A Case Study of CO<Subscript>2</Subscript>, CO and Particles Content Evolution in the Suburban Atmospheric Boundary Layer Using a 2-μm Doppler DIAL,a 1-μm Backscatter Lidar and an Array of In-situ Sensors

A network of remote and in-situ sensors was deployed in a Paris suburb in order to evaluate the mesoscale evolution of the daily cycle of CO₂ and related tracers in the atmospheric boundary layer (ABL) and its relation to ABL dynamics and nearby natural and anthropogenic sources and sinks. A 2-μm heterodyne Doppler differential absorption lidar, which combines measurements of, (1) structure of the atmosphere, (2) radial velocity, and (3) CO₂ differential absorption was a particularly unique element of the observational array. We analyse the differences in the diurnal cycle of CO, CO₂, lidar reflectivity (a proxy for aerosol content) and H₂O using the lidar, airborne measurements in the free troposphere and ground-based measurements made at two sites located few kilometres apart. We demonstrate that vertical mixing dominates the early morning drawdown of CO and aerosol content trapped in the former nocturnal layer but not the H₂O and CO₂ mixing ratio variations. Surface fluxes, vertical mixing and advection all contribute to the ABL CO₂ mixing ratio decrease during the morning transition, with the relative importance depending on the rate and timing of ABL rise. We also show evidence that when the ABL is stable, small-scale (0.1-km vertical and 1-km horizontal) gradients of CO₂ and CO are large. The results illustrate the complexity of inferring surface fluxes of CO₂ from atmospheric budgets in the stable boundary layer.     

Laser Ablation (193 nm), Purification and Determination of Very Low Concentrations of Solar Wind Nitrogen Implanted in Targets from the GENESIS Spacecraft

The GENESIS space mission recovered ions emitted by the Sun during a 27 month period. In order to extract, purify and determine the very low quantities of solar nitrogen implanted in the GENESIS targets, a new installation was developed and constructed at the CRPG (Nancy, France). It permitted the simultaneous determination of nitrogen and noble gases extracted from the target by laser ablation. The extraction procedure used a 193 nm excimer laser that allowed for surface contamination in the outer 5 nm to be removed, followed by a step that removed 50 nm of the target material, extracting the solar nitrogen and noble gases implanted in the target. Following purification using Ti and Zr getters for noble gases and a Cu-CuO oxidation cycle for N₂, the extracted gases were analysed by static mode (pumps closed) mass spectrometry using electron multiplier and Faraday cup detectors. The nitrogen blanks from the purification section and the static line (30 minutes) were only 0.46 picomole and 0.47 picomole, respectively.     

Observations Of The Turbulence Structure Within Two Stratocumulus-Topped, Marine Boundary Layers

Two situations observed during the second Aerosol Characterization Experiment (ACE-2) are analysed from aircraft measurements in the broken stratocumulus (Sc)-topped marine boundary layer. The first one (26 June 1997), characterized by a non-polluted, oceanic air mass, presents a decoupling between the Sc layer (1400–1520 m) and the turbulent mixed layer, this latter extending from the surface up to 580 m. In contrast, the second case (9 July 1997), during which continental air had been advected over the experimental area, presents a well-coupled layer extending from the surface up to the top of the Sc layer(910 m). This coupling, uncommon in this area in the middle of the day, isrelated to the relative shallowness of the boundary layer. For both situations,it is shown that the turbulent fluxes can be computed with reasonably goodaccuracy (better than 10 %), taking into account both the random and thesystematic errors involved in the eddy-correlation technique. Estimationof random error is based on the computation of the integral scale of thecovariance, and systematic error is estimated from the parameterizationof Mann and Lenschow. The fluxes show that the buoyancy, as a sourceof turbulence, is due to latent heat flux rather than sensible heat flux,with values comparable to previous experiments in the Azores-Canariesbasin. In addition, we propose a method to analyse, for coupled situations,the relationship between the fractional cloudiness and the organization ofthe turbulent field below the clouds. This method is based on a conditionalsampling technique. It is shown that this organization cannot be deducedfrom the analysis of the velocity signal, which is dominated by turbulence.However, when the signals are conditionally sampled according to thepresence or absence of clouds, a weak cloud-related organization can beshown, and the cloud-related transports quantified; the values found areof the order of 10 % of the total transfers, i.e. the same order of magnitude asthe errors on the total flux computation. The method developed is thereforepromising, provided that the uncertainties can be reduced by analyzing a highamount of data.     

Geochimie et teneurs isotopiques des systèmes saisonniers de dissolution de la calcite dans un sol sur craie

In a soil developed on the Cretaceous chalk of the Eastern Paris basin, calcite dissolution begins at the surface. The soil water is rapidly saturated in calcite. Calcite dissolution follows two different pathways according to seasonal pedoclimatic conditions.During winter: the soil is only partly saturated in water and the CO₂ partial pressure is low (Ca 10^?3 atm.). As a consequence total inorganic dissolved carbon (TIDC) is a hundred times the carbon content of the gaseous phase. Equilibrium is usually observed between the two phases. It is a closed system. The measured carbon 14 activity (87,5%) and ¹³C content ($\text{δ}{}_{\mathrm{tidc}}{}^{13}\text{C = ?12,2\%0}$) of the drainage water are very close to theoretical values calculated for an ideal mixing system between gaseous and mineral phases (respectively characterized by the following isotopic values: $\text{δ}{}_{\mathrm{G}}{}^{13}\text{C = ?21,5\%0}$; $\text{A}{}_{\mathrm{G}}{}^{14}\text{C = 118\%}$; $\text{δ}{}_{\mathrm{M}}{}^{13}\text{C = +2,9\%0}$; $\text{A}{}_{\mathrm{M}}{}^{14}\text{C = 28\%}$).During spring and summer: the soil moisture decreases, the input of biogenic CO₂ induces an increase of the soil CO₂ partial pressure (Ca from 3.10^?3 atm to 7.10^?3 atm). The carbon content of the gaseous phase is higher by an order of magnitude compared to winter conditions. Therefore the aqueous phase is undersaturated in CO₂ with respect to the latter. This disequilibrium occurs as a result of unbalanced rates of CO₂ dissolution and CO₂ effusion toward atmosphère. It is an open system. The carbon isotopic ratio of the aqueous phase is regulated by that of the gaseous phase, as demonstrated by the agreement between measured and calculated isotopic compositions (respectively δ_{L mes} = from ?9,4%0 to ?11,5%0, δ_{l calc} = from ?9,8%0 to ?13,9%0 A_{L mes} = 119%, A_{L calc} = from 119% to 125%).The solutions originating from both systems (open and closed) move downwards without significant mixing together. It has also been observed that no significant variation of the TIDC isotopic composition occurs during precipitation of secondary calcite.     

Molecular parameters of maturation in the Toarcian shales,Paris Basin,France—I. Changes in the configurations of acyclic isoprenoid alkanes,steranes and triterpanes

The changes in configuration at a number of chiral centres in certain acyclic isoprenoid alkanes, steranes, rearranged steranes and triterpanes of the hopane type in a suite of fourteen Toarcian shales (Paris Basin) have been determined by gas chromatography and combined gas chromatography-mass spectrometry. A sequence of changes in the ratios of various stereoisomers occurs both with increasing maximum depth of burial and in a North-South direction for shallow samples (maximum burial depth < 1000m). These changes cover the full range of maturity shown by the samples. The presence of 5α(H), 14β(H), 17β(H)-steranes in immature samples indicates the presence of a reworked component. The extent of epimerisation at a number of the chiral centres suggests that it relates to the extent of steric hindrance at the centres.     

Geochemical studies on the organic matter from the Douala Basin (Cameroon)—II. Evolution of kerogen

Optical examinations, elemental analysis, i.r. spectroscopy and thermogravimetric analysis have been used to characterize the kerogens from the Logbaba (Upper Cretaceous) cores from the Douala Basin (Cameroon). It is shown that those kerogens are derived from the same type of organic matter, having mainly a land-plant origin. This conclusion fits very well that obtained from the examination of the soluble organic matter (see Part I). Thus the evolution of the properties of kerogens during burial is not due to a change in the nature of organic matter and can be related mainly to catagenesis. Owing to the existence of a high geothermal gradient in the basin and a sampling along a 4000 m thick sedimentary column, this evolution can be followed over a large range and correlated to the formation of petroleum and gas.     

L'essai de torsion et la résistance au cisaillement des roches

Rock Mechanics and Rock Engineering - Cette étude présente un appareillage de torsion mis au point au laboratoire de Mécanique des Roches d'Electricité de France. Les...     

Les minéraux techniques naturels : connaissance,typologie et propriétés d'usageNatural technical minerals: investigation,typology and utilisation properties

By nature minerals are heterogeneous materials for many of their properties. These properties also vary according to composition and structure fluctuations, compared to definitions. Technical minerals are used in applications where their performances depend on intrinsic properties and processing conditions. It is possible to base rankings on simple criteria, allowing estimating the abilities of minerals for each utilisation. The research of the corresponding mechanisms concerns the molecular level. These questions are discussed for kaolins, raw materials for baked clays, talqueous materials and montmorillonites. To cite this article: J. Yvon et al., C. R. Geoscience 334 (2002) 717–730.     

Experimental investigation of atmospheric boundary layer turbulence

This paper describes how to measure turbulence in the atmospheric boundary layer (ABL) in order to address certain problems in modern atmospheric physics. These problems mainly relate to the Earth's energy budget (including the hydrological cycle) and biogeochemical cycles. Starting from the main characteristic numbers and the basic equations of atmospheric turbulent flow, we show what turbulence parameters are important to measure. Special attention is given to the various methods used to compute the turbulent fluxes. We analyse the range of scales which has to be measured to properly capture the eddies contributing to the turbulent transfers. This range of scales determines what sensors can be used in the atmospheric surface layer and in the ABL. We describe the most widely used instruments and their performances. The principal platforms used to deploy these instruments are examined. Aircraft are described in more details, because they allow a thorough exploration of the ABL. In the last section, some examples of ABL turbulence signals measured in various conditions are presented. These examples illustrate horizontally homogeneous turbulence as well as inhomogeneous signals for which standard analysis techniques cannot be used. We show how some recent techniques, like wavelet transforms, can help to investigate this kind of signal. At the end, we present what would be interesting to do in the near future for the study of ABL turbulence.     

A mesoscale shear convective cell observed during the C.O.A.S.T. experiment: Acoustic sounder measurements

A mesoscale shear convective cell was observed with a Doppler sodar and a minisodar on May 22, 1983 near the Netherland Coast. Boundary-layer modifications associated with fair weather precipitating clouds were observed and a separation is undertaken between the different scales of the perturbations. There is difficulty in estimating the turbulent dissipation rate by the inertial method in the presence of mesoscale perturbations, which suggests the need for independent computation of spatial structure functions of velocity fluctuations and spectral density of velocity fluctuations as functions of frequency to observe the relationship between wave lengths and frequencies.C.O.A.S.T.: Cooperative Experiment with Acoustic Sounding Techniques.