Geochemistry of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex,South Sulawesi,Indonesia: Protolith origin and tectonic setting

We present the first data on bulk‐rock major and trace element compositions for a suite of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex, Indonesia, with the aim of better constraining the protolith origins and nature of the subducted crust. The eclogites can be classified into two groups: glaucophane‐rich eclogite and glaucophane‐free eclogite, whereas the blueschists are divided into albite–epidote glaucophanite and quartz–glaucophane schists. SiO₂ contents of the eclogites are 43.3–49.6 wt%, with Na₂O + K₂O contents 3.7–4.7 wt%. The blueschists show a wider range of compositions, with SiO₂ = 40.7–63.8 wt% and Na₂O + K₂O = 2.7–4.5 wt%. Trace element data suggest that the eclogite protoliths include both enriched and normal mid‐oceanic ridge basalt (E‐MORB and N‐MORB) and also gabbroic cumulates. The blueschists show more variation in protoliths, which include N‐MORB, Oceanic Island Basalt (OIB) and Island Arc Basalt (IAB). Plots of element concentrations against the immobile Zr show considerable mobility of large ion lithophiles but not of high field‐strength elements during high‐pressure metamorphism, and indicate that the high SiO₂ content of some blueschists is probably due to metasomatism by a LILE‐rich siliceous aqueous fluid. Strong correlations between K, Rb, Ba and Cs suggests that enrichment of these elements occurred by a single process. All the protoliths were subducted, metamorphosed to blueschist/eclogite‐facies and subsequently exhumed. It is noteworthy that the samples deduced to have come from thicker‐crust environments (OIB, IAB) were subducted to shallower depths (blueschist‐facies) than MORB‐derived samples, all except one of which reached eclogite‐facies conditions. The geochemical data of this study demonstrate the variety of ocean floor types that were subducted under the southeast margin of Sundaland in the late Jurassic period.     

Epithermal Gold Mineralization in the Trenggalek District,East Java,Indonesia

Gold‐mineralized quartz veins at the Trenggalek district of the Southern Mountains Range in East Java, Indonesia, are hosted by Oligo‐Miocene volcaniclastic and volcanic rocks, and are distributed close to andesitic plugs in the northern prospects (Dalangturu, Suruh, Jati, Gregah, Jombok, Salak, and Kojan) and the southern prospects (Sentul and Buluroto). The plugs are subalkaline tholeiitic basaltic‐andesite to calc‐alkaline andesite in composition. ⁴⁰Ar–³⁹Ar dating of a quartz‐adularia vein at the Dalangturu prospect yielded an age of 16.29 ± 0.56 Ma (2σ), and a crystal tuff of a limestone‐pyroclastic rock sequence at the southwest of the Dalangturu prospect was determined as 15.6 ± 0.5 Ma (2σ). Statistic overlap of ages suggests that the gold mineralization in the northern prospects took place in a shallow marine to subaerial transitional environment. Hydrothermal alteration of the host rocks is characterized by the replacement of quartz, illite and adularia. Quartz veins in surface outcrops are up to 50 cm wide in the northern prospects and up to 3 m wide in the southern prospects, showing a banded or brecciated texture, and are composed of quartz, adularia, carbonates with pyrite, electrum, sphalerite, galena, and polybasite. Gold contents of quartz veins are positively correlated with Ag, Zn, Pb, and Cu contents in both the northern and southern prospects. The quartz veins at the Jati, Gregah, and Sentul prospects have relatively lower gold‐silver ratios (Ag/Au = 23.2) compared to those at the Kojan, Dalangturu, Salak, and Suruh prospects (Ag/Au = 66.8). The quartz veins at the Dalangturu prospect are relatively rich in base metal sulfides. Ag/(Au+Ag) ratios of electrum in the Dalangturu prospect range from 45.2 to 65.0 at%, and FeS contents of sphalerite range from 1.2 to 6.4 mol%. Fluid inclusion microthermometry indicates ore‐forming temperatures of 190–200°C and 220–230°C at the Sentul and Kojan prospects, respectively. Widely variable vapor/liquid ratio of fluid inclusions indicates that fluid boiling took place within the hydrothermal system at the Sentul prospect. Salinities of ore‐fluids range from 0 to 0.7 wt% (av. 0.4 wt% NaCl equiv.) and from 0.5 to 1.4 wt% (av. 0.9 wt%) for the Sentul and Kojan prospects, respectively. The boiling of hydrothermal fluid was one of the gold deposition mechanisms in the Sentul prospect.     

The stemflow of trees in a Bornean lowland tropical forest

Stemflow volume generation in lowland tropical forests was measured over a 1‐year period in the Malaysian state of Sarawak. The stemflow volume generated by 66 free‐standing trees with a diameter at breast height (DBH) over 1 cm and a tree height over 1 m were measured daily in a representative 10 m × 10 m plot of the forest. Throughfall in the plot was also measured using 20 gauges in a fixed position. Of the 2292 mm of total rainfall observed during the year‐long period, stemflow accounted for 3·5%, throughfall for 82% and there was an interception loss of 14·5%. Understory trees (DBH < 10 cm) played an important role in stemflow generation, producing 77% of the overall stemflow volume and 90% during storms with less than 20 mm of rainfall. Also, owing to their efficiency at funneling rainfall or throughfall water received by their crowns, some understory trees noticeably reduced the catches of the throughfall gauges situated under the reach of their crown areas. During storms producing greater than 20 mm of rainfall, 80% of the total stemflow occurred; trees with a large DBH or height and for which the ratio between crown's diameter and depth is less than 1, tended to generate more stemflow volume in these storms. Mean areal stemflow as a fraction of rainfall in this lowland tropical forest was 3·4%, but may range from 1–10% depending upon the proportion of trees that are high or poor stemflow yielders. Trees with DBH greater than 10 cm were likely to contribute less than 1% of the 3·4% mean areal stemflow in the forest. Copyright © 2004 John Wiley & Sons, Ltd.     

Characteristics of Gold Mineralization at the Ciurug Vein, Pongkor Gold-Silver Deposit, West Java, Indonesia

Abstract. The Pongkor Gold‐Silver Mine, Bogor district, West Java, is approximately 80 km southwest of Jakarta. The gold and silver mineralization in the area is present in a deposit consisting of an epithermal vein‐system named individually as the Pasir Jawa, Gudang Handak, Ciguha, Pamoyanan, Kubang Cicau, and Ciurug veins. In the area studied, rocks of basaltic‐andesitic composition are dominated by volcanic breccia and lapilli tuff, with andesite lava and siltstone present locally. The hydrothermal alteration minerals in the Ciurug area are typical of those formed from acid to near‐neutral pH thermal waters, where the acid alteration is distributed from the surface to shallow depth, while the near‐neutral pH alteration becomes dominant at depths. The Ciurug vein shows four main mineralization stages where each discrete stage is characterized by a specific facies; these are, from early to late: carbonate‐quartz, manganese carbonate‐quartz, banded‐massive quartz and gray sulfide‐quartz facies. The major metallic minerals are pyrite, sphalerite, chalcopyrite and galena; they occur in almost each mineralization stage. Bornite was observed only in the southern part of the Ciurug vein at a depth of 515 m, and the occurrence of this mineral is reported here for the first time. Electrum and silver sulfides (mostly acanthite) are minor, whereas silver sulfosalts, stromeyerite and mckinstryite, and covellite are in trace amounts. The silver sulfosalts have compositional ranges of pearceite, antimon‐pearceite and polybasite. Most of the electrum occurs coexisting with other sulfide minerals, as inclusions in pyrite grains, with very little as inclusions in chalcopyrite or sphalerite. Gold grades within the Ciurug vein vary from 1.2 to hundreds of ppm, where the highest gold grade occurs in the latest mineralization stage in a thin sulfide band in vein quartz. Fluid inclusion microthermometry of calcite and quartz indicates deposition throughout the mineralized veins in the range from 170 to 230d?C and from low salinity fluids (predominantly lower than 0.2 wt% NaCl equiv.). Fluid inclusions occur with features of boiling.     

Origin of Ore-forming Fluids Responsible for Gold Mineralization of the Pongkor Au-Ag Deposit, West Java, Indonesia: Evidence from Mineralogic, Fluid Inclusion Microthermometry and Stable Isotope Study of the Ciurug–Cikoret Veins

The Pongkor gold–silver mine is situated at the northeastern flank of the Bayah dome, which is a product of volcanism in the Sunda–Banda Arc. The hydrothermal alteration minerals in the Ciurug–Cikoret area are typical of those formed from acid to near‐neutral pH thermal waters. On the surface, illite/smectite mixed layer mineral (I/Sm), smectite and kaolinite, and spotting illite, I/Sm and K‐feldspar alteration occur at the top of the mineralized zone. Silicification, K‐feldspar and I/Sm zones are commonly formed in the wall rock, and gradually grade outwards into a propylitic zone. The mineralization of precious metal ore zone is constrained by fluid temperatures between 180 and 220°C, and with low salinity (<0.2 wt% NaCl equivalent) and boiling condition. The minimum depth of vein formation below the paleo‐water table is approximately 90–130 m for the hydrostatic column. Hydrogen and oxygen isotope data for quartz and calcite show relatively homogeneous fluid composition (?53 to ?68‰δD and ?5.7 to +0.3‰δ¹⁸O H₂O). There is no specific trend in the data with respect to the mineralization stages and elevation, which suggests that the ore‐forming fluids did not significantly change spatially during the vein formation. The stable isotope data indicate mixing between the hydrothermal fluids and meteoric water and interaction between the hydrothermal fluids and the host rock.     

Concentration of Gold(I) Thiosulfate Complex Ions on the Surface of Alumina Gel and their Change in Chemical State: Preliminary Experiment in the Elucidation of the Formation Mechanism of Epithermal Gold Deposits

In order to elucidate the formation mechanism of low‐sulfidation epithermal gold deposit, the adsorption of [Au(S₂O₃)₂]^3? (a model compound for gold(I) complex ion) on alumina gel (a model compound for the aluminum‐bearing minerals) and change in chemical state of [Au(S₂O₃)₂]^3? after adsorption on the surface of alumina gel were investigated as a basic model experiment. In the pH range from 4 to 6, the amount of [Au(S₂O₃)₂]^3? adsorbed on alumina gel decreased with increasing pH and decreased drastically between pH 6 and 7, and then approached zero above pH 8 at 30°C. At 60°C, the amount of gold adsorbed above pH 7 was enhanced compared with that at 30°C. This adsorption tendency indicates that [Au(S₂O₃)₂]^3? is mainly adsorbed by electrostatic interaction between negative charges of [Au(S₂O₃)₂]^3? and positive charges of alumina gel because of its isoelectric point around pH 9. The chemical state of gold after adsorption of [Au(S₂O₃)₂]^3? on alumina gel was examined using X‐ray absorption near edge structure (XANES). The result showed that [Au(S₂O₃)₂]^3? was spontaneously reduced to elemental gold even in the absence of specific reducing agents after adsorption on alumina gel. This reduction reaction might occur by two steps: (i) disproportionation of the adsorbed [Au(S₂O₃)₂]^3? at the surface of alumina gel, and (ii) spontaneous reduction of the resulting gold(III) complex ions on the surface of alumina gel. The experimental results suggest that aluminum plays an important role in the concentration of gold(I) complex ions and subsequent reduction of gold during the formation of low‐sulfidation epithermal gold deposits.     

Internal structure of the Nojima Fault zone from the Hirabayashi GSJ drill core

Abstract The internal structures of the Nojima Fault, south-west Japan, are examined from mesoscopic observations of continuous core samples from the Hirabayashi Geological Survey of Japan (GSJ) drilling. The drilling penetrated the central part of the Nojima Fault, which ruptured during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake) ( M 7.2). It intersected a 0.3 m-thick layer of fault gouge, which is presumed to constitute the fault core (defined as a narrow zone of extremely concentrated deformation) of the Nojima Fault Zone. The rocks obtained from the Hirabayashi GSJ drilling were divided into five types based on the intensities of deformation and alteration: host rock, weakly deformed and altered granodiorite, fault breccia, cataclasite, and fault gouge. Weakly deformed and altered granodiorite is distributed widely in the fault zone. Fault breccia appears mostly just above the fault core. Cataclasite is distributed mainly in a narrow (≈1 m wide) zone in between the fault core and a smaller gouge zone encountered lower down from the drilling. Fault gouge in the fault core is divided into three types based on their color and textures. From their cross-cutting relationships and vein development, the lowest fault gouge in the fault core is judged to be newer than the other two. The fault zone characterized by the deformation and alteration is assumed to be deeper than 426.2 m and its net thickness is > 46.5 m. The fault rocks in the hanging wall (above the fault core) are deformed and altered more intensely than those in the footwall (below the fault core). Furthermore, the intensities of deformation and alteration increase progressively towards the fault core in the hanging wall, but not in the footwall. The difference in the fault rock distribution between the hanging wall and the footwall might be related to the offset of the Nojima Fault and/or the asymmetrical ground motion during earthquakes.