Chondritic ingredients: II. Reconstructing early solar system history via refractory lithophile trace elements in individual objects of the Leoville CV3 chondrite

We performed a LA-ICP-MS study of refractory lithophile trace elements in 32 individual objects selected from a single section of the reduced CV3 chondrite Leoville. Ingredients sampled include ferromagnesian type I and II chondrules, Al-rich chondrules (ARCs), calcium-aluminum-rich inclusions (CAIs), a single amoeboid olivine aggregate (AOA), and matrix. The majority of rare earth element (REE) signatures identified are either of the category “group II” or they are relatively flat, i.e., more or less unfractionated. Data derived for bulk Leoville exhibit characteristics of the group II pattern. The bulk REE inventory is essentially governed by those of CAIs (group II), ARCs (flat or group II), type I chondrules (about 90% flat, 10% group II), and matrix (group II). Leoville matrix also shows a superimposed positive Eu anomaly. The excess in Eu is possibly due to terrestrial weathering. The group II pattern, however, testifies to volatility-controlled fractional condensation from a residual gas of solar composition at still relatively high temperature. In principle, this signature (group II) is omnipresent in all types of constituents, suggesting that the original REE carrier of all components was CAI-like dust. In addition, single-element anomalies occasionally superimposing the group II signature reveal specific changes in redox conditions. We also determined the bulk chemical composition of all objects studied. For Mg/Si, Mg/Fe, and Al/Ca, Leoville's main ingredients—type I chondrules and matrix—display a complementary relationship. Both components probably formed successively in the same source region.     

Probabilistic Marcinkiewicz–Zygmund Inequalities on the Rotation Group

Approximation problems on the rotation group SO(3) naturally arise in various fields, like crystallography, chemistry, and biology. For example, in crystallographic texture analysis one is confronted with the problem of evaluating so-called orientation density functions (ODFs). In many situations one only has a finite number of measurements at scattered sampling nodes. In order to reconstruct ODFs over all rotations, so-called Marcinkiewicz–Zygmund inequalities on the rotation group are an important tool. These inequalities provide norm equivalences between polynomials on SO(3) and their sample values. Recently shown equivalences depend on a density parameter of the sampling set and the proven inequalities hold true for polynomials on SO(3) whose degree does not exceed an upper bound which is determined by this density parameter. In this paper, we show that we can enlarge this upper bound for the polynomial degree significantly if we are satisfied by such norm equivalences that hold with a given probability only. Moreover, we show that there are fixed sampling sets for which we get probabilistic Marcinkiewicz–Zygmund inequalities that hold for polynomials on SO(3) of all degrees.     

RoboNet‐II: Follow‐up observations of microlensing events with a robotic network of telescopes

RoboNet‐II uses a global network of robotic telescopes to perform follow‐up observations of microlensing events in the Galactic Bulge. The current network consists of three 2 m telescopes located in Hawaii and Australia (owned by Las Cumbres Observatory) and the Canary Islands (owned by Liverpool John Moores University). In future years the network will be expanded by deploying clusters of 1 m telescopes in other suitable locations. A principal scientific aim of the RoboNet‐II project is the detection of cool extra‐solar planets by the method of gravitational microlensing. These detections will provide crucial constraints to models of planetary formation and orbital migration. RoboNet‐II acts in coordination with the PLANET microlensing follow‐up network and uses an optimization algorithm (“web‐PLOP”) to select the targets and a distributed scheduling paradigm (eSTAR) to execute the observations. Continuous automated assessment of the observations and anomaly detection is provided by the ARTEMiS system (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Parameter degeneracies and (un)predictability of gravitational microlensing events

Some of the difficulties in determining the underlying physical properties that are relevant for observed anomalies in microlensing light curves, such as the mass and separation of extrasolar planets orbiting the lens star, or the relative source–lens parallax, are already anchored in factors that limit the amount of information available from ordinary microlensing events and in the way these are being parametrized. Moreover, a real-time detection of deviations from an ordinary light curve while these are still in progress can only be done against a known model of the latter, and such is also required for properly prioritizing ongoing events for monitoring in order to maximize scientific returns. Despite the fact that ordinary microlensing light curves are described by an analytic function that only involves a handful of parameters, modelling these is far less trivial than one might be tempted to think. A well-known degeneracy for small impacts, and another one for the initial rise of an event, makes an interprediction of different phases impossible, while in order to determine a complete set of model parameters, the fundamental characteristics of all these phases need to be properly assessed. While it is found that the wing of the light curve provides valuable information about the time-scale that absorbs the physical properties, the peak flux of the event can be meaningfully predicted only after about a third of the total magnification has been reached. Parametrizations based on observable features not only ease modelling by bringing the covariance matrix close to diagonal form, but also allow good predictions of the measured flux without the need to determine all parameters accurately. Campaigns intending to infer planet populations from observed microlensing events need to invest some fraction of the available time into acquiring data that allow to properly determine the magnification function.     

Geochemical and stratigraphic evidence of environmental change at Lynch's Crater, Queensland, Australia

This is one of the first applications of geochemical proxies to define changes in vegetation, hydrology and atmospheric dust influence on a peat deposit in the southern hemisphere. A 6.6 m deep peat record from Lynch's Crater in NE-Queensland, Australia, provides a sensitive  5000 to 30,000 cal years BP archive of environmental change. The deposit consists of 1.5 m of ombrotrophic peat underlain by a minerotrophic peat. Within the minerotrophic section, sponge spicules and diatom fragments offer evidence of prolonged flooding of the peat environment resulting in several layers containing (up to 50%) high inorganic material. The Ca and Mg data display episodes of enhanced dust influx and nutrient recycling and support previous palynological studies that show a Pleistocene to Holocene switch from sclerophyll woodlands to rainforest vegetation.     

Iron isotope fractionation during leaching of granite and basalt by hydrochloric and oxalic acids

Transport of iron (Fe) within hydrothermal and soil environments involves the transferral into aqueous solutions by leaching of complex, polyminerallic rocks. Understanding the isotope fractionation mechanisms during this process is key for any application of the Fe-isotope system to biogeochemical studies. Here, we reacted biotite granite and tholeiite-basalt with 0.5 M hydrochloric acid and 5 mM oxalic acid solutions at ambient temperature. Solution aliquots were recovered over a seven-day period and analysed for major and trace element concentrations and Fe isotopic compositions. In all experiments, Fe initially released into solution was isotopically lighter, with Δ⁵⁶Fe_{solution-rock} as low as −1.80‰ in the granite-hydrochloric acid system. The oxalic acid experiments showed similar patterns but smaller fractionation. In all experiments, the Δ⁵⁶Fe_{solution-rock} reduced over time, which would be in line with the formation of a leached layer as proposed before [Brantley S. L., Liermann L. J., Guynn R. L., Anbar A., Icopini G. A., and Barling J. (2004) Fe isotopic fractionation during mineral dissolution with and without bacteria. Geochim. Cosmochim. Acta68(15), 3189-3204]. Granite and basalts reacting with hydrochloric acid reached apparent steady-state values of −0.60 ± 0.15‰ and −0.40 ± 0.20‰, respectively, whilst experimental values with oxalic acid were −1.0 ± 0.15‰ and −0.50 ± 0.15‰. During the granite experiments, alteration of biotite to chlorite, followed by dissolution of chlorite, were likely the dominant processes, whilst in the basalt experiments, dissolution of pigeonite was likely the principal source of Fe. Variations in pH during the hydrochloric acid experiments were minimal, remaining below 0.5 at all times. In oxalic acid solutions, the pH increased to over 4, leading likely to precipitation of secondary minerals and adsorption/co-precipitation of Fe onto mineral surfaces. These processes could contribute to the greater fractionation observed in the final stages of the oxalic acid experiments. Our results highlight the importance of mineralogy and fluid composition on the Fe-isotope systematics during weathering. The fractionation processes identified for granites and basalts are in line with those inferred from field observations in soils, sediments, groundwater and hydrothermal deposits and from laboratory studies of single-mineral leaching.     

In situ micro‐Raman and X‐ray diffraction study of diamonds and petrology of the new ureilite UAE 001 from the United Arab Emirates

Abstract— A new olivine‐pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo_79.8–81.8) and pyroxene (En_73.9–75.2, Fs_15.5–16.9, Wo_8.8–9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo_96.1–96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro‐Raman and in situ synchrotron X‐ray diffraction. The main diamond Raman band (LO = TO mode at ?1332 cm^?1) is broadened when compared to well‐ordered diamond single crystals. Full widths at half maximum (FWHM) values scatter around 7 cm^?1. These values resemble FWHM values obtained from chemical vapor deposition (CVD) diamond. In situ XRD measurements show that diamonds have large grain sizes, up to >5 μm. Some of the graphite measured is compressed graphite. We explore the possibilities of CVD versus impact shock origin of diamonds and conclude that a shock origin is much more plausible. The broadening of the Raman bands might be explained by prolonged shock pressure resulting in a transitional Raman signal between experimentally shock‐produced and natural diamonds.     

Modal abundances of CAIs: Implications for bulk chondrite element abundances and fractionations

Abstract— Modal abundances of Ca,Al‐rich inclusions (CAIs) are poorly known and reported data scatter across large ranges. CAIs are Poisson distributed, and if only small areas (<1000 mm²) are studied, the data are probably not representative of the true CAI modal abundances, explaining their reported large scatter in a single chondrite group. We combine reported CAI modal abundances and our own set, and present a complete list of CAI modal abundances in carbonaceous chondrites. This includes (in area%): CV: 2.98, CM: 1.21, Acfer 094: 1.12, CO: 0.99, CK/CV (Ningqiang and Dar al Gani [DaG] 055): 0.77, CK: 0.2, CR: 0.12 and CB: 0.1. CAIs are Poisson distributed and if only small areas are studied, the data are probably not representative of the true CAI modal abundances, Carbonaceous chondrites have excess bulk Al concentrations when compared to the CI‐chondritic value. We find a correlation between this excess and CAI modal abundances and conclude that the excess Al was delivered by CAIs. The excess Al is only a minor fraction (usually ?10 rel%, but 25 rel% in case of CVs) of the bulk chondrite Al and cannot have contributed much ²⁶Al to heat the chondrite parent body. Ordinary, enstatite, R and K chondrites have an Al deficit relative to CI chondrites and only very low CAI modal abundances, if any are present at all. Carbonaceous chondrites also had an initial Al deficit if the contribution of Al delivered by CAIs is subtracted. Therefore all chondrites probably lost a refractory rich high‐T component. Only minor amounts of CAIs are present in the matrix or have been present in the chondrule precursor aggregates. Most CAI size distributions contain more than one size population, indicating that CAIs from within a single meteorite group had different origins.     

ARTEMiS (Automated Robotic Terrestrial Exoplanet Microlensing Search): A possible expert‐system based cooperative effort to hunt for planets of Earth mass and below

The technique of gravitational microlensing is currently unique in its ability to provide a sample of terrestrial exoplanets around both Galactic disk and bulge stars, allowing to measure their abundance and determine their distribution with respect to mass and orbital separation. Thus, valuable information for testing models of planet formation and orbital migration is gathered, constituting an important piece in the puzzle for the existence of life forms throughout the Universe. In order to achieve these goals in reasonable time, a well‐coordinated effort involving a network of either 2m or 4×1m telescopes at each site is required. It could lead to the first detection of an Earth‐mass planet outside the Solar system, and even planets less massive than Earth could be discovered. From April 2008, ARTEMiS (Automated Robotic Terrestrial Exoplanet Microlensing Search) is planned to provide a platform for a three‐step strategy of survey, follow‐up, and anomaly monitoring. As an expert system embedded in eSTAR (e‐Science Telescopes for Astronomical Research), ARTEMiS will give advice for follow‐up based on a priority algorithm that selects targets to be observed in order to maximize the expected number of planet detections, and will also alert on deviations from ordinary microlensing light curves by means of the SIGNALMEN anomaly detector. While the use of the VOEvent (Virtual Observatory Event) protocol allows a direct interaction with the telescopes that are part of the HTN (Heterogeneous Telescope Networks) consortium, additional interfaces provide means of communication with all existing microlensing campaigns that rely on human observers. The success of discovering a planet by microlensing critically depends on the availability of a telescope in a suitable location at the right time, which can mean within 10 min. To encourage follow‐up observations, microlensing campaigns are therefore releasing photometric data in real time. On ongoing planetary anomalies, world‐wide efforts are being undertaken to make sure that sufficient data are obtained, since there is no second chance. Real‐time modelling offers the opportunity of live discovery of extra‐solar planets, thereby providing “Science live to your home”. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Fen ecosystem responses to water‐level fluctuations during the early and middle Holocene in central Europe: a case study from Wilczków,Poland

This paper presents a palaeoenvironmental reconstruction of the Wilczków fen (central Poland). The fen developed in an inactive valley at the onset of the Holocene (~11 ka BP) and peat accumulation lasted until 5.7 ka BP. Multi‐proxy reconstructions were made on the basis of palaeobotanical, cladoceran, chironomid, beetle and geochemical analyses. A Kohonen self‐organizing map (SOM, unsupervised artificial neural network) of the biotic sequence distinguished four stages of fen history. Stage X₁ (11.0–10.7 ka BP) was relatively wet and cool. Organic matter started to accumulate but the habitat conditions remained unstable. Moss, sedge and fern communities then developed. Sedimentary changes reveal an intensive groundwater supply at that time. Numerous and diverse chironomid and cladoceran subfossils indicate nearly permanent aquatic conditions. During stage Y₁ (10.6–9.2 ka BP) conditions were dry and the upper peat layer desiccated. Cladocera nearly disappeared whereas chironomids were represented by semi‐terrestrial and predatory (Tanypodinae) species. Conditions started to be more reducing. All the remaining samples belonged to the interweaving stages X₂ and Y₂. Stage Y₂ (mostly 9.1–7.3 and 6.0–5.7 ka BP) was also dry but humidity increased towards the top. Oxidizing conditions occurred and the pH became more alkaline, favouring Cladium mariscus. The basin received mostly allochthonous matter input at that time. Stage X₂ (mostly 6.8–6.1 ka BP) was humid and warm. The groundwater supply remained low but there was an increase in precipitation, changing local conditions to ombrotrophic. Species‐rich chironomid and cladoceran communities were associated with temporary pools. Finally, conditions returned to those characteristic of stage Y₂. The presented reconstruction documents long‐term abiotic and biotic changes determined by water supply, including groundwater outflow, which have rarely been detected at a multi‐proxy scale. We show that inactivated valley fens are sensitive to climate‐driven hydrological fluctuations. Kohonen neural networks appear to be a promising method for analysing variability in multi‐proxy data.