A statistical procedure for the analysis of seismotectonically induced hydrochemical signals: A case study from the Eastern Carpathians, Romania

Changes in the stress field of an aquifer system induced by seismotectonic activity may change the mixing ratio of groundwaters with different compositions in a well, leading to hydrochemical signals which in principle could be related to discrete earthquake events. Due to the complexity of the interactions and the multitude of involved factors the identification of such relationships is a difficult task. In this study we present an empiric statistical approach suitable to analyse if there is an interdependency between changes in the chemical composition of monitoring wells and the regional seismotectonic activity of a considered area. To allow a rigorous comparison with hydrochemistry the regional earthquake time series was aggregated into an univariate time series. This was realized by expressing each earthquake in form of a parameter “e”, taking into consideration both energetic (magnitude of a seismic event) and spatial parameters (position of epi/hypocentrum relative to the monitoring site). The earthquake and the hydrochemical time-series were synchronised aggregating the e-parameters into “earthquake activity” functions E, which takes into account the time of sampling relative to the earthquakes which occurred in the considered area. For the definition of the aggregation functions a variety of different “e” parameters were considered. The set of earthquake functions E was grouped by means of factor analysis to select a limited number of significant and representative earthquake functions E to be used further on in the relation analysis with the multivariate hydrochemical data set. From the hydrochemical data a restricted number of hydrochemical factors were extracted. Factor scores allow to represent and analyse the variation of the hydrochemical factors as a function of time. Finally, regression analysis was used to detect those hydrochemical factors which significantly correlate with the aggregated earthquake functions.This methodological approach was tested with a hydrochemical data set collected from a deep well monitored for two years in the seismically active Vrancea region, Romania. Three of the hydrochemical factors were found to correlate significantly with the considered earthquake activities. A screening with different time combinations revealed that correlations are strongest when the cumulative seismicity over several weeks was considered. The case study also showed that the character of the interdependency depends sometimes on the geometrical distribution of the earthquake foci. By using aggregated earthquake information it was possible to detect interrelationships which couldn't have been identified by analysing only relations between single geochemical signals and single earthquake events. Further on, the approach allows to determine the influence of different seismotectonic patterns on the hydrochemical composition of the sampled well. The method is suitable to be used as a decision instrument in assessing if a monitoring site is suitable or not to be included in a monitoring net within a complex earthquake prediction strategy.     

Correlation between hydrogen isotope ratios of lipid biomarkers and sediment maturity

We investigated the influence of thermal maturity on the hydrogen isotope ratios of sedimentary hydrocarbons to prove that the isotope ratio of hydrocarbons mirrors paleoclimate signatures. δD values from n-alkanes and acyclic isoprenoids of two sediment sections (Kupferschiefer [KS], 258 Ma, and Posidonienschiefer [PS], 184 Ma) with different maturation history were investigated. Both covered thermal maturity from 0.48 to 1.3 R_c (vitrinite reflectance and reflectance calculated from MPI1). Sediment burial up to 4500 m caused thermal maturation of organic matter in the KS horizon from the Early Zechstein basin of Poland, whereas contact metamorphic thermal maturation originated in the Early Toarcian PS (Posidonienschiefer) of the North German Vlotho Massif. The δD values of the extracted n-alkanes positively correlate with thermal maturity in the KS (y = 56‰ × MPI1[x] − 160‰ [VSMOW]) and in the PS (y = 104‰ × MPI1[x] − 200‰ [VSMOW]). The δD values of isoprenoids (i.e., pristane, phytane) were even more enriched with increasing maturity (y = 179‰ × MPI1[x] − 341‰ [VSMOW] in the KS; y = 300‰ × MPI1[x] − 415‰ [VSMOW] in PS).These results explain why isotope ratios of n-alkanes and isoprenoids in mature sediments are generally enriched in D and do not have the expected isotopic difference between n-alkanes and isoprenoids of ∼190‰. Moreover, the correlation between sediment maturity parameters and δD values suggests that after correction the δD values of n-alkanes can be used to reconstruct climate and environment in the geological past.     

Long-term soil moisture dynamics derived from GNSS interferometric reflectometry: a case study for Sutherland,South Africa

Soil moisture is a geophysical key observable for predicting floods and droughts, modeling weather and climate and optimizing agricultural management. Currently available in situ observations are limited to small sampling volumes and restricted number of sites, whereas measurements from satellites lack spatial resolution. Global navigation satellite system (GNSS) receivers can be used to estimate soil moisture time series at an intermediate scale of about 1000 m². In this study, GNSS signal-to-noise ratio (SNR) data at the station Sutherland, South Africa, are used to estimate soil moisture variations during 2008–2014. The results capture the wetting and drying cycles in response to rainfall. The GNSS Volumetric Water Content (VWC) is highly correlated (r ² = 0.8) with in situ observations by time-domain reflectometry sensors and is accurate to 0.05 m³/m³. The soil moisture estimates derived from the SNR of the L1 and L2P signals compared to the L2C show small differences with a RMSE of 0.03 m³/m³. A reduction in the SNR sampling rate from 1 to 30 s has very little impact on the accuracy of the soil moisture estimates (RMSE of the VWC difference 1–30 s is 0.01 m³/m³). The results show that the existing data of the global tracking network with continuous observations of the L1 and L2P signals with a 30-s sampling rate over the last two decades can provide valuable complementary soil moisture observations worldwide.     

Petrogenesis and tectonic association of rift-related basic Panjal dykes from the northern Indian plate,North-Western Pakistan: evidence of high-Ti basalts analogous to dykes from Tibet

Mineralogy and Petrology - Rift related magmatism during Permian time in the northern margin of Indian plate is represented by basic dykes in several Himalayan terranes including north western...     

Structural evolution of the contact between two Penninic nappes (Zermatt-Saas zone and Combin zone,Western Alps) and implications for the exhumation mechanism and palaeogeography

The boundary zone between two Penninic nappes, the eclogite-facies to ultrahigh-pressure Zermatt-Saas zone in the footwall and the blueschist-facies Combin zone in the hanging wall, has been interpreted previously as a major normal fault reflecting synorogenic crustal extension. Quartz textures of mylonites from this fault were measured using neutron diffraction. Together with structural field observations, the data allow a refined reconstruction of the kinematic evolution of the Pennine nappes. The main results are: (1) the contact is not a normal fault but a major thrust towards northwest which was only later overprinted by southeast-directed normal faulting; (2) exhumation of the footwall rocks did not occur during crustal extension but during crustal shortening; (3) the Sesia-Dent Blanche nappe system originated from a continental fragment (Cervinia) in the Alpine Tethys ocean, and the Combin zone ophiolites from the ocean basin southeast of Cervinia; (4) out-of-sequence thrusting played a major role in the tectonic evolution of the Penninic nappes. An erratum to this article can be found at     

GPS radio holography as a tool for remote sensing of the atmosphere, mesosphere, and terrestrial surface from space

GPS radio occultation (RO) signals are highly coherent and precise, and thus sufficient for holographic investigation of the atmosphere, ionosphere, and the Earth's surface from space. In principle, three-dimensional radio-holographic remote sensing is possible by using new radio holographic equations to retrieve the radio field within the atmosphere from a radio field known at some interface outside the atmosphere. A simplified two-dimensional form of the radio-holographic equations which are developed under an assumption of local spherical symmetry can be used to obtain two-dimensional radio images of the atmosphere and terrestrial surface. To achieve this, radio holograms recorded by a GPS receiver onboard a low earth orbit (LEO) satellite at two GPS frequencies can be used and focused synthetic aperture principle applied. Analysis of GPS/MET RO data is presented to show the effectiveness of a radio-holographic approach. It is shown that the amplitude of GPS radio signals (in addition to phase data) can be used to obtain detailed altitude profiles of the vertical gradient of refractivity in the atmosphere and electron density in the mesosphere. The results demonstrate the applicability of GPS radio holography for a detailed global study of the natural processes in the atmosphere and mesosphere. Electronic Publication     

Direct measurements of volume transports through Fram Strait

Heat and freshwater transports through Fram Strait are understood to have a significant influence on the hydrographic conditions in the Arctic Ocean and on water mass modifications in the Nordic seas. To determine these transports and their variability reliable estimates of the volume transport through the strait are required. Current meter moorings were deployed in Fram Strait from September 1997 to September 1999 in the framework of the EU MAST III Variability of Exchanges in the Northern Seas programme. The monthly mean velocity fields reveal marked velocity variations over seasonal and annual time scales, and the spatial structure of the northward flowing West Spitsbergen Current and the southward East Greenland Current with a maximum in spring and a minimum in summer. The volume transport obtained by averaging the monthly means over two years amounts to 9.5 ± 1.4 Sv to the north and 11.1 ± 1.7 Sv to the south (1 Sv = 10⁶ m³s⁻¹). The West Spitsbergen Current has a strong barotropic and a weaker baroclinic component; in the East Greenland Current barotropic and baroclinic components are of similar magnitude. The net transport through the strait is 4.2 ± 2.3 Sv to the south. The obtained northward and southward transports are significantly larger than earlier estimates in the literature; however, within its range of uncertainty the balance obtained from a two year average is consistent with earlier estimates.     

High temperature alteration minerals and thermal brines,Reykjanes, Iceland

The geothermal area on Reykjanes, Iceland has been investigated mineralogically. The temperature within the studied area is very variable from 30–300° C. Mineral zones corresponding to the temperature conditions in the area are found. Accidental changes in the geothermal system are also reflected in the mineralogy by formation of anhydrite. Changes in temperature conditions in the field are indicated by epidote occurrence at 40° C and retrograd formation of montmorillonite.