Chemical ozone loss in the Arctic vortex in the winter 1995–96: HALOE measurements in conjunction with other observations

Severe chemical ozone loss has been detected in the Arctic in the winter and spring of 1995–96 by a variety of methods. Extreme reductions in column ozone due to halogen catalysed chemistry were derived from measurements of the Halogen Occultation Experiment (HALOE) on board the Upper Atmosphere Research Satellite in the Arctic vortex. Here, we discuss further aspects of the HALOE observations in the Arctic over this period. Potential problems, both in the data themselves and in the methodology of the data analysis are considered and the reason for the differences between the Arctic ozone losses deduced from HALOE data version 17 and 18 is analysed. Moreover, it is shown that HALOE measurements in the Arctic in winter and spring 1995–96 compare well with observations by other ground-based and satellite instruments.     

Pétrographie des „Permoskyth“ der Jaggl-Plawen-Einheit (Südtirol) und Diskussion der Detritusherkunft mit Hilfe von Kathoden-Lumineszenz-Untersuchungen

The Permo-Scythian deposits E of Lake Reschen (North-Italy) are composed of a sequence of terrestrial sediments in Verrucanofacies and of a series of detrital carbonate and lagoonal-evaporitic rocks (“Wechselschichten”) overlaid by Anisian fossiliferous dolomites. Examinations by cathodo-luminescence give reference to the source area of the detrius and to the diagenesis of the sediments. Further statements can be made by X-ray (triclinity of K-feldspars; inclusions in authigenic minerals) and chemical examinations (composition of dolomites). The detritus of the slightly metamorphic rocks, indicated by the crystallinity of illite, does not originate from the underlying “Plawenkristallin” and from the adjacent “ötztalkristallin”, respectively, but by 70% from a porphyritic source area that is supposed to be located in the region of Lugano.     

Geography of contamination: The location of industrial waste dumps in Catalonia

The handling of the solid industrial waste (SIW) generated in Catalonia is one of the main problems of industrial and territorial policy confronting the public bodies controlling this area of activity. The most recent estimates in this regard indicate that the annual production of SIW is 1,700,000 tons and that only 300,000 tons are treated.In this situation it is usual for a large number of industries to eliminate their SIW furtively, it is common practice to dump waste in various unprepared areas. In this article we present a series of hypotheses which we believe allow us to understand the logic that guides the siting of a large number of these dumps.In the first place we demonstrate the importance of a series of conditions derived from the same industrial logic, to wit, a) the cost of transporting the SIW to the dumps, b) the industrial decentralization process and the metropolitan development of Catalonia, c) vertical integration and the appearance of companies especially dedicated to the elimination of waste and, d) the development of land use through revaluation of the land and greater possibilities for control forces furtive dumps to be sited in more and more distant areas.Secondly, we examine the role of public bodies in this process, concentrating on the characteristics of the legal system and the real effectiveness of urban controls. Finally, in third place, an explanation is given of research carried out in the Barcelona area which shows the importance of the conditions examined above.     

Zur Glazialgeologie der chilenischen Anden

Ohne Zusammenfassung     

Early-Morning Flow Transition in a Valley in Low-Mountain Terrain Under Clear-Sky Conditions

We investigate the evolution of the early-morning boundary layer in a low-mountain valley in south-western Germany during COPS (convective and orographically induced precipitation study) in summer 2007. The term low-mountain refers to a mountainous region with a relief of gentle slopes and with an absolute altitude that remains under a specified height (usually 1,500 m a.s.l.). A subset of 23 fair weather days from the campaign was selected to study the transition of the boundary-layer flow in the early morning. The typical valley atmosphere in the morning hours was characterized by a stable temperature stratification and a pronounced valley wind system. During the reversal period—called the low wind period—of the valley wind system (duration of 1–2 h), the horizontal flow was very weak and the conditions for free convection were fulfilled close to the ground. Ground-based sodar observations of the vertical wind show enhanced values of upward motion, and the corresponding statistical properties differ from those observed under windless convective conditions over flat terrain. Large-eddy simulations of the boundary-layer transition in the valley were conducted, and statistical properties of the simulated flow agree with the observed quantities. Spatially coherent turbulence structures are present in the temporal as well as in the ensemble mean analysis. Thus, the complex orography induces coherent convective structures at predictable, specific locations during the early-morning low wind situations. These coherent updrafts, found in both the sodar observations and the simulation, lead to a flux counter to the gradient of the stably stratified valley atmosphere and reach up to the heights of the surrounding ridges. Furthermore, the energy balance in the surface layer during the low wind periods is closed. However, it becomes unclosed after the onset of the valley wind. The partition into the sensible and the latent heat fluxes indicates that missing flux components of sensible heat are the main reason for the unclosed energy balance in the considered situations. This result supports previously published investigations on the energy balance closure.     

Estimation of unrecorded groundwater abstractions in Jordan through regional groundwater modelling

Jordan suffers from water scarcity and groundwater covers the majority of Jordan’s water supply. Therefore, there is an urgent need to manage this resource conscientiously. A regional numerical groundwater flow model, developed as part of a decision support system for the country of Jordan, allows for quantification of the overexploitation of groundwater resources and enables determination of the extent of unrecorded agricultural groundwater abstraction. Groundwater in Jordan is abstracted from three main aquifers partly separated by aquitards. With updated geological, structural, and hydrogeological data available in the country, a regional numerical groundwater flow model for the whole of Jordan and the southernmost part of Syria was developed using MODFLOW. It was first calibrated for a steady-state condition using data from the 1960s, when groundwater abstraction was negligible. After transient calibration using groundwater level measurements from all aquifers, model results reproduce the large groundwater-level declines experienced in the last decades, which have led to the drying out of numerous springs. They show a reversal of groundwater flow directions in some regions, due to over-abstraction, and demonstrate that documented abstractions are not sufficient to cause the observed groundwater-level decline. Only after considering irrigation water demand derived from remote sensing data, the model is able to simulate these declines. Illegal abstractions can be quantified and predictive scenarios show the potential impact of different management strategies on future groundwater resources.

     

Light-Time Effect in the Eclipsing Binaries GO Cyg, GW Cep, AR Aur and V505 Sgr

Orbital period changes of the eclipsing binaries GO Cyg and GW Cep are explained by the light-time effect for the first time. New minima of the eclipsing binary AR Aur improve the predicted light-time orbit. The light-time orbit with the quadratic ephemeris of the binary matches the new observations of V505 Sgr better than the linear one. As the light-time effect fits in corresponding O − C diagrams of all four systems have been reaching extreme values, the observations of minima times in forthcoming years are highly desirable.     

Infrared spectroscopy of Triassic conodonts: a new tool for assessing conodont diagenesis

The Fourier transform infrared spectra of individual conodonts with various CAI values indicate definite changes in conodont francolite during diagenesis. Steady decarbonation can be observed in the increasing intensity of the band with the wavenumber 2340 an^-1, which is assigned to trapped molecular CO₂. Carbon dioxide originates from decomposing CO^2-₃-ions occupying the B-site in francolite. Furthermore, the intensity of the water-deformation band at 1644 cm^-1 decreases with higher CAI values. These changes of intensity can be quantified by calculating the maximum extinction (E_max) for the corresponding absorption maxima and correlated with the CAI. Unaltered conodonts have a relative variable water 'content' and very little CO₂. Up to a CAI value of 4 conodont francolite continuously expells water and carbon dioxide is trapped. Conodonts with CAI = 5 have similar water 'contents' to CAI = 4 conodonts, but decarbonation continues to take place during this stage of diagenesis.