Plio-Pleistocene age of high-potassium volcanism in the northwestern part of the hellenic arc

Summary Two newK/Ar dates firmly establish that the high potassium volcanic rocks of Thessaly are of late Pliocene and Pleistocene age, considerably younger than the geochemically similar rocks of the Dodecanese.

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Das plio-pleistozäne Alter des kalireichen Vulkanismus im Nordwest-Teil des hellenischen Bogens

Zusammenfassung Zwei neue Altersbestimmungen nach derK/Ar-Methode zeigen, daß die kalireichen Vulkanite Thessaliens spät-pliozänen und pleistozänen Alters sind und damit beträchtlich jünger als die geochemisch ähnlichen Gesteine des Dodekanes.

     

Geochemistry of Miocene shoshonites,Lesbos, Greece

Mid-Miocene shoshonitic volcanism in Lesbos is preceded and followed by minor calcalkaline activity that probably terminated in the Pliocene. Two differentiation trends are recognised in the shoshonites. The older shoshonites include voluminous acid rocks (mostly ignimbrites) and show normal shoshonite REE patterns. They were probably derived from partial melting of garnet peridotite enriched in LILE, with later fractionation controlled by anhydrous phases. Cooling units in the ignimbrites show upward increase in the K content of glass, suggesting K-feldspar fractionation in a high level magma chamber. Later shoshonites and the calc-alkali rocks have HREE enrichment and contain hydrous cognate xenoliths. Partial melting of a rising periodite diapir which had been relatively enriched in HREE within the garnet stability field and then entered the spinel stability field, would produce the observed HREE enrichment pattern. Later fractionation of these younger shoshonites and calc-alkali rocks was controlled largely by hydrous phases.     

Irrigation Effects on Hydro-Climatic Change: Basin-Wise Water Balance-Constrained Quantification and Cross-Regional Comparison

Hydro-climatic changes driven by human land and water use, including water use for irrigation, may be difficult to distinguish from the effects of global, natural and anthropogenic climate change. This paper quantifies and compares the hydro-climatic change effects of irrigation using a data-driven, basin-wise quantification approach in two different irrigated world regions: the Aral Sea drainage basin in Central Asia and the Indian Mahanadi River Basin draining into the Bay of Bengal. Results show that irrigation-driven changes in evapotranspiration and latent heat fluxes and associated temperature changes at the land surface may be greater in regions with small relative irrigation impacts on water availability in the landscape (here represented by the Mahanadi River Basin) than in regions with severe such impacts (here represented by the Aral region). Different perspectives on the continental part of Earth’s hydrological cycle may thus imply different importance assessments of various drivers and impacts of hydro-climatic change. Regardless of perspective, however, actual basin-wise water balance constraints should be accounted to realistically understand and accurately quantify continental water change.     

Arctic Climate and Water Change: Model and Observation Relevance for Assessment and Adaptation

The Arctic is subject to growing economic and political interest. Meanwhile, its climate and water systems are in rapid transformation. In this paper, we review and extend a set of studies on climate model results, hydro-climatic change, and hydrological monitoring systems. Results indicate that general circulation model (GCM) projections of drainage basin temperature and precipitation have improved between two model generations. However, some inaccuracies remain for precipitation projections. When considering geographical priorities for monitoring or adaptation efforts, our results indicate that future projections by GCMs and recent observations diverge regarding the basins where temperature and precipitation changes currently are the most pronounced and where they will be so in the future. Regarding late twentieth-century discharge changes in major Arctic rivers, data generally show excess of water relative to precipitation changes. This indicates a possible contribution to sea-level rise of river water that was previously stored in permafrost or groundwater. The river contribution to the increasing Arctic Ocean freshwater inflow is similar in magnitude to the separate contribution from glaciers, which underlines the importance of considering all possible sources of freshwater when assessing sea-level change. We further investigate monitoring systems and find a lack of harmonized water chemistry data, which limits the ability to understand the origin and transport of nutrients, carbon and sediment to the sea. To provide adequate information for research and policy, Arctic hydrological and hydrochemical monitoring needs to be extended, better integrated and made more accessible. Further water-focused data and modeling efforts are required to resolve the source of excess discharge in Arctic rivers. Finally, improvements in climate model parameterizations are needed, in particular for precipitation projections.     

Exchange and pathways of deep and shallow groundwater in different climate and permafrost conditions using the Forsmark site, Sweden, as an example catchment

This study simulates and quantifies the exchange and the pathways of deep and shallow groundwater flow and solute transport under different climate and permafrost conditions, considering the example field case of the coastal Forsmark catchment in Sweden. A number of simulation scenarios for different climate and permafrost condition combinations have been performed with the three-dimensional groundwater flow and transport model MIKE SHE. Results show generally decreasing vertical groundwater flow with depth, and smaller vertical flow under permafrost conditions than under unfrozen conditions. Also the overall pattern of both the vertical and the horizontal groundwater flow, and the water exchange between the deep and shallow groundwater systems, change dramatically in the presence of permafrost relative to unfrozen conditions. However, although the vertical groundwater flow decreases significantly in the presence of permafrost, there is still an exchange of water between the unfrozen groundwater system below the permafrost and the shallow groundwater in the active layer, via taliks. ‘Through taliks’ tend to prevail in areas that constitute groundwater discharge zones under unfrozen conditions, which then mostly shift to net recharge zones (through taliks with net downward flow) under permafrost conditions.     

Cost-efficient management of coastal aquifers via recharge with treated wastewater and desalination of brackish groundwater: general framework

Abstract

Semi-arid coastal zones often suffer water-stress, as water demand is high and markedly seasonal, due to agriculture and tourism. Driven by scarcity of surface water, the communities in semi-arid coastal regions turn to aquifers as prime water source; but intensive exploitation of coastal aquifers causes seawater intrusion, which degrades the quality of groundwater. The cost-efficient and sustainable development of coastal aquifers can be achieved through a holistic management scheme which combines two non-traditional water sources: (a) saltwater, to be treated to the desired quality, and (b) wastewater, to be re-claimed to augment aquifer recharge for control of seawater intrusion, and also to meet certain demands. This management scheme is based on the idea that it is cost-advantageous to: (i) desalt brackish groundwater, instead of seawater, as the former requires far less energy, and (ii) to re‐use wastewater at only the differential cost to any treatment already practiced. In this paper, we present the general framework of the proposed management scheme, and a decision aid tool (DAT) which has been developed to assist decision makers to explore the scheme's decision space. The DAT uses cost as optimization criterion to screen various management scenarios, via modelling of the dynamic natural-engineered system behaviour, and identifies those cost-efficient ones that meet the water demand and achieve aquifer protection.

Citation Koussis, A. D., Georgopoulou, E., Kotronarou, A., Lalas, D. P., Restrepo, P., Destouni, G., Prieto, C., Rodriguez, J. J., Rodriguez-Mirasol, J., Cordero, T. & Gomez-Gotor, A. (2010 Koussis, A. D., Georgopoulou, E., Kotronarou, A., Mazi, K., Restrepo, P., Destouni, G., Prieto, C., Rodriguez, J. J., Rodriguez-Mirasol, J., Cordero, T., Schwartz, J., Ioannou, C., Georgiou, A. and Zacharias, I. 2010. Cost-efficient management of coastal aquifers in water-stressed regions via recharge with treated wastewater and desalination of brackish groundwater: application to the Akrotiri basin and aquifer, Cyprus. Hydrol. Sci. J, 55(7): 1234–1245. [Taylor & Francis Online], [Web of Science ®] , [Google Scholar]) Cost-efficient management of coastal aquifers via recharge with treated wastewater and desalination of brackish groundwater: general framework. Hydrol. Sci. J. 55(7),1217–1233.     

Sediment geochemistry as a provenance indicator: Unravelling the cryptic signatures of polycyclic sources,climate change,tectonism and volcanism

Interpretation of bulk‐sediment geochemistry is one of several approaches for determining sediment provenance. This study investigates the value added by bulk‐sediment geochemical analysis in interpreting provenance in a passive margin clastic basin, the Upper Jurassic–Lower Cretaceous deltaic sediments of the Scotian Basin. Provenance studies in this basin are challenging because source tectonic terranes are parallel to the basin margin and polycyclic sediment sources are abundant. More than 400 samples of mudstone and sandstone representing the geographical and stratigraphic range of interest were analysed for 57 elements. Diagenetic processes added calcium to many samples and removed potassium in rocks buried below 3 km, thus impacting principal component analysis and published weathering indices. However, multiple geochemical approaches to assessing the degree of weathering showed climatically controlled changes in weathering in the Tithonian and Barremian, and changes in supply from major tectonic events, such as the top‐Aptian uplift in the Labrador rift. Covariance of elements in heavy minerals demonstrates the varying magnitude of polycyclic supply and stratigraphic changes in sources. Geochemical analyses revealed a previously unsuspected Tithonian alkali volcanic sediment source, characterized by high niobium and tantalum. The lack of highly contrasting sources means that geochemistry alone is inadequate to determine sediment provenance. Published discrimination diagrams are of limited value. Statistical analysis of geochemical data is strongly influenced by diagenetic processes, episodic volcanic inputs and polycyclic concentration of resistant heavy minerals in sandstones. Single indicator elements for particular sources are generally lacking. Nevertheless, careful consideration of geochemical variability on a case by case basis, integrated with detrital mineral studies, provides new insights into palaeoclimate, sediment provenance and, hence, regional tectonics. Although there is no simple template for such analysis, this study demonstrates an approach that can be used for other basins.