Laboratory study of self-potential signals during releasing of CO2 and N2 plumes

Carbon Capture Sequestration (CCS) projects require, for safety reasons, monitoring programmes focused on surveying gas leakage on the surface. Generally, these programmes include detection of chemical tracers that, once on the surface, could be associated with CO₂ degassing. We take a different approach by analysing feasibility of applying electrical surface techniques, specifically Self-Potential. A laboratory-scale model, using water-sand, was built for simulating a leakage scenario being monitored with non-polarisable electrodes. Electrical potentials were measured before, during and after gas injection (CO₂ and N₂) to determine if gas leakage is detectable. Variations of settings were done for assessing how the electrical potentials changed according to size of electrodes, distance from electrodes to the gas source, and type of gas. Results indicated that a degassing event is indeed detectable on electrodes located above injection source. Although the amount of gas could not be quantified from signals, injection timespan and increasing of injection rate were identified. Even though conditions of experiments were highly controlled contrasting to those usually found at field scale, we project that Self-Potential is a promising tool for detecting CO₂ leakage if electrodes are properly placed.     

Spectral characteristics of rocks: Effects of composition and texture and implications for the interpretation of planet surface compositions

In spectroscopic remote sensing for the exploration of the surface compositions of Earth and terrestrial planets, reflectance spectra with very low spectral contrast and even devoid of diagnostic absorption bands can be observed, which make the interpretation of the component minerals ambiguous. Using selected examples of terrestrial rock samples from intrusive and effusive geologic systems, we discuss compositional and textural properties related to these particular spectral shapes. We show that: (1) this spectral behaviour is common for coarse grains of multimineral rocks, where the optical coupling is expected to occur between welded mineral particles; (2) it is emphasised by the presence of opaque minerals with various compositions, such as ulvospinel, magnetite and chromite in effusive rock groundmass and in intrusive rocks; (3) it is controlled by the number of silicate phases within which the FeO is distributed, irrespective of the total iron content in the rock: a rock composition with a high number of iron-bearing minerals producing this kind of low contrast, almost featureless spectra is indicated here as “critical mode”; (4) it is also strongly intensified by aqueous alteration of silicates.These observations suggest unpredictable combinations of several different petrographic variables affecting the spectra of some compact rocks, and stimulate both targeted studies to quantitatively relate spectral and petrographic parameters, and the development of appropriate methods of spectral decomposition. Our ongoing work is at present focused on the spectroscopic effects of the FeO concentration in transparent neutral plagioclase, the different compositions of the opaque neutral minerals, and the iron bearing amorphous phases.We also discuss the analogy between the rocks used in the analysis reported here and the crustal rock compositions observed on Mars and inferred for Mercury as well as the compatibility of the factors responsible for the low spectral contrast of terrestrial rock samples with the factors expected for the two planets. We observe that a coarse-grained surface and a composition approaching a critical mode could explain the featureless Acidalia spectra on Mars, and suggest that the still open questions about Mercury’s surface regolith characteristics and composition do not exclude a priori the contribution of some of the factors examined in this paper to the peculiar surface properties of this planet.     

Anisotropic dark energy stars

A model of compact object coupled to inhomogeneous anisotropic dark energy is studied. It is assumed a variable dark energy that suffers a phase transition at a critical density. The anisotropic Λ-Tolman-Oppenheimer-Volkoff equations are integrated to know the structure of these objects. The anisotropy is concentrated on a thin shell where the phase transition takes place, while the rest of the star remains isotropic. The family of solutions obtained depends on the coupling parameter between the dark energy and the fermionic matter. The solutions share several features in common with the gravastar model. There is a critical coupling parameter that gives non-singular black hole solutions. The mass-radius relations are studied as well as the internal structure of the compact objects. The hydrodynamic stability of the models is analyzed using a standard test from the mass-radius relation. For each permissible value of the coupling parameter there is a maximum mass, so the existence of black holes is unavoidable within this model.     

Relationships between bioturbation by Tylos spinulosus (Crustacea, Isopoda) and its distribution on sandy beaches of north-central Chile

The semi-terrestrial isopod, Tylos spinulosus Dana, is a common inhabitant of the upper shore levels of sandy beaches of north-central Chile (ca. 26–30°S). During daylight hours, this isopod remains buried in the sand, while during the night emerges for feeding on stranded organic detritus, leaving exit holes on the beach surface. After feeding, isopods return to dig in their burrowing zones leaving surface irregularities such as cone-shaped mounds of sand. The burrowing preference of T. spinulosus was studied in the field, by: (i) releasing 30 isopods on artificially prepared sand circles (2 m diameter) having exit holes and mounds similar to those left by the isopods and on circles without holes and mounds, and (ii) counting active and buried isopods 15 min after their release in the experimental arenas. The circles had two densities of holes and mounds: treatments 1 and 2 had 100 and 200 holes, respectively, while treatments 3 and 4 had 100 and 200 mounds, respectively. Other 30 isopods were released on sand circles without these holes and mounds (treatment 5). A significantly higher number of isopods buried in circles with holes and mounds (either inside or outside them), compared with experimental arenas without such structures. These results show that the beach surface heterogeneity resulting from holes and mounds would be one of the processes explaining the patchiness of T. spinulosus and thus, its zonation on the intertidal zones of sandy beaches of north-central Chile.     

Accuracy and sensitivity analysis for 54 models of computing hourly diffuse solar irradiation on clear sky

Fifty-four broadband models for computation of solar diffuse irradiation on horizontal surface were tested in Romania (South-Eastern Europe). The input data consist of surface meteorological data, column integrated data, and data derived from satellite measurements. The testing procedure is performed in 21 stages intended to provide information about the sensitivity of the models to various sets of input data. There is no model to be ranked “the best” for all sets of input data. However, some of the models performed better than others, in the sense that they were ranked among the best for most of the testing stages. The best models for solar diffuse radiation computation are, on equal footing, ASHRAE 2005 model (ASHRAE 2005) and King model (King and Buckius, Solar Energy 22:297–301, 1979). The second best model is MAC model (Davies, Bound Layer Meteor 9:33–52, 1975). Details about the performance of each model in the 21 testing stages are found in the Electronic Supplementary Material.     

Provenance analysis as a key to orogenic exhumation: a case study from the East Carpathians (Romania)

Provenance analysis of the sediments from foredeep basins is crucial in understanding the contemporaneous orogenic exhumation processes. We report in this paper complex sediment provenance analysis using sandstone petrography and mudstone geochemistry, combined with magnetic susceptibility of the Upper Miocene to Pliocene deposits from Focşani foredeep basin (Romania). Data show a change of source area between 5 and 6 Ma, from an active volcanic arc towards a recycled orogenic belt, concurrent with an important increase of accumulation rate. This change was triggered by exhumation and erosion of the outer nappes from East Carpathians.     

Lavoisierite, Mn2+ 8[Al10(Mn3+Mg)][Si11P]O44(OH)12, a new mineral from Piedmont, Italy: the link between “ardennite” and sursassite

The new mineral species lavoisierite, ideally Mn²⁺ ₈[Al₁₀(Mn³⁺Mg)][Si₁₁P]O₄₄(OH)₁₂, has been discovered in piemontite-bearing micaschists belonging to the Piedmontese Nappe from Punta Gensane, Viù Valley, Western Alps, Italy. It occurs as yellow-orange acicular to prismatic-tabular crystals up to a few millimeters in length, with white streak and vitreous luster, elongated along [010] and flattened on {001}. Lavoisierite is associated with quartz, “mica,” sursassite, piemontite, spessartine, braunite, and “tourmaline.” Calculated density is 3.576 g cm^?3. In plane-polarized light, it is transparent, pleochroic, with pale yellow parallel to [010] and yellow-orange normal to this direction; extinction is parallel and elongation is positive. Birefringence is moderate; the calculated average refraction index n is 1.750. Lavoisierite is orthorhombic, space group Pnmm, with a 8.6891(10), b 5.7755(3), c 36.9504(20) Å, V 1854.3(2) Å³, Z = 2. Calculated main diffraction lines of the X-ray powder diffraction pattern are [d in Å, (I), (hkl); relative intensities are visually estimated]: 4.62 (m) (112), 2.931 (vs) (1110), 2.765 (s) (1111), 2.598 (s) (310), 2.448 (ms) (028). Chemical analyses by electron microprobe give (in wt%) P₂O₅ 2.08, V₂O₅ 0.37, SiO₂ 34.81, TiO₂ 0.13, Al₂O₃ 22.92, Cr₂O₃ 0.32, Fe₂O₃ 0.86, Mn₂O₃ 6.92, MnO 19.09, MgO 5.73, CaO 1.94, Na₂O 0.01, H₂O 5.44, sum 100.62 wt%. H₂O content was calculated from structure refinement. The empirical formula, based on 56 anions, is (Mn _5.340 ²⁺ Mg_1.810Ca_0.686Na_0.006)_Σ=7.852(Al_8.921Mn _1.739 ³⁺ Mg_1.010Fe _0.214 ³⁺ Cr_0.084Ti_0.032)_Σ=12.000(Si_11.496P_0.582V_0.081)_Σ=12.159O_43.995(OH)_12.005. The crystal structure of lavoisierite was solved by direct methods and refined on the basis of 1743 observed reflections to R ₁ = 4.6 %. The structure is characterized by columns of edge-sharing octahedra running along [010] and linked to each other by means of [SiO₄], [Si₂O₇], and [Si₃O₁₀] groups. Lavoisierite, named after the French chemist and biologist Antoine-Laurent de Lavoisier (1743–1794), displays an unprecedented kind of structure, related to those of “ardennite” and sursassite.     

Tidal evolution of close-in exoplanets in co-orbital configurations

In this paper, we study the behavior of a pair of co-orbital planets, both orbiting a central star on the same plane and undergoing tidal interactions. Our goal is to investigate final orbital configurations of the planets, initially involved in the 1/1 mean-motion resonance (MMR), after long-lasting tidal evolution. The study is done in the form of purely numerical simulations of the exact equations of motions accounting for gravitational and tidal forces. The results obtained show that, at least for equal mass planets, the combined effects of the resonant and tidal interactions provoke the orbital instability of the system, often resulting in collision between the planets. We first discuss the case of two hot-super-Earth planets, whose orbital dynamics can be easily understood in the frame of our semi-analytical model of the 1/1 MMR. Systems consisting of two hot-Saturn planets are also briefly discussed.     

Spatio-temporal patterns of the interaction between groundwater and surface water in plains

The study of the dynamics of anthropic disturbances that have an effect on the hydrological systems in plains requires integral simulation tools for their diagnosis. The objective of this article is, first, to analyse and reproduce the spatio-temporal interactions between groundwater (GW) and surface water, net recharge, GW level, surface run-off, and evapotranspiration in the upper creek basin of Del Azul, which is located in the centre of the province of Buenos Aires, Argentina, and second, to obtain insights to apply the methodology to other similar situations. For this purpose, a model coupling the semidistributed hydrological model (Soil and Water Assessment Tool [SWAT]) and the hydrogeological model (MODFLOW) has been used. A simulation was carried out for a period of 13 years (2003–2015) on a daily scale. The application of the SWAT–MODFLOW coupling gave good results based on the adjustment between the calculated flows and levels, reaching a Nash–Sutcliffe of 0.6 and R²0.6 at the Seminario hydrometric station located at the watershed outlet point. According to the annual average balance, out of the total rainfall, evapotranspiration accounts for 85%, recharge accounts for 10.2%, and surface run-off accounts for 4.8%. Annual and monthly trends of the stream–aquifer interaction were determined, obtaining on average an annual GW discharge of 34 mm and an annual average recharge of the stream to the aquifer of 1.4 mm. Monthly GW discharges are higher in winter–spring (July to December with an average of 3.3 mm) and lower in summer–autumn (January to June with an average of 2.8 mm). The monthly average recharge of the stream towards the aquifer varies from 0.02 to 0.36 mm and is higher in March, May, and August, when water excess is produced in the basin. Through the analysis of coupled modelling, it is possible to analyse and reproduce the spatio-temporal transitions of flow existing between the stream, the hyporheic zone, and the aquifer.