Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

Geologic and hydrologic settings for development of freshwater lenses in arid lands

Satellite observations were used to test the validity of previously identified favourable conditions for the formation of freshwater lenses, identify additional potential occurrences, and model modern potential recharge in the Raudhatain Watershed (3696) in northern Kuwait. Favourable conditions include infrequent yet intensive precipitation events, drainage depressions to collect the limited runoff, and presence of conditions (e.g. high infiltration capacity) that promote groundwater recharge and preservation (e.g. underlying saline aquifer) of infiltrating groundwater as freshwater lenses floating over saline aquifer water due to differences in density. Specifically, the following field and satellite‐based observations were noted for the Raudhatain Watershed: (1) Over ~30 precipitation events were identified from the Tropical Rainfall Measuring Mission precipitation data (1998–2009); (2) slope is gentle (2 m/km), and the surface is largely (80%) covered by alluvial deposits with high infiltration capacities (up to 9 m/day); (3) no flows and long‐term ponding were reported at the watershed outlet or detected from Landsat thematic mapper images; (4) infiltration is high based on increases in soil moisture content (from an advanced microwave scanning radiometer) and vegetation index following large precipitation events; and (5) freshwater lenses that overlie highly saline [total dissolved solids (TDS): >35 000] unconfined aquifers underlying the watershed are absent in the southern regions, where infiltrating fresh water mixes with the less saline groundwater (TDS: <10 000). Twenty potential locations (size: 1 to 75 km²) for freshwater lens development were identified in northern Kuwait, and continuous rainfall–runoff models (Soil Water and Assessment Tool) were applied to provide a first‐order estimation of the average annual recharge in the watershed (127 × 10⁶ m³) and freshwater lenses (8.17 × 10⁶ m³). Results demonstrate the settings for enhanced opportunities for groundwater recharge, outline the amounts of and preservation conditions for the groundwater feeding the freshwater lenses, and highlight potential applications and locations of freshwater lenses in similar settings elsewhere in the Arabian Peninsula and beyond. Copyright © 2013 John Wiley & Sons, Ltd.     

Concentration of selected radionuclides in seawater from Kuwait

No baseline existed for the radionuclides in Kuwait territorial water. With changing trend in the region to embrace nuclear energy, the baseline study is imperative to create a reference and to record the influence-functioning of upcoming power plants. The first one in Bushehr, Iran is ready to start and several more are likely to come-up in UAE, Saudi Arabia and Kuwait. The present baseline concentration of the four considered radionuclide's show low concentration of tritium, polonium, strontium and cesium; their concentration is comparable to most oceanic waters.     

Characteristics of concentrated flow hydraulics for rangeland ecosystems: implications for hydrologic modeling

Concentrated flow is often the dominant source of water erosion following disturbance on rangelands. Because of the lack of studies that explain the hydraulics of concentrated flow on rangelands, cropland‐based equations have typically been used for rangeland hydrology and erosion modeling, leading to less accurate predictions due to different soil and vegetation cover characteristics. This study investigates the hydraulics of concentrated flow using unconfined field experimental data over diverse rangeland landscapes within the Great Basin Region, United States. The results imply that the overall hydraulics of concentrated flow on rangelands differ significantly from those of cropland rills. Concentrated flow hydraulics on rangelands are largely controlled by the amount of cover or bare soil and hillslope angle. New predictive equations for concentrated flow velocity (R² = 0·47), hydraulic friction (R² = 0·52), and width (R² = 0·4) representing a diverse set of rangeland environments were developed. The resulting equations are applicable across a wide span of ecological sites, soils, slopes, and vegetation and ground cover conditions and can be used by physically‐based rangeland hydrology and erosion models to estimate rangeland concentrated flow hydraulic parameters. Published in 2011. This article is a US Government work and is in the public domain in the USA.     

Geospatial and geostatistical approach for groundwater potential zone delineation

Over the past few decades, groundwater has become an essential commodity owing to increased demand as a result of growing population, industrialization, urbanization and so on. The water supply situation is expected to become more severe in the future because of continued unsustainable water use and projected change in hydrometeorological parameters due to climate change. This study is based on the integrated approach of remote sensing, geographical information system and multicriteria decision‐making techniques to determine the most important contributing factors that affect the groundwater resources and to delineate the groundwater potential zones. Ten thematic layers, namely, geomorphology, geology, soil, topographic elevation (digital elevation model), land use/land cover, drainage density, lineament density, proximity of surface water bodies, surface temperature and post‐monsoon groundwater depth, were considered for the present study. These thematic layers were selected for groundwater prospecting based on the literature; discussion with the experts of the Central Ground Water Board, Government of India; field observations; geophysical investigation; and multivariate techniques. The thematic layers and their features were assigned suitable weights on Saaty's scale according to their relative significance for groundwater occurrence. The assigned weights of the layers and their features were normalized by using the analytic hierarchy process and eigenvector method. Finally, the selected thematic maps were integrated using a weighted linear combination method to create the final groundwater potential zone map. The final output map shows different zones of groundwater potential, namely, very good (16%), good (35%), moderate (28%) low (17%) and very low (2.1%). The groundwater potential zone map was finally validated using the discharge and groundwater depth data from 28 and 98 pumping wells, respectively, which showed good correlation. Copyright © 2014 John Wiley & Sons, Ltd.     

The Taratash indenter and its role in the geological structure of the Urals

This work presents the results of studying zones bounded by the Archean and Early Proterozoic Taratash block, which breaks the meridional structure of the Urals, pinching its structural zones at the latitude of the town of Miass. The mesostructures of rupture zones, microtextures of tectonites, anisotropy of the magnetic susceptibility, and seismic-wave propagation rate in blastomylonites were studied. The kinematic history of the Taratash block consists of two phases: (1) exhumation in the Middle Riphean under conditions of crustal extension; and (2) the formation of an indenter in the Late Paleozoic under conditions of compression.     

Mobility of rare earth elements in the system soils–plants–groundwaters: a case study of an arid area (Oman)

Groundwater samples from six wells and various species of plants from soils developed on ophiolites were collected from an arid area (AlKhod area, Oman) and analyzed for trace elements including rare earth elements (REEs). The distribution patterns of REEs in plants indicated an enrichment in middle REEs (MREEs?=?Sm to Dy) and heavy REEs (HREEs?=?Ho to Lu), when they are normalized to the REE composition of the Post Archean Australian Shale (PAAS), with a significant negative anomaly in Ce and a positive anomaly in Eu. Compared to Oman ophiolites, the REEs in different species of plants are depleted in Ce and enriched in MREEs and slightly enriched in light REE (LREE?=?from La to Nd). Relative to PAAS, the distribution of REEs in groundwaters revealed similar patterns to the REE distribution in plants. The distribution patterns of REEs in plants relative to those in waters are nearly flat. These patterns suggest that the transfer of REEs from soil solutions to the groundwaters in Oman occurs without any significant fractionation.