Maturation related changes in the distribution of ester bound fatty acids and alcohols in a coal series from the New Zealand Coal Band covering diagenetic to catagenetic coalification levels

A rank series of lignites and coals of low to moderate maturation levels (vitrinite reflectance (R₀): 0.27–0.8%) from the New Zealand Coal Band were investigated using alkaline ester cleavage experiments to reveal compositional changes of ester bound components (fatty acids and alcohols) during increasing maturation. Ester bound alcohols are found to be present in highest amounts in the very immature lignite samples (R₀: 0.27–0.29%), but show a rapid decrease during early diagenesis. Ester bound fatty acids also show an initial exponential decrease during diagenesis, but reveal an intermittent increase during early catagenesis before decreasing again during main catagenesis. This intermittent increase was related to the short chain fatty acids. To obtain a maturity related signal and to eliminate facies related scattering in the amounts of fatty acids in the coal samples, the carbon preference index of fatty acids (CPI_FA) parameter is introduced here. For the long chain fatty acids (C₂₀–C₃₂) originating from terrigenous plant debris, the CPI_FA decreases with increasing maturity, showing a strong maturation related signal. During diagenesis, the same trend can be observed for the short chain fatty acids, but the intermittent increase in the amounts of short chain fatty acids is also accompanied by high CPI_FA values. This indicates less altered organic biomass at this advanced maturation level and is in contrast to the mature CPI_FA signal of the long chain fatty acids of the same samples. One possible reason for this discrepancy could be extremely different amounts of short and long chain fatty acids in the original source organic matter of these samples. However, another intriguing explanation could be the incorporation of immature bacterial biomass from deep microbial communities containing C₁₆ and C₁₈ fatty acids as main cell membrane components. Deep microbial life might be stimulated at this interval by the increasing release of thermally generated potential substrates from the organic matrix during early catagenesis. In contrast to the fatty acids, the high amounts of alcohols in the immature lignite samples are also visible in the alkene distribution from the open system pyrolysis experiments of the organic matrix before and after saponification.     

A novel procedure to detect low molecular weight compounds released by alkaline ester cleavage from low maturity coals to assess its feedstock potential for deep microbial life

In recent years the widespread occurrence of microorganisms was demonstrated in deep marine and terrestrial sediments. With this discovery inevitably the question of the potential carbon and energy sources for this deep subsurface microbial life arises. In the current study a new method for the investigation of low molecular weight (LMW) organic acids linked to the kerogen matrix is presented. These LMW organic acids form a potential feedstock for deep microbial populations. Twelve coal samples of different maturity (vitrinite reflectance (R₀) of 0.28–0.80%) from several coal mines on the North and South Island of New Zealand (NZ) were examined to assess the amount of bound LMW organic acids. Formate, acetate and oxalate were detected in significant amounts whereas the amounts of these compounds decrease with increasing maturity of the coal sample. This decrease of LMW organic acids mainly correlates to the phase of diagenetic alteration of the organic matter characterized by the release of oxygen containing compounds. Concomitantly, it coincides with temperature conditions assumed to be still compatible with microbial life in the deep subsurface. First assessments of the feedstock potential and generation rates of LMW organic acids indicate that the NZ coals investigated exhibit the potential to feed deep terrestrial microbial life with appropriate substrates over geological time spans.     

Environmental Radioxenon Levels in Europe: a Comprehensive Overview

Activity concentration data from ambient radioxenon measurements in ground level air, which were carried out in Europe in the framework of the International Noble Gas Experiment (INGE) in support of the development and build-up of a radioxenon monitoring network for the Comprehensive Nuclear-Test-Ban Treaty verification regime are presented and discussed. Six measurement stations provided data from 5 years of measurements performed between 2003 and 2008: Longyearbyen (Spitsbergen, Norway), Stockholm (Sweden), Dubna (Russian Federation), Schauinsland Mountain (Germany), Bruyères-le-Châtel and Marseille (both France). The noble gas systems used within the INGE are designed to continuously measure low concentrations of the four radioxenon isotopes which are most relevant for detection of nuclear explosions: ^131mXe, ^133mXe, ¹³³Xe and ¹³⁵Xe with a time resolution less than or equal to 24 h and a minimum detectable concentration of ¹³³Xe less than 1 mBq/m³. This European cluster of six stations is particularly interesting because it is highly influenced by a high density of nuclear power reactors and some radiopharmaceutical production facilities. The activity concentrations at the European INGE stations are studied to characterise the influence of civilian releases, to be able to distinguish them from possible nuclear explosions. It was found that the mean activity concentration of the most frequently detected isotope, ¹³³Xe, was 5–20 mBq/m³ within Central Europe where most nuclear installations are situated (Bruyères-le-Châtel and Schauinsland), 1.4–2.4 mBq/m³ just outside that region (Stockholm, Dubna and Marseille) and 0.2 mBq/m³ in the remote polar station of Spitsbergen. No seasonal trends could be observed from the data. Two interesting events have been examined and their source regions have been identified using atmospheric backtracking methods that deploy Lagrangian particle dispersion modelling and inversion techniques. The results are consistent with known releases of a radiopharmaceutical facility.     

Pressure-specific and multiple pressure response of fish assemblages in European running waters

We classified homogenous river types across Europe and searched for fish metrics qualified to show responses to specific pressures (hydromorphological pressures or water quality pressures) vs. multiple pressures in these river types. We analysed fish taxa lists from 3105 sites in 16 ecoregions and 14 countries. Sites were pre-classified for 15 selected pressures to separate unimpacted from impacted sites. Hierarchical cluster analysis was used to split unimpacted sites into four homogenous river types based on species composition and geographical location. Classification trees were employed to predict associated river types for impacted sites with four environmental variables. We defined a set of 129 candidate fish metrics to select the best reacting metrics for each river type. The candidate metrics represented tolerances/intolerances of species associated with six metric types: habitat, migration, water quality sensitivity, reproduction, trophic level and biodiversity. The results showed that 17 uncorrelated metrics reacted to pressures in the four river types. Metrics responded specifically to water quality pressures and hydromorphological pressures in three river types and to multiple pressures in all river types. Four metrics associated with water quality sensitivity showed a significant reaction in up to three river types, whereas 13 metrics were specific to individual river types. Our results contribute to the better understanding of fish assemblage response to human pressures at a pan-European scale. The results are especially important for European river management and restoration, as it is necessary to uncover underlying processes and effects of human pressures on aquatic communities.     

Nuclear and incommensurate magnetic structure of NaFeGe2O6 between 5?K and 298?K and new data on multiferroic NaFeSi2O6

The compound NaFeGe₂O₆ was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe₂O₆ is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO₄ tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe₂O₆ transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO₆ octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe₂O₆ with NaFeSi₂O₆ is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.     

Surface motion in the pulsating DA white dwarf G29‐38

We present time-resolved spectrophotometry of the pulsating DA white dwarf G29-38. As in previous broad-band photometry, the light curve shows the presence of a large number of periodicities. Many of these are combination frequencies, i.e. periodicities occurring at frequencies that are sums or differences of frequencies of stronger, real modes. We identify at least six real modes, and at least five combination frequencies. We measure line-of-sight velocities for our spectra and detect periodic variations at the frequencies of five of the six real modes, with amplitudes of up to 5 km s⁻¹. We argue that these variations reflect the horizontal surface motion associated with the g-mode pulsations. No velocity signals are detected at any of the combination frequencies, confirming that the flux variations at these frequencies do not reflect physical pulsation, but rather reflect mixing of frequencies owing to a non-linear transformation in the outer layers of the star. We discuss the amplitude ratios and phase differences found for the velocity and light variations, as well as those found for the real modes and their combination frequencies, both in a model-independent way and in the context of models based on the convective-driving mechanism. In a companion paper, we use the wavelength dependence of the amplitudes of the modes to infer their spherical degree.     

Rapid decrease of soil erosion rates with soil formation and vegetation development in periglacial areas

High mountainous areas are geomorphologically active environments which are strongly shaped by redistribution of sediments and soils. With the projected climate warming in the twenty-first century and the continued retreat of glaciers, the area of newly exposed, highly erodible sediments and soils will increase. This presents a need to better understand and quantify erosion processes in young mountainous soils, as an increase in erodibility could threaten human infrastructure (i.e. hydroelectric power, tourist installations and settlements). While soil development is increasingly well understood and quantified, a coupling to soil erosion rates is still missing. The aim of this study was, therefore, to assess how soil erosion rates change with surface age. We investigated two moraine chronosequences in the Swiss Alps: one in the siliceous periglacial area of Steingletscher (Sustenpass), with soils ranging from 30 a to 10 ka, and the other in the calcareous periglacial area of Griessgletscher (Klausenpass) with surfaces ranging from age of 110 a to 13.5 ka. We quantified the erosion rates using the ^239+240Pu fallout radionuclides and compared them to physical and chemical soil properties and the vegetation coverage. We found no significant differences between the two parent materials. At both chronosequences, the erosion rates were highest in the young soils (on average 5−10 t ha^-1 a^-1 soil loss). Erosion rates decreased markedly after 3−5 ka of soil development (on average 1−2.5 t ha^-1 a^-1 soil loss) to reach a more or less stable situation after 10−14 ka (on average 0.3–2 t ha^-1 a^-1). Climate change not only causes glacier retreat, but also increased sediment dynamics. Depending on the relief and vegetational development, it takes up to at least 10 ka to reach soil stability. The establishment of a closed vegetation cover with dense root networks seems to be the controlling factor in the reduction of soil erodibility. © 2020 John Wiley & Sons, Ltd.     

Late Quaternary record of Indian summer monsoon-induced stratification and productivity collapse in the Andaman Sea

During each summer monsoon, the northeastern Indian Ocean receives a huge amount of rain and river discharge, resulting in strong stratification and prevalence of oligotrophic conditions. These water column changes impact upper ocean productivity which is reflected in the planktonic foraminifera distribution, providing an opportunity to study the effect of monsoon forcing and stratification history. Analogous to modern-day stratification, very intense water column stratification and productivity collapse were observed associated with Indian summer monsoon (ISM) evolution. This paper reports significant stratification events during MIS 3 (37.0 to 33 and 27 to 24 cal ka), Bølling/Allerød (B/A), early Holocene (10.0 to 8.0 cal ka) and mid-Holocene (7.0 to 5.0 cal ka) which slowly muted upwelling and productivity. The deglacial intensification of the ISM started in the early stages of the Bølling/Allerød (B/A) followed by slight weakening during the Younger Dryas and regained strength during the early Holocene, coinciding with the highest summer insolation at 30°N. A progressive decline in the abundances of productivity and salinity proxies from 4.2 to 2.0 cal ka suggests a gradual weakening of the ISM. The late Quaternary productivity variations in the Bay of Bengal and the Andaman Sea are primarily controlled by salinity-related stratification.