Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

全数字摄影测量系统DEM生产的质量控制

目前,数字高程模型(DEM)在理论研究和实践应用方面都有了很大的进展,已在测绘、地质、农业、工程、建筑、军事、导航等多个领域得到了广泛应用,因此高效快捷地生产高精度的DEM是十分必要和迫切的。全数字摄影测量系统DEM生产方案是解决这一问题的有效途径,文章针对该系统的特点,提出了加强质量控制的策略和方法,并阐述了对一些实践问题的解决。     

地震波混合阶褶积算法模拟

基于正反傅立叶变换,提出了地震波模拟的混合阶褶积算法。该方法原理简单、易于实现,结合了有限差分与伪谱法的优点,具有较高的精度和计算效率,适用于地震波场的正演计算,同时还给出了二维地震波场的理论计算实例。计算结果表明,此算法模拟结果正确、精度高、速度快、能适应较为复杂地质模型,并且易于推广到各向异性介质中去。     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

甘肃北山造山带红石山地区正εNd(t)值花岗质岩石的成因及地质意义

在1：5万红岭幅等3幅区域地质调查中，对晚古生代中酸性侵入岩和火山岩的Sm—Nd同位素研究表明，这些不同时代、不同类型的岩石，均表现出高的正εNd（t）值和较低的TDM值，而且变化范围很小，揭示该区花岗质岩石的源岩同位素成分均一，且主要来源于地幔。正εNd（t）值花岗质岩石的存在，可能对研究大陆地壳生长具有重要意义。     

葛洲坝水利枢纽运行后泥沙冲淤变化分析

对葛洲坝水利枢纽及其运行情况和河段特性进行了介绍。分析认为葛洲坝水利枢纽运行前后的入库水沙特性基本一致。探讨了库区冲淤变化特点、淤积量及其分布,冲淤过程及达到冲淤平衡的时间。对坝下游河床的冲淤过程、冲淤量、达到冲淤平衡的时间以及河床粗化,河底高程历年变化及同流量水位降低的原因、降低量及变化过程进行了分析总结。研究结果可为进一步探讨三峡水利枢纽与葛洲坝水利枢纽联合调度运用后水库泥沙淤积变化规律提供参考。     

三峡深水高土石围堰工程的渗流研究

为了对三峡工程二期高土石围堰防渗设施的布置方案及其阻渗效果进行比较,采用有限元法对二期高土石围堰在不利的运行工况下的渗流场进行数值分析.比较了双排混凝土防渗墙方案、单排塑性混凝土低防渗墙加土工膜斜墙和单排厚塑性混凝土防渗墙等3种方案,分别采用恒定与非恒定模型计算,对立面二维和三维绕渗及防渗墙局部开裂等不利工况分别进行了数值模拟.结果表明:三方案均可有效抑制渗流场,双排混凝土防渗墙的防渗效果最好;墙体的局部开裂仅对局部区域的流场有影响.非恒定数值分析表明,堰体、基础不均匀沙石料及基坑抽水速度对渗流场影响极大,为保证堰体稳定,应限制基坑水位降落速度小于2 m/d.     

土钉墙技术在长春市北方大厦基坑工程中的应用实践

结俣长春市北方大厦基坑支护工程实际，着重介绍了土钉墙支护方案的设计，施工及应用情况，为土钉墙支护技术在长春市深基开挖工程中的推广应用积累了经验。