The tropospheric distribution of formaldehyde during TROPOZ II

A series of 149 measurements of the HCHO mixing ratio were made between 0 and 10 km altitude and 70° N to 60° S latitude during TROPOZ II. The data show a vertical decrease of the HCHO mixing ratio with altitude at all latitudes and a broad latitudinal maximum in the HCHO mixing ratio between 30° N and 30° S at all altitudes. The measured mixing ratios of HCHO are considerably higher than those expected from CH₄ oxidation alone, but agree broadly with the average latitude by altitude distribution of HCHO derived by a 2D model including emissions of C₁–C₇ hydrocarbons. A number of the regional scale deviations of the measured HCHO distribution from the average modelled one can be explained in terms of the local wind field.     

Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.     

Effects of land-surface heterogeneity upon surface fluxes and turbulent conditions

Summary In this paper, we examine the effects of land-surface heterogeneity on the calculation of surface-energy and momentum fluxes in a meso-scale atmospheric model. A series of numerical experiments has been carried out with a combination of different resolutions for the atmosphere and the land surface, which allows an examination of the aggregation and dynamic effects associated with land-surface heterogeneity. The numerical results show that for a given atmospheric model resolution, increased land-surface resolution leads to better estimates of surface-energy and momentum fluxes, and for a given land-surface resolution, increased atmospheric model resolution also improves the estimates of these fluxes. This latter result contradicts the prevailing view that subgrid variation in atmospheric data plays only a minor role in estimating the fluxes. It is also shown that subgrid land-surface heterogeneity leads to increased turbulent fluctuations. The responsible mechanisms of this effect are both the subgrid variation of surface-energy fluxes and their impact upon the development of convective cells. It is suggested that subgrid atmospheric motions induced by surface heterogeneity may be an important factor which needs to be considered in subgrid closure schemes for atmospheric models. Received August 28, 2000/Revised June 1, 2001     

Four thousand years of atmospheric lead pollution in northern Europe: a summary from Swedish lake sediments

This paper presents a large palaeolimnological study of the pre-industrial and industrial history of atmospheric lead pollution deposition in Sweden. Both lead concentrations and ²⁰⁶Pb/²⁰⁷Pb ratios have been analysed in 31 lakes covering most of Sweden, plus one lake in north-west Russia. Four of the lakes have varved (annually-laminated) sediments. Isotope analysis is a sensitive and effective method to distinguish pollution lead from natural catchment lead and to detect early pollution influence, because the ²⁰⁶Pb/²⁰⁷Pb ratio in unpolluted background sediments in Sweden was > 1.3, while that of lead from pollution, derived from ores and coal, was < 1.2. The sediments show a consistent picture of past temporal changes in atmospheric lead pollution. These changes include: the first traces of pollution 3,500-3,000 yrs ago; a pollution peak in Greek-Roman Times (about 0 AD); lower lead fall-out between 400 and 900 AD; a significant and permanent increase in atmospheric lead fall-out from about 1000 AD; an increase with the Industrial revolution; a major increase following World War II; the maximum peak in the 1970s; and decreasing fall-out over the last decades. The four varved sediments provide high-resolution records of atmospheric pollution. They reveal pollution peaks about 1200 and 1530 AD which match the history of metal production in Europe. According to the varve records the lead pollution level in the late 1990s had decreased beneath the level of the 1530s. The pollution level 1200 AD was about 35% of the 1980s, when lead pollution was still near its all time high. About 50% of the total accumulated atmospheric lead pollution deposition through time was deposited in the pre-industrial period. The sediments also show a consistent picture of the geographic distribution of atmospheric lead deposition over time, with higher deposition in south Sweden and declining levels to the north, which supports the hypothesis that the main sources of pre-industrial atmospheric lead pollution in Sweden were cultural areas in mainland Europe and Great Britain.     

Surface NO and NO2 mixing ratios measured between 30° N and 30° S in the Atlantic region

Surface NO and NO₂ mixing ratios were measured aboard the research vessel Polarstern during the mission ANT VII/1 from 24 September to 5 October 1988. The measurements were taken along the meridian at 30° W in the Atlantic region covering latitudes between 30° N and 30° S. The average mixing ratios were about 12 pptv NO/30 pptv NO₂ in the Northern Hemisphere and about 7 pptv NO/22 pptv NO₂ in the Southern. Elevated mixing ratios of 20 pptv NO/70 pptv NO₂ were found at 12° N (probably due to air masses originating from the surface of West Africa) and in the region of the ITCZ between 8° N and 5° N. Because of probable contamination by the ship, the measured mixing ratios mostly represent upper limits.     

The fog front of 25 May 1989 — A gravity flow?

Summary During the field experiment FRONTEX 1989 a shallow cold front with a fog field behind its leading edge was observed over the North Sea. The fog field was about 70 km wide, 160 m deep at the front side and 400 m deep at the rear side and was capped by a strong frontal inversion. With increasing height of the inversion the fog broke up into cumulus clouds. The horizontal temperature gradient was largest at 500 m with 9 K/100 km. The observed segment of the front was situated near the col of a geostrophic deformation field with vanishing cross-front wind but non-vanishing cross-front confluence. The front moved at a rate of 5 m/s. It exhibits characteristics of a gravity current which propagates into a stably stratified environment.The physical processes leading to the observed frontal structure and motion are elucidated by experiments with a two-dimensional numerical model. The charateristics of the observed front can be reproduced if both, geostrophic forcing and boundary-layer processes, such as air-sea temperature difference, moisture content and cloud radiational cooling are taken into account. The development of the front under altered conditions is studied by the comparison of different simulations. The reason for the movement of the front is discussed refering to the mechanisms of geostrophic forcing and the forcing by surface friction. The analysis of the forces acting on the cold air mass shows that the Coriolis force is important at some distance behind the frontal head, but has little effect on the processes at the frontal head.With 13 Figures     

The mantle rock (“laterite”) of the Gold Coast and its origin

Zusammenfassung Der Verwitterungsmantel (Laterit s. l.) der südlichen Goldküste besteht aus Horizonten, die sowohl verschiedene Entstehungsart als verschiedenes Alter haben. Brekzien oder Steinschichten sind unter aridem Klima als Wüstenpflaster entstanden. Zonen chemisch verwitterten Felses, Horizonte von lehmigem Sand (an deren Aufbau Termiten wesentlich beteiligt sind) und Konkretionen haben sich unter feuchtem Klima gebildet. Harte limonitische Oberflächen-Krusten deuten auf progressive Austrocknung hin. Unter diesen drei klimatischen Bedingungen gebildete Horizonte wiederholen sich mehrfach im Verwitterungsmantel der Goldküste. Ein junger, unvollständiger Zyklus ist weit verbreitet, ein älterer Zyklus tritt nur in begrenzten Vorkommen auf, und ein dritter Zyklus ist fast nur noch in aufgearbeiteten, limonitisierten Bruchstücken erhalten. Die wiederholten Klimaschwankungen machen es wahrscheinlich, daß der Verwitterungsmantel zeitlich dem größeren Teil des Quartärs entspricht. Wahrscheinlich können die Ergebnisse auf weit größere Gebiete angewandt werden.     

Daily Weather Observations in Sixteenth-Century Europe

Thirty-two weather diaries written in astronomical calendars in central Europe in the late fifteenth and sixteenth centuries are presented and discussed. Systematic weather observations were promoted by the rise of planetary astronomy and its application in astro-meteorology. The practice of keeping weather diaries spread from Cracow (Poland) to Ingolstadt (Germany) and from there to other universities. The data obtained from these sources provided the backbone for setting up series of precipitation indices for Poland, Germany and Switzerland. Monthly statistics of days with precipitation, snowfall and frost were computed by counting the relevant entries in the most important diaries. The results were compared with either those obtained from instrumental measurements in the same place or with those from modern instrumental measurements in a neighbouring place. The final results show that autumn was considerably colder in the early sixteenth century. April was considerably drier and July was wetter during the period 1508-1531 than during 1901-1960. In order to highlight the impact of weather patterns on grain prices in a year of crisis, the timing of wet and dry spells in southern Poland and southern Germany is compared for the year 1529. Winters became 1.7°C colder from 1564 to 1576 and the month of July tended to be wetter than in 1901-1960. Details noted in the diaries kept between 1585 and 1600 by the astronomers Brahe (near Copenhagen) and Fabricius (in the Ostfriesland region of northwestern Germany) closely agree. It rained more often in June and July and temperatures dropped. The winter months were more frequently dominated by winds from easterly directions, the frequency of snowfall was higher and a deficit occurred in precipitation. This points to a higher frequency of high pressure in the Fennoscandian area with cold air advection from the east or northeast.