A combined statistical approach for evaluation of the effects of land use,agricultural and urban activities on stream water chemistry in small tile-drained catchments of south Bohemia,Czech Republic

This work evaluates the changes of nitrate-nitrogen (NO₃-N), ammonium-nitrogen (NH₄-N), total phosphorus (P) and chemical oxygen demand (COD) concentrations in stream waters as related to the land use/land cover (LULC) alterations within eight small (5–39 km²) tile-drained catchments in the southern part of The Czech Republic in the period 1993–2010, when massive grassing of arable land took place. The robust tools of seasonal Mann–Kendall trend test and LOcally WEighted Scatterplot Smoothing methods were employed to reveal trends of the monitored parameters with adjustment to hydrology. Using principal component analysis and multiple regressions, statistically significant factors with highest impacts on the assessed water quality parameters were identified. Besides indicators of LULC changes in the catchments and their various zones, information of built tile drainage systems were used along with factors reflecting point pollution sources such as the population number, sewerage type and proximity to a watercourse, effectiveness of wastewater treatment, and number of livestock units. The change in LULC was essential only for NO₃-N concentrations, when grassing of arable land, presence of water ponds, areas of permanent cultures and also areas of drained land explained up to 90.6 % NO₃-N variability and nitrate-nitrogen concentrations showed a significantly decreasing trend in all monitored catchments during the evaluated period. LULC changes within infiltration vulnerable zones were discovered as less important for the assessed water quality parameters compared to LULC changes in the whole catchment area. However, for NH₄-N, P and COD, the results did not enable a definite quantification of the effects of LULC changes. The influence of non-point pollution sources on these parameters was revealed as uncertain and was heavily overshadowed by point sources, in particular by wastewater management, and livestock numbers, although the proportion of arable land in tile drainage subcatchments was discovered fundamental in case of the COD. The increasing numbers of livestock, population, and changes in sewage treatment led in some catchments to significant worsening of water quality. Achieved findings may be critical for supporting water quality policy and management decisions.     

Crystallization and eruption ages of Breccia Museo (Campi Flegrei caldera,Italy) plutonic clasts and their relation to the Campanian ignimbrite

The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km³ Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km² in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI ⁴⁰Ar/³⁹Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated ⁴⁰Ar/³⁹Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.     

Fluid–rock interactions associated with regional tectonics and basin evolution

An integrated approach consisting of fracture analysis, petrography, carbon, oxygen and strontium‐isotope analyses, as well as fluid‐inclusion micro‐thermometry, led to a better understanding of the evolution of fluid–rock interactions and diagenesis of the Upper Permian to Upper Triassic carbonates of the United Arab Emirates. The deposited carbonates were first marked by extensive early dolomitization. During progressive burial, the carbonates were affected by dolomite recrystallization as well as precipitation of vug and fracture‐filling dolomite, quartz and calcite cements. After considerable burial during the Middle Cretaceous, sub‐vertical north–south oriented fractures (F1) were cemented by dolomite derived from mesosaline to hypersaline fluids. Upon the Late Cretaceous maximum burial and ophiolite obduction, sub‐vertical east–west fractures (F2) were cemented by dolomite (Dc2) and saddle dolomite (Ds) derived from hot, highly saline fluids. Then, minor quartz cement has precipitated in fractures from hydrothermal brines. Fluid‐inclusion analyses of the various diagenetic phases imply the involvement of increasingly hot (200°C) saline brines (20 to 23% NaCl eq.). Through one‐dimensional burial history numerical modelling, the maximum temperatures reached by the studied rocks are estimated to be in the range of 160 to 200°C. Tectonically‐driven flux of hot fluids and associated diagenetic products are interpreted to have initiated during the Late Cretaceous maximum burial and lasted until the Oligocene–Miocene compressional tectonics and related uplift. The circulation of such hydrothermal brines led to partial dissolution of dolomites (Dc2 and Ds) and to precipitation of hydrothermal calcite C1 in new (mainly oriented north–south; F3) and pre‐existing, reactivated fractures. The integration of the obtained data confirms that the diagenetic evolution was controlled primarily by the interplay of the burial thermal evolution of the basin and the regional tectonic history. Hence, this contribution highlights the impacts of regional tectonics and basin history on diagenetic processes, which may subsequently affect reservoir properties.     

The Purpose and Age of Underwater Walls in the Bay of Elaia of Western Turkey: A Multidisciplinary Approach

Pergamum (modern: Bergama) was operating an important harbour used by military forces and merchants at the city of Elaia during Hellenistic and Roman Imperial times. Harbour‐related facilities such as warehouses, breakwaters and wharfs document the importance of this harbour site not only for the Pergamenians. This paper focuses on the purpose and age of six submerged wall structures situated approximately 1 km south of the ancient closed harbour basin of Elaia. Geoelectric cross‐sections and semi‐aquatic coring near these walls failed to detect any solid basement under the walls which excludes their possible use as breakwaters or wharfs. Instead, the walls were most likely delineating and separating evaporation ponds of salt works, which compares well with similar structures from other periods and places around the Mediterranean. Combined OSL and ¹⁴C‐dating determined the construction age of the installation between the 4th and 6th centuries A.D. Subsequent (re‐)uses are likely and are in agreement with findings from archaeological surveys.     

Estimating Sensible and Latent Heat Fluxes over an Inland Water Body Using Optical and Microwave Scintillometers

Boundary-Layer Meteorology - Observations of turbulent heat fluxes over inland water bodies are scarce despite being critical to adequate lake parametrization for numerical weather forecast and...     

Correction to: Evaluation of a multi-model approach to estimate leaf wetness duration: an essential input for disease alert systems

Theoretical and Applied Climatology -     

Coastal margin evolution and postulated “basin‐shipyard” area at ancient Locri‐Epizephiri,Calabria, Italy

Environmental settings on the Ionian coastal plain and inner shelf seaward of Locri‐Epizephiri in Calabria, Italy, differed markedly before, during, and following settlement by the Greeks. Sediment core analyses and geophysical surveys in this study support recent archaeological findings and the hypothesis that the margin may once have served as a harbor and/or shipyard. The subsurface Holocene stratigraphy records that (1) the shoreline advanced to a maximum landward position before Greek settlement, then regressed offshore to what is now the inner shelf before once again migrating landward. These marked coastal shifts were triggered primarily by land uplift and probable subsidence offshore along this structurally active Calabrian Arc segment. Associated with this are: (2) a sediment fining‐upward sequence in Greek–Roman time that indicates only partial protection of the coastal area, and (3) possible presence of subsurface structures seaward of the city wall in a sector now positioned ∼200 m offshore. © 2010 Wiley Periodicals, Inc.     

A remarkable example of a Late Jurassic shallow-water ophiuroid assemblage from the Swiss Jura Mountains

Although much effort has been put into attempts to unravel the Mesozoic ophiuroid fossil record, surprisingly little attention has been paid to the geological history of family-level compositions of brittle star assemblages. Here, we describe new ophiuroid material from the Late Oxfordian Bure Member as exposed in a construction site along the federal Highway A16 (Transjurane Highway) near Boncourt–Queue au Loup (Swiss Jura Mountains). The remains are exceptionally well preserved and partially articulated, enabling detailed morphological observations at a level comparable to Recent material. Three species are identified; they are here shown to display unequivocal affinities with extant ophiuroid lineages. The assemblage comprises a new ophiacanthid genus and species, Juracantha hottingeri, which is closely related to extant Ophientrema, an ophiolepidid close to extant Ophiozonella described here as a new genus and species, Eozonella bergeri, and a species previously described as Ophiacantha? francojurassica, which is here reassigned to the extant ophionereidid genus Ophiodoris. The assemblage was found in association with Nanogyra oyster buildups encrusted by serpulids and associated with partially-articulated crinoids, deposited in a shallow subtidal setting. Its family level composition is highly unusual with respect to modern equivalents, and instead is reminiscent of modern bathyal assemblages.     

Dynamic limits on planar libration-orbit coupling around an oblate primary

This paper explores the dynamic properties of the planar system of an ellipsoidal satellite in an equatorial orbit about an oblate primary. In particular, we investigate the conditions for which the satellite is bound in librational motion or when the satellite will circulate with respect to the primary. We find the existence of stable equilibrium points about which the satellite can librate, and explore both the linearized and non-linear dynamics around these points. Absolute bounds are placed on the phase space of the libration-orbit coupling through the use of zero-velocity curves that exist in the system. These zero-velocity curves are used to derive a sufficient condition for when the satellite’s libration is bound to less than $90^{\circ }$ . When this condition is not satisfied so that circulation of the satellite is possible, the initial conditions at zero libration angle are determined which lead to circulation of the satellite. Exact analytical conditions for circulation and the maximum libration angle are derived for the case of a small satellite in orbits of any eccentricity.