Mercury levels in fish,invertebrates and sediment in a recently recorded polluted area (Nissum Broad,western Limfjord,Denmark)

High concentrations of mercury were measured in sediment and animals collected in the immediate vicinity of a closed-down chemical factory. Sediment contained up to 22 ppm (dry wt) of mercury, deposit-feeding bivalves between 1.4 and 4.4 ppm (wet wt), suspension-feeding bivalves between 0.9 and 1.9 ppm and predatory fish between 0.3 and 0.8 ppm. Outside the ‘hot spot’ area, the mercury concentration in sediment and mussels (Mytilus edulis) rapidly decreased with increasing distance from the former factory. Mercury concentration in flounders (Platichthys flesus) also decreased with distance from the source; the decline was, however, much less marked.     

Alterations of cretaceous siltstones and sandstones near basalt contacts (Nûgssuaq,Greenland)

The influence of the intrusion of basaltic dykes and sills was investigated on sandstones and siltstones of the Atane Formation (Turonian-Coniacian) from the Sarqaq area (Nûgssuaq peninsula, central West Greenland).In the unaltered rock sequence, the siltstones are dominated by kaolinite, quartz and feldspar. No cementation was observed. The sandstones which are prevalent in this formation are arkoses and lithic arkoses with quartz/feldspar ratios of about 1, with variable contents of rock fragments and with minor amounts of matrix. The matrix consists mainly of kaolinite, less frequently of illite-muscovite and smectite or interstratified illite-smectite. Cement minerals include calcite, Fe-calcite, both mainly in concretions, and subordinate Fe-oxide hydrates.The porosity of the sandstones and siltstones indicates a former maximum depth of burial of 1000 m in the Sarqaq region.Adjacent to thin dykes and sills (1–2 m) the above-described rocks are altered as follows. In sandstones albite (fibrous), quartzine, smectite, goethite were all formed at the expense of kaolinitic matrix, and aragonite cement. In siltstones, interstratified illite-smectite, illite, smectite and low-cristobalite replaced kaolinite. These minerals, especially smectite, exclude temperatures above 200°C; they were probably formed during a cooling period.Adjacent to thicker basalt intrusions—only sills, over 5 m thick, and no dykes are known from this area—the following alterations are observed. In sandstones two textural types of albite were formed in addition to: (1) fibrous albite mentioned above; (2) undulose lath-shaped albite; (3) coarse-twinned non-undulose replacement albite. Moreover, brownish luminescing undulose quartz, muscovite, chlorite, epidote, nontronite and anatase occur. In siltstones the mineral association muscovite-chlorite-pyrophyllite-albite occurs, suggesting temperatures in the range of 250–500°C. Additionally a 22–26 Å mixed-layer mineral (chlorite-muscovite?) formed. At the contacts of thick as well as thin basalt intrusions the detrital grains directly adjoining the basalt are partly fractured; potassium feldspar grains show also a chemical disintegration.The temperatures calculated by application of a cooling model are higher than those indicated by the mineral alterations observed. Convective heat transfer by pore water is suggested as an explanation.     

Wind characteristics at the Boulder Atmospheric Observatory

Wind speeds at the 300 m tower at the Boulder Atmospheric Observatory have been analyzed. This tower is located in slightly rolling farmland. The following conclusions have been reached:

1. For west winds, the terrain is sufficiently uniform for simple surface-layer theory to be adequate without modification even though the air has moved up a small slope to reach the tower. For south and southeast winds, ‘effective’ roughness lengths must be introduced, which are significantly larger than the ‘true’ roughness length.
2. Useful wind estimates up to 150 m can be made from winds at 10 m and stability information, provided the ‘effective’ roughness length is known.
3. The observations are consistent with a von Kármán constant of 0.35.

     

Magmatism and crustal evolution in Costa Rica (Central America)

New major element and trace element data of Lower Tertiary volcanics and of rocks of the Aguacate volcanic series permit a better understanding of the petrochemical evolution in the Costa Rica area. This evolution of the magmatic and tectonic processes shows clearly the transformation of oceanic crust with basic magmatism into a continental crust with intermediate to acidic magmatic activity. The main trend since the upper Cretaceous is characterized by a continual increase of the silica level of the magmatic products which build up the present tectonitic crust of Costa Rica.Only the Aguacate volcanic series is contrasting from all other magmatic series by predominance of alkaline rocks which are petrochemically quite similar to the volcanics of the East-Pacific Islands. It is considered, therefore, that the Aguacate volcanics represent remnants of Upper Tertiary island volcanoes.

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Zusammenfassung Neue chemische Gesteinsanalysen und Spurenelement-Daten von tertiären Vulkaniten Costa Ricas erlauben eine bessere Interpretation der petrochemischen Entwicklung im südlichen Mittelamerika. Sie ist gekennzeichnet durch einen kontinuierlichen Anstieg des SiO₂-Gehaltes der magmatischen Förderprodukte von der Oberkreide bis zur Gegenwart. Hierin kommt die Umwandlung ozeanischer in kontinentale (tectonitic) Kruste zum Ausdruck.Abweichend von allen anderen magmatischen Serien Costa Ricas weist die Aguacate-Serie eine Vorherrschaft von alkalinen Gesteinen auf, die petrochemisch denen der ost-pazifischen Inselvulkane ähnlich sind. Es wird daher die Möglichkeit erörtert, da\ die Aguacate-Serie stark abgetragene Reste tertiärer Inselvulkane darstellt.

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Resumen Nuevos análisis químicos y datos de elementos trazas en los volcanitos terciarios de Costa Rica permiten una mejor interpretación de la evolución quimica del magmatismo en la zona de América Central. Dicha evolución está caracterizada por un continuo aumento en el contenido de SiO₂ de las rocas volcánicas desde el Cretácico superior hasta el Reciente. El aumento de silice manifesta la transformación de la corteza oceánica en una corteza continental (tectonítica).La Serie Aguacate se diferencia de todas las otras series magmáticas de Costa Rica, mostrando una predominación de las rocas alcalinas, que químicamente se parecen a las de las islas volcánicas en el Pacífico oriental. Por esta razón se discute la posibilidad de que la Serie Aguacate representa los restos fuertemente erosionados de islas volcánicas terciarias.

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Vorläufige Mitteilungen über das Vorkommen des aus Purpurbakterien stammenden Pigmentes Okenon in Seesedimenten

The isolation of the carotenoid Okenone from the sediments of several shallow lakes gives evidence of anaerobic zones existing during the sedimentation 13 000 years before.