Geochemical study of the redistribution of elements in soil—I. Evaluation of degree of weathering of transported soil materials by distribution of major elements among the particle size fractions and soil extract

Sixteen alluvial and terrace soils from Japan and Thailand were separated into six fractions ; an amorphous sesquioxide and combined organic matter fraction, crystalline sesquioxides, clay, silt, fine sand and coarse sand. Content of ten major and minor elements in these six fractions was analyzed; SiO₂, A1₂O₃, Fe₂O₃, MgO, CaO, K₂O, TiO₂, Rb₂O and SrO were determined by X-ray fluorescence spectrometry, and Na₂O was determined by neutron activation analysis. The clay, silt, fine sand and coarse sand mineralogy were estimated semi-quantitatively by X-ray diffraction methods.We propose three indices of geochemical maturity for the soils and test their usefulness as measures of the degree of weathering. Three concomitant factors are proposed to measure the relative resistate, hydrolyzate and oxidate nature of the major elements in the soils.     

The design and flight performance of the PoGOLite Pathfinder balloon-borne hard X-ray polarimeter

In the 50 years since the advent of X-ray astronomy there have been many scientific advances due to the development of new experimental techniques for detecting and characterising X-rays. Observations of X-ray polarisation have, however, not undergone a similar development. This is a shortcoming since a plethora of open questions related to the nature of X-ray sources could be resolved through measurements of the linear polarisation of emitted X-rays. The PoGOLite Pathfinder is a balloon-borne hard X-ray polarimeter operating in the 25-240 keV energy band from a stabilised observation platform. Polarisation is determined using coincident energy deposits in a segmented array of plastic scintillators surrounded by a BGO anticoincidence system and a polyethylene neutron shield. The PoGOLite Pathfinder was launched from the SSC Esrange Space Centre in July 2013. A near-circumpolar flight was achieved with a duration of approximately two weeks. The flight performance of the Pathfinder design is discussed for the three Crab observations conducted. The signal-to-background ratio for the observations is shown to be 0.25 ±0.03 and the Minimum Detectable Polarisation (99 % C.L.) is (28.4 ±2.2) %. A strategy for the continuation of the PoGOLite programme is outlined based on experience gained during the 2013 maiden flight.     

南海大气季节内振荡特征及其与ENSO循环的关系

采用1979—2009年NCEP/NCAR再分析资料、NOAA向外长波辐射(outgoing long-wave radiation,简称OLR)及扩展重建海表面温度资料,对南海大气季节内振荡(Intra-seasonal Oscillation,简称ISO)特征及其与ENSO循环的关系进行了诊断分析。结果表明:1)南海大气ISO的30~60 d周期在5—10月均显著。一般年南海大气ISO的对流传播在纬向上存在东传和西传,在经向上具有南北半球季节性摆动的特征。以低频动能表征的南海大气ISO强度年代际变化特征明显,近31 a来趋势增强,年变化呈单峰结构,峰值在7—8月。2)南海大气ISO的对流与ENSO循环显著相关,其强度在El Nio(La Nia)年减弱(增强)。与一般年对比,南海大气ISO对流在El Nio和La Nia年均表现为西传减弱、北传显著。北传特征表现为强对流活跃带于春季(4—5月)北跳至北半球(在La Nia年最北可至35°N),但在北半球的传播方向与一般年相比存在显著差异。3)南海大气ISO强度与ENSO循环关系密切,在El Nio(La Nia)年减弱(增强),两者表现为约半年(6~8个月)的滞后相关。Nio3区海表面温度异常序列与南海大气ISO强度的相关在中西太平洋地区和El Nio成熟前的春、秋季最显著,同时相关中心伴随低频动能高值区东移。     

Alkaline leaching characteristics of biogenic opal in Eocene sediments from the central Arctic Ocean: a case study in the ACEX cores

Accurate knowledge of the extent of biogenic opal preservation in marine sediment cores is important for paleoceanographic reconstructions. The alkaline leaching method is widely employed for %biogenic opal analysis due to its ease and speed. In this study, a revised method for measuring %biogenic opal in sediment from arctic coring expedition samples was suggested. The studied middle Eocene sediments from the central Arctic Ocean presented a problem in insufficiently leaching biogenic opal with a Na₂CO₃ solution. Based on XRD analysis, it was suggested that such an alkaline resistance results from slight diagenesis of biogenic opal. In order to solve this problem, an alkaline leaching method utilizing a 2 M NaOH solution was suggested for the accurate measurement of %biogenic opal in the Eocene sediments from the central Arctic. Furthermore, dissolution rates from lithogenic matter by NaOH solution were measured in order to correct the %biogenic opal values.     

Performance assessment of three convective parameterization schemes in WRF for downscaling summer rainfall over South Africa

Austral summer rainfall over the period 1991/1992 to 2010/2011 was dynamically downscaled by the weather research and forecasting (WRF) model at 9 km resolution for South Africa. Lateral boundary conditions for WRF were provided from the European Centre for medium-range weather (ECMWF) reanalysis (ERA) interim data. The model biases for the rainfall were evaluated over the South Africa as a whole and its nine provinces separately by employing three different convective parameterization schemes, namely the (1) Kain–Fritsch (KF), (2) Betts–Miller–Janjic (BMJ) and (3) Grell–Devenyi ensemble (GDE) schemes. All three schemes have generated positive rainfall biases over South Africa, with the KF scheme producing the largest biases and mean absolute errors. Only the BMJ scheme could reproduce the intensity of rainfall anomalies, and also exhibited the highest correlation with observed interannual summer rainfall variability. In the KF scheme, a significantly high amount of moisture was transported from the tropics into South Africa. The vertical thermodynamic profiles show that the KF scheme has caused low level moisture convergence, due to the highly unstable atmosphere, and hence contributed to the widespread positive biases of rainfall. The negative bias in moisture, along with a stable atmosphere and negative biases of vertical velocity simulated by the GDE scheme resulted in negative rainfall biases, especially over the Limpopo Province. In terms of rain rate, the KF scheme generated the lowest number of low rain rates and the maximum number of moderate to high rain rates associated with more convective unstable environment. KF and GDE schemes overestimated the convective rain and underestimated the stratiform rain. However, the simulated convective and stratiform rain with BMJ scheme is in more agreement with the observations. This study also documents the performance of regional model in downscaling the large scale climate mode such as El Niño Southern Oscillation (ENSO) and subtropical dipole modes. The correlations between the simulated area averaged rainfalls over South Africa and Nino3.4 index were ?0.66, ?0.69 and ?0.49 with KF, BMJ and GDE scheme respectively as compared to the observed correlation of ?0.57. The model could reproduce the observed ENSO-South Africa rainfall relationship and could successfully simulate three wet (dry) years that are associated with La Niña (El Niño) and the BMJ scheme is closest to the observed variability. Also, the model showed good skill in simulating the excess rainfall over South Africa that is associated with positive subtropical Indian Ocean Dipole for the DJF season 2005/2006.     

Primary melt from Sannome-gata volcano,NE Japan arc: constraints on generation conditions of rear-arc magmas

The conditions under which rear-arc magmas are generated were estimated using primary basalts from the Sannome-gata volcano, located in the rear of the NE Japan arc. Scoriae from the volcano occur with abundant crustal and mantle xenoliths, suggesting that the magma ascended rapidly from the upper mantle. The scoriae show significant variations in their whole-rock compositions (7.9–11.1 wt% MgO). High-MgO scoriae (MgO > ~9.5 wt%) have mostly homogeneous ⁸⁷Sr/⁸⁶Sr ratios (0.70318–0.70320), whereas low-MgO scoriae (MgO < ~9 wt%) have higher ⁸⁷Sr/⁸⁶Sr ratios (>0.70327); ratios tend to increase with decreasing MgO content. The high-MgO scoriae are aphyric, containing ~5 vol% olivine microphenocrysts with Mg# [100 × Mg/(Mg + Fe²⁺)] of up to 90. In contrast, the low-MgO scoriae have crustal xenocrysts of plagioclase, alkali feldspar, and quartz, and the mineralogic modes correlate negatively with whole-rock MgO content. On the basis of these observations, it is inferred that the high-MgO scoriae represent primary or near-primary melts, while the low-MgO scoriae underwent considerable interaction with the crust. Using thermodynamic analysis of the observed petrological features of the high-MgO scoriae, the eruption temperature of the magmas was constrained to 1,160–1,220 °C. Given that the source mantle was depleted MORB-source mantle, the primary magma was plausibly generated by ~7 % melting of a garnet-bearing spinel peridotite; taking this into consideration, and considering the constraints of multi-component thermodynamics, we estimated that the primary Sannome-gata magma was generated in the source mantle with 0.5–0.6 wt% H₂O at 1,220–1,230 °C and at ~1.8 GPa, and that the H₂O content of the primary magma was 6–7 wt%. The rear-arc Sannome-gata magma was generated by a lower degree of melting of the mantle at greater depths and lower temperatures than the frontal-arc magma from the Iwate volcano, which was also estimated to be generated by ~15 % melting of the source mantle with 0.6–0.7 wt% H₂O at ~1,250 °C and at ~1.3 GPa.     

Small body surface gravity fields via spherical harmonic expansions

Conventional gravity field expressions are derived from Laplace’s equation, the result being the spherical harmonic gravity field. This gravity field is said to be the exterior spherical harmonic gravity field, as its convergence region is outside the Brillouin (i.e., circumscribing) sphere of the body. In contrast, there exists its counterpart called the interior spherical harmonic gravity field for which the convergence region lies within the interior Brillouin sphere that is not the same as the exterior Brillouin sphere. Thus, the exterior spherical harmonic gravity field cannot model the gravitation within the exterior Brillouin sphere except in some special cases, and the interior spherical harmonic gravity field cannot model the gravitation outside the interior Brillouin sphere. In this paper, we will discuss two types of other spherical harmonic gravity fields that bridge the null space of the exterior/interior gravity field expressions by solving Poisson’s equation. These two gravity fields are obtained by assuming the form of Helmholtz’s equation to Poisson’s equation. This method renders the gravitational potentials as functions of spherical Bessel functions and spherical harmonic coefficients. We refer to these gravity fields as the interior/exterior spherical Bessel gravity fields and study their characteristics. The interior spherical Bessel gravity field is investigated in detail for proximity operation purposes around small primitive bodies. Particularly, we apply the theory to asteroids Bennu (formerly 1999 RQ36) and Castalia to quantify its performance around both nearly spheroidal and contact-binary asteroids, respectively. Furthermore, comparisons between the exterior gravity field, interior gravity field, interior spherical Bessel gravity field, and polyhedral gravity field are made and recommendations are given in order to aid planning of proximity operations for future small body missions.     

Interface wave generated by an electromagnetic induction source

Interface waves such as the Scholte wave are a useful tool to study geoacoustic properties and can be conventionally generated by an explosive or a pneumatic source on/above the seafloor. This type of source, however, generates strong compressional waves in the water and sediment at the same time; these waves then disturb an observation of interface waves and leads to difficulty in processing. These sources are also relatively hard to control at sea from a viewpoint of repeatability and stability of interface waves to be generated. In addition, environmental problems caused by those sources is a concern. In this paper, an electromagnetic induction source whose vibrator plate hits the seafloor directly and excites interface waves is described. The capability of this source was evaluated both in a water tank and at seashore. The pulsed Scholte waves excited both by several types of electromagnetic induction source having a different shape of vibrator plate and by dropping weight were transmitted in sediment and received using geophones. As a result of comparison of measured signals, the pulse signal propagating from the source demonstrates a sharper rise time than that from dropping weight