Hydrogen bonding in goldichite,KFe(SO4)2⋅4H2O: structure refinement

Mineralogy and Petrology - The crystal structure of goldichite KFe(SO4)2⋅4H2O was determined on a single crystal from the Baiyinchang copper deposit, Gansu, China. [P121/c1, a = 10.395(2), b...     

The IWAS-ToolBox: Software coupling for an integrated water resources management

Numerical modeling of interacting flow and transport processes between different hydrological compartments, such as the atmosphere/land surface/vegetation/soil/groundwater systems, is essential for understanding the comprehensive processes, especially if quantity and quality of water resources are in acute danger, like e.g. in semi-arid areas and regions with environmental contaminations. The computational models used for system and scenario analysis in the framework of an integrated water resources management are rapidly developing instruments. In particular, advances in computational mathematics have revolutionized the variety and the nature of the problems that can be addressed by environmental scientists and engineers. It is certainly true that for each hydro-compartment, there exists many excellent simulation codes, but traditionally their development has been isolated within the different disciplines. A new generation of coupled tools based on the profound scientific background is needed for integrated modeling of hydrosystems. The objective of the IWAS-ToolBox is to develop innovative methods to combine and extend existing modeling software to address coupled processes in the hydrosphere, especially for the analysis of hydrological systems in sensitive regions. This involves, e.g. the provision of models for the prediction of water availability, water quality and/or the ecological situation under changing natural and socio-economic boundary conditions such as climate change, land use or population growth in the future.     

Gravitational signature of rotationally distorted Jupiter caused by deep zonal winds

Both deep zonal winds, if they exist, and the basic rotational distortion of Jupiter contribute to its zonal gravity coefficients J_n for n ? 2. In order to capture the gravitational signature of Jupiter that is caused solely by its deep zonal winds, one must take into account the full effect of rotational distortion by computing the coefficients J_n in non-spherical geometry. This represents a difficult and challenging problem because the widely-used spherical-harmonic-expansion method becomes no longer suitable. Based on the model of a polytropic Jupiter with index unity, we compute Jupiter’s gravity coefficients J₂, J₄, J₆, … , J₁₂ taking into account the full effect of rotational distortion of the gaseous planet using a finite element method. For the model of deep zonal winds on cylinders parallel to the rotation axis, we also compute the variation of the gravity coefficients ΔJ₂, ΔJ₄, ΔJ₆, … , ΔJ₁₂ caused solely by the effect of the winds in non-spherical geometry. It is found that the effect of the zonal winds on lower-order coefficients is weak, ∣ΔJ_n/J_n∣ < 1%, for n = 2, 4, 6, but it is substantial for the high-degree coefficients with n ? 8.     

Strength Behavior of Naturally Cemented Marine Clay Due to Change in Ground Water Level

The change in strength and deformation behavior of a typical marine clay deposit formed under shallow water is presented and discussed for the conditions of changing water table. This is a costal marine clay deposit with moderate carbonates along the east coast of India. The soil samples were taken from tidal flats where the sea had receded some time back, and the behavior of this deposit had been studied for the conditions of 1976, with high water table, and for the conditions of 2001, with depleted water table. Undisturbed soil samples were taken from sheeted open test pits. Standard consolidation and triaxial shear tests were conducted. Consolidation tests conducted on the samples taken for 1976 conditions with high water contents indicate that cementation effect are erased out under moderate stresses. Beyond this stress range, it behaves like soft, normally consolidated clay. In contrast, the results obtained from samples taken during 2001, with depleted water table, clearly indicate that the soil behaves like an over-consolidated one, and the improvement in the system is due to the chemical bonding and desiccation.     

Grain misorientations in partially molten olivine aggregates: an electron backscatter diffraction study

In polycrystalline aggregates of olivine with mean grain sizes above 35 μm plus a low basaltic melt fraction, both wetted and melt-free grain boundaries are observed after equilibration times at high pressures and temperatures of between 15 and 25 days. In order to assess a possible dependence of the wetting behaviour on the relative orientation of neighbouring grains, a SEM based technique, electron backscatter diffraction (EBSD), is used to determine grain orientations. From the grain orientations relative orientations of neighbouring grains are calculated, which are expressed as misorientation axis/angle pairs. The distribution of misorientation angles and axes of melt-free grain boundaries differ significantly from a purely random distribution, whereas those of wetted grain boundaries are statistically indistinguishable from the random distribution. The relative orientation of two neighbouring grains therefore influences the character of their common grain boundary. However, no clustering towards special (coincident site lattice) misorientation axes is observed, with the inference that the energy differences between special and general misorientations are too small to lead to the development of preferred misorientations during grain growth. Received: 8 December 1997 / Revised, accepted: 6 April 1998     

GPS Antenna Calibration at the National Geodetic Survey

The precise point whose position is being measured when a GPS baseline is determined is generally assumed to be the phase center of the GPS antenna. However, the phase center of a GPS antenna is neither a physical point nor a stable point. For any given GPS antenna, the phase center will change with the changing direction of the signal from a satellite. Ideally, most of this phase center variation depends on satellite elevation. Azimuthal effects are only introduced by the local environment around each individual antenna site. These phase center variations affect the antenna offsets that are needed to connect GPS measurements to physical monuments. Ignoring these phase center variations can lead to serious (up to 10 cm) vertical errors. This article will describe the procedure by which the National Geodetic Survey is calibrating GPS antennas and how this information may be obtained and used to avoid problems from these antenna variations. ? 1999 John Wiley & Sons, Inc.     

SPM response to tide and river flow in the hyper-turbid Ems River

In this paper, we analyse the behaviour of fine sediments in the hyper-turbid Lower Ems River, with focus on the river’s upper reaches, a stretch of about 25 km up-estuary of Terborg. Our analysis is based on long records of suspended particulate matter (SPM) from optical backscatter (OBS) measurements close to the bed at seven stations along the river, records of salinity and water level measurements at these stations, acoustic measurements on the vertical mud structure just up-estuary of Terborg and oxygen profiles in the lower 3 m of the water column close to Leerort and Terborg. Further, we use cross-sectionally averaged velocities computed with a calibrated numerical model. Distinction is made between four timescales, i.e. the semi-diurnal tidal timescale, the spring–neap tidal timescale, a timescale around an isolated peak in river flow (i.e. about 3 weeks) and a seasonal timescale. The data suggest that a pool of fluid/soft mud is present in these upper reaches, from up-estuary of Papenburg to a bit down-estuary of Terborg. Between Terborg and Gandersum, SPM values drop rapidly but remain high at a few gram per litre. The pool of fluid/soft mud is entrained/mobilized at the onset of flood, yielding SPM values of many tens gram per litre. This suspension is transported up-estuary with the flood. Around high water slack, part of the suspension settles, being remixed during ebb, while migrating down-estuary, but likely not much further than Terborg. Around low water slack, a large fraction of the sediment settles, reforming the pool of fluid mud. The rapid entrainment from the fluid mud layer after low water slack is only possible when the peak flood velocity exceeds a critical value of around 1 m/s, i.e. when the stratified water column seems to become internally supercritical. If the peak flood velocity does not reach this critical value, f.i. during neap tide, fluid mud is not entrained up to the OBS sensors. Thus, it is not classical tidal asymmetry, but the peak flood velocity itself which governs the hyper-turbid state in the Lower Ems River. The crucial role of river flow and river floods is in reducing these peak flood velocities. During elongated periods of high river flow, in e.g. wintertime, SPM concentrations reduce, and the soft mud deposits consolidate and possibly become locally armoured as well by sand washed in from the river. We have no observations that sediments are washed out of the hyper-turbid zone. Down-estuary of Terborg, where SPM values do not reach hyper-turbid conditions, the SPM dynamics are governed by classical tidal asymmetry and estuarine circulation. Hence, nowhere in the river, sediments are flushed from the upper reaches of the river into the Ems-Dollard estuary during high river flow events. However, exchange of sediment between river and estuary should occur because of tide-induced dispersion.     

The influence of bank strength on channel geometry: an integrated analysis of some observations

Bank strength exerts a significant influence on river channel geometry, but quantification of this relationship has been limited to only a few specific circumstances. This is due to both the complex nature of bank strength and the difficulty in incorporating its influence in river channel geometry relations. In order to undertake an integrated analysis of wide-ranging field observations, this study applies a recently developed multivariate model of channel geometry. When the banks of a number of laterally stable streams are categorized on the basis of the bank sediment and vegetation, the multivariate model yields numerical indices of bank strength. Within the range of the data analysed, bank strength can produce a three-fold change in channel width and a two-fold change in depth corresponding to about a 1·6-fold change in cross-sectional area. © 1998 John Wiley & Sons, Ltd.