The American oyster as a coastal zone pollution monitor: A pilot study

The Condition Index [(dry meat weight)(100)/(internal cavity volume)] has been analyzed and compared in the American oyster,Crassostrea virginica, from two South Carolina estuaries, one of which was considered polluted by coliform bacteria standards. During the warmer months, oysters from the unpolluted habitat showed a consistently and significantly higher Condition Index. Best fit and power function regressions of Condition Index on total coliform bacteria levels conform with previously cited effects of pollutants on oysters. Condition Index droped markedly as the incidence of total coliforms increased toward levels of 100 per 100 ml of water. Our results and the known sensitivity of oysters to a spectrum of pollutants suggest that their condition could be used to monitor waterborne pollution in coastal zone areas.     

Retention of riverine iron in estuaries

Retention of Fe flocs, resulting from the mixing of river water and seawater, was examined in three Maine estuaries. Riverine Fe was found to remain fairly conservative with salinity, implying that the process of floccufation does not necessarily remove Fe from water parcels. Laboratory experiments corroborated the field data by demonstrating that neither gravity nor suspended sediment were very effective in removing flocculated Fe from suspension. However, input of a tannery effluent did appear to result in scavenging of Fe from estuarine waters. Flocculated riverine Fe was found to increase considerably the Fe concentrations of estuarine bottom sediments, with the amount of iron per sediment specific surface area dependent on mean river flow entering an estuary. While no long term retention efficiencies could be calculated for these estuaries, it seems likely that a significant portion of flocculated riverine Fe escapes to shelf waters.     

High precision glacial–interglacial benthic foraminiferal Sr/Ca records from the eastern equatorial Atlantic Ocean and Caribbean Sea

Glacial–interglacial variation in the marine Sr/Ca ratio has important implications for coral Sr thermometry [J.W. Beck et al., Science 257 (1992) 644–647]. A possible variation of 1–3% was proposed based on ocean models [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118]. Subsequently, studies have used fossil foraminifera to test this prediction [P.A. Martin et al., Geochem. Geophys. Geosyst. 1 (1999); H.M. Stoll et al., Geochim. Cosmochim. Acta 63 (1999) 3535–3547; H. Elderfield et al., Geochem. Geophys. Geosyst. 1 (2000)]. But whether some component of foraminiferal Sr/Ca variation can be uniquely ascribed to seawater Sr variation is still not clear. To address this question, we developed cleaning and analysis techniques and measured Sr/Ca ratios on individual shells of the modern benthic foraminifer Cibicidoides wuellerstorfi. We showed that different size shells have different Sr/Ca ratios; however, samples with shell sizes of 355–500 μm appear to have normally distributed Sr/Ca ratios (1σ=1.8%). For multi-shell measurements (with estimated errors of 0.12–0.39%), the ratio varied by as much as 7.2±0.5% during the last glaciation for two Caribbean records at the same site and by 3.7±0.5% over the past 40,000 yr for one record from the Sierra Leone Rise in the eastern equatorial Atlantic. The two Caribbean records are very similar indicating that the behavior of shell Sr uptake was identical locally and that the shell Sr/Ca ratio faithfully reflects the local environment. The Atlantic record differs from the Caribbean records by as much as several percent. Thus, the foraminiferal Sr/Ca changes cannot be solely due to changes in seawater Sr/Ca unless the glacial deep ocean had spatial variation in Sr/Ca well in excess of the modern ocean. Certain similarities between the three records do exist. Notably, the rate of change of Sr/Ca is similar between 9 and 0 ka (−0.25%/kyr) and between 25 and 16 ka (+0.16%/kyr). This suggests that during these intervals, benthic foraminiferal Sr/Ca was affected by similar large-scale variables. One of these variables may be the average marine Sr/Ca ratio; however, comparison with model predictions [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118] suggests other factors must also be considered. The discrepancies between the two sites may be related to the different water mass histories for the Caribbean and eastern Atlantic. Our results suggest that variation of the seawater Sr budget only partially contributed to C. wuellerstorfi Sr/Ca records, while other significant factors still need to be quantified. At present we cannot confidently determine past seawater Sr/Ca variation from our foraminiferal records.     

On using mixed-layer transport parameterizations with radiometric surface temperature for computing regional scale sensible heat flux

Recent mixed-layer formulations for computing large-scale surface energy fluxes under daytime convective conditions do not require the estimation of surface-layer parameters, such as the roughness lengths for momentum and heat. This greatly simplifies approaches using operational satellite measurements of surface temperature for computing the surface energy balance at regional scales because the surface roughness parameters are not well known for many landscapes. The utility of such mixed-layer formulations is tested using data from several recent multidisciplinary field experiments (HAPEX-MOBILHY, FIFE and Monsoon 90). The results indicate that specific mixed-layer formulations adequately simulate surface sensible heat fluxes in the grassland and shrubland sites. However, use of the original values of proposed empirical coefficients for the forested site yield poor results. This is probably due to the fact that the forested site has significantly different surface geometry and associated distribution of temperature among the surface components (especially the relative importance of soil background temperatures) compared to the other sites. Therefore, the relationship between aerodynamic and radiometric surface temperature may have greatly differed between the forested site and the other locations. However, differences in aerodynamic roughness between the experimental sites were not correlated with changes required in the values of the coefficients. Instead, a two-source model which makes the distinction between aerodynamic and radiative temperature is proposed, as a means to determine which surface properties significantly affect the magnitude of the mixed-layer coefficients.     

Scales of nutrient-limited phytoplankton productivity in Chesapeake Bay

The scales on which phytoplankton biomass vary in response to variable nutrient inputs depend on the nutrient status of the plankton community and on the capacity of consumers to respond to increases in phytoplankton productivity. Overenrichment and associated declines in water quality occur when phytoplankton growth rate becomes nutrient-saturated, the production and consumption of phytoplankton biomass become uncoupled in time and space, and phytoplankton biomass becomes high and varies on scales longer than phytoplankton generation times. In Chesapeake Bay, phytoplankton growth rates appear to be limited by dissolved inorganic phosphorus (DIP) during spring when biomass reaches its annual maximum and by dissolved inorganic nitrogen (DIN) during summer when phytoplankton growth rates are highest. However, despite high inputs of DIN and dissolved silicate (DSi) relative to DIP (molar ratios of N∶P and Si∶P>100), seasonal accumulations of phytoplankton biomass within the salt-intruded-reach of the bay appear to be limited by riverine DIN supply while the magnitude of the spring diatom bloom is governed by DSi supply. Seasonal imbalances between biomass production and consumption lead to massive accumulations of phytoplankton biomass (often>1,000 mg Chl-a m^?2) during spring, to spring-summer oxygen depletion (summer bottom water <20% saturation), and to exceptionally high levels of annual phytoplankton production (>400 g m^?2 yr^?1). Nitrogen-dependent seasonal accumulations of phytoplankton biomass and annual production occur as a consequence of differences in the rates and pathways of nitrogen and phosphorus cycling within the bay and underscore the importance of controlling nitrogen inputs to the mesohaline and lower reaches of the bay.     

The study of the undiscovered mineral resources of the Tongass National Forest and adjacent lands,Southeastern Alaska

The quantitative probabilistic assessment of the undiscovered mineral resources of the 17.1-million-acre Tongass National Forest (the largest in the United States) and its adjacent lands is a nonaggregated, mineral-resource-tract-oriented assessment designed for land-planning purposes. As such, it includes the renewed use of gross-in-place values (GIPV's) in dollars of the estimated amounts of metal contained in the undiscovered resources as a measure for land-use planning.Southeastern Alaska is geologically complex and contains a wide variety of known mineral deposits, some of which have produced important amounts of metals during the past 100 years. Regional geological, economic geological, geochemical, geophysical, and mineral exploration history information for the region was integrated to define 124 tracts likely to contain undiscovered mineral resources. Some tracts were judged to contain more than one type of mineral deposit. Each type of deposit may contain one or more metallic elements of economic interest. For tracts where information was sufficient, the minimum number of as-yet-undiscovered deposits of each type was estimated at probability levels of 0.95, 0.90, 0.50, 0.10, and 0.05.The undiscovered mineral resources of the individual tracts were estimated using the U.S. Geological Survey's MARK3 mineral-resource endowment simulator; those estimates were used to calculate GIPV's for the individual tracts. Those GIPV's were aggregated to estimate the value of the undiscovered mineral resources of southeastern Alaska. The aggregated GIPV of the estimates is $40.9 billion.Analysis of this study indicates that (1) there is only a crude positive correlation between the size of individual tracts and their mean GIPV's: and (2) the number of mineral-deposit types in a tract does not dominate the GIPV's of the tracts, but the inferred presence of synorogenic-synvolcanic nickel-copper, porphyry copper skarn-related, iron skarn, and porphyry copper-molybdenum deposits does. The influence of this study on the U.S. Forest Service planning process is yet to be determined.     

The protective role of mountain forests

While additional research in needed on the hydrological and erosional effects of changes in mountain forests, sufficient knowledge is available, or may be inferred from existing research, to question, refute or reaffirm some of the conventional wisdom about the protective role of these forests. A major difficulty is sorting out the consequences of natural processes from those caused by anthropogenic actions. The effects of alteration or removal/conversion of mountain forests on rainfall, surface erosion, mass erosion, sediment, floods and low flows is reviewed. It is suggested that a key factor in the cause/effect scenario is the size of the catchment unit being appraised.     

EPA's Approach to Vadose Zone Monitoring at RCRA Facilities

The U.S. Environmental Protection Agency (EPA) recently proposed to amend federal regulations to require vadose zone monitoring at certain hazardous waste facilities. To support this proposal, EPA evaluated previous policy on vadose zone monitoring and examined advances in vadose zone monitoring technology. Changes in EPA vadose zone monitoring policy were driven by demonstrated advances in the available monitoring technology and improvements in understanding of vadose zone processes/When used under the appropriate conditions, currently available direct and indirect monitoring methods can effectively detect contamination that may leak from hazardous waste facilities into the vadose zone. Direct techniques examined include soil-core monitoring and soil-pore liquid monitoring. Indirect techniques examined include soil-gas monitoring, neutron moderation, complex resistivity, ground-penetrating radar, and electrical resistivity. Properly designed vadose zone monitoring networks can act as a complement to saturated zone monitoring networks at numerous hazardous waste facilities. At certain facilities, particularly those in arid climates where the saturated zone is relatively deep, effective vadose zone monitoring may allow a reduction in the scope of saturated zone monitoring programs.