compositions of the bulk continental crust and of other sections considered as belonging to the lower crust, confirms the hypothesis that (1) the lower crust is heterogeneous, and (2) it is more basic than the continental crust.     

Morphology of the Itapeva to Tramandai transgressive dunefield barrier system and mid‐ to late Holocene sea level change

The surface morphology of the transgressive dunefield barrier extending from Itapeva to Tramandai along the northern littoral of Rio Grande do Sul, is examined and an attempt is presented to link morphological changes across the barrier to Holocene sea level changes. The 4·5 km wide Holocene barrier displays two typical morphologies: an inner part dominated by large‐scale, continuous alongshore, overlapping dunefield phases comprising sand sheets, dunes, deflation plains and precipitation ridges; and an outer part dominated by discontinuous, medium‐ to small‐scale, triangular to lobate transgressive dunefield phases, cut by both active and relict (palaeo‐) creeks or washouts. Holocene sea level in the region rose to c. +1 to +3 m above present reaching a maximum around 5100 years bp and then progressively fell to the present level. We argue that the effect on barrier development was to suppress the development of a drainage system during the rising and maximum stages, and encourage the development of an organized drainage system in the form of regularly spaced washouts during the falling period, and that this change in sea level from rising to falling therefore produced the large‐scale differences in barrier morphology. Copyright © 2006 John Wiley & Sons, Ltd.