On 50th Anniversary of the Global Carbon Dioxide Record

The 50-year global CO₂ record led the way in establishing a scientific fact: modern civilization is changing important properties of the global atmosphere, oceans and biosphere. The evidence on which this scientific fact is based will be refined further, but the next challenge for scientists is broader. In addition to its traditional role in providing discovery, diagnosis, and prediction of the changes that are taking place on our planet, science has now also a role in helping society mitigate emissions by objectively quantifying them, and in helping adaptation by providing environmental forecasts on regional scales. Science is also expected to provide new options for society to tackle the transition to a new energy system, and to provide thorough environmental evaluation of all such options. This is what the meeting recognized as planetary responsibilities for scientists in the next 50 years.     

紫硫镍矿交代镍黄铁矿的水热反应机理及动力学

本工作首次在实验室条件下对浅生区紫硫镍矿(Ni,Fe)3S4交代镍黄铁矿(Ni,Fe)9S8水热反应的机理及动力学进行了研究。起始反应矿物采用高纯自然镍黄铁矿,合成纯镍黄铁矿或合成镍黄铁矿-磁黄铁矿集合体。反应pH值采用0.2M醋酸-醋酸纳缓冲溶液控制在3～5的范围内。反应进程由X-射线衍射物相定量分析及扫描电镜观察进行跟踪。结果表明,当反应温度恒定在80℃时,交代20(4)%的镍黄铁矿需792h。相同条件下加入少量H2S可将反应速率提高一倍。当反应在125℃饱和蒸汽压水热环境下进行时,完全交代纯镍黄铁矿需约168h。此过程由于磁黄铁矿的存在而被催化,交代集合体中的镍黄铁矿仅需68h,进一步反应磁黄铁矿被交代成白铁矿。磁黄铁矿的催化作用可能源于溶解产生的微裂纹加速了流体的传质过程。当反应温度升高至145℃时,速率反而下降,不遵循Arrhenius经验规律。动力学分析得80℃速率常数介于5.8×10-8～3.0×10-7/s之间,125℃及145℃速率常数分别介于2.8×10-6～2.08×10-5/s及1×10-6～5.1×10-6/s之间,远高于同温度下固相扩散反应的速率常数,表明该反应在地质时标上为一快速反应。此外,用背散射电子显微技术对矿物表面形貌进行了分析,发现交代产物紫硫镍矿具有颗粒细小及存在微裂纹等特征,与自然界浅生矿床中的紫硫镍矿非常相似;电镜实验还表明该交代作用是一个典型的耦合溶解-再沉淀反应。其耦合机制的驱动力可能与反应界面处微空隙对流体饱和度的控制有关。     

Assessing the vulnerability of food crop systems in Africa to climate change

Africa is thought to be the region most vulnerable to the impacts of climate variability and change. Agriculture plays a dominant role in supporting rural livelihoods and economic growth over most of Africa. Three aspects of the vulnerability of food crop systems to climate change in Africa are discussed: the assessment of the sensitivity of crops to variability in climate, the adaptive capacity of farmers, and the role of institutions in adapting to climate change. The magnitude of projected impacts of climate change on food crops in Africa varies widely among different studies. These differences arise from the variety of climate and crop models used, and the different techniques used to match the scale of climate model output to that needed by crop models. Most studies show a negative impact of climate change on crop productivity in Africa. Farmers have proved highly adaptable in the past to short- and long-term variations in climate and in their environment. Key to the ability of farmers to adapt to climate variability and change will be access to relevant knowledge and information. It is important that governments put in place institutional and macro-economic conditions that support and facilitate adaptation and resilience to climate change at local, national and transnational level.     

Full-scale structural monitoring using an integrated GPS and accelerometer system

Accurate in situ measurement of the full-scale structural responses, especially tall buildings, under severe loading conditions is an important requirement for validating their design, evaluating their construction as well as facilitating their maintenance. Traditionally such response has been measured using accelerometers. However, it is impossible to measure the static and quasi-static components of motion with acceleration sensors. An integrated system comprising of RTK-GPS and accelerometers has been developed with the objective of assessing full-scale structural responses by exploiting the complementary characteristics of GPS and accelerometer sensors. The data used in this paper were obtained from GPS and accelerometer sensors installed on a 108-m-high steel tower in Tokyo, together with other sensors such as anemometer and strain gauge. The seismic and wind-induced responses of the tower were analyzed using the Fast Fourier Transformation (FFT) and compared to results from finite element modeling (FEM). In order to study the system reliability, the correlated signals were extracted by applying a digital filtering technique. Then the filtered data sets were converted to displacement (in the case of accelerometer data) and acceleration (in the case of GPS data) through double integration and double differentiation, respectively, for the purpose of direct comparison and to further fuse data from the two different sensors. The results agree with each other very well, although the static and quasi-static components are missing from the accelerometer-derived results. The redundancy of the monitoring system therefore has been achieved.     

A note on a property of pulasting stars

An explanation for the observed correlation between the ratio (relative amplitude of flux variation)/(relative amplitude of radius variation) and the period of radial pulsation in cepheids is proposed. If the explanation is correct, correlations may be expected for other classes of pulsating stars with the general functional form determined by physical conditions in the atmosphere.     

Herbicides implicated as the cause of severe mangrove dieback in the Mackay region, NE Australia: consequences for marine plant habitats of the GBR World Heritage Area

Herbicides, particularly diuron, were correlated with severe and widespread dieback of the dominant mangrove, Avicennia marina (Forsk.) Vierh. var. eucalyptifolia (Val.) N.C. Duke (Avicenniaceae), its reduced canopy condition, and declines in seedling health within three neighbouring estuaries in the Mackay region of NE Australia. This unusual species-specific dieback, first observed in the early 1990s, had gotten notably worse by 2002 to affect >30 km(2) of mangroves in at least five adjacent estuaries in the region. Over the past century, agricultural production has responded well to the demands of increasing population with improvements in farm efficiency assisted by significant increases in the use of agricultural chemicals. However, with regular and episodic river flow events, these chemicals have sometimes found their way into estuarine and nearshore water and sediments where their effects on marine habitats have been largely unquantified. Investigations over the last three years in the Mackay region provide compelling evidence of diuron, and possibly other agricultural herbicides, as the most likely cause of the severe and widespread mangrove dieback. The likely consequences of such dieback included declines in coastal water quality with increased turbidity, nutrients and sediment deposition, as well as further dispersal of the toxic chemicals. The implications of such findings are immense since they describe not only the serious deterioration of protected and beneficial mangrove habitat but also the potential for significant direct and indirect effects on other highly-valued estuarine and marine habitats in the region, including seagrass beds and coral reefs of the Great Barrier Reef lagoon. This article reviews all key findings and observations to date and describes the essential correlative and causative evidence.     

新疆叶城晚新生代山前盆地演化与高原北缘的隆升—Ⅰ地层学与岩石学证据

叶城晚新生代山前盆地的岩性主要由中新世的细粒泥岩和砂岩（乌恰群）,上新世的砂岩夹薄层砾岩（阿图什组）及上新世－更新世的粗粒砾岩（西域组）构成。中新世的沉积以细颗粒泥砂岩为主,表明物源区较远,古流域坡度较小,搬运距离较长。古流向分析显示物源区位于南和偏南方,此时昆仑山的地势起伏尚不大。到上新世的阿图什组沉积时,开始出现砾石沉积,反映西昆仑山已经开始有规模地隆升。西域砾岩的沉积标志着作为物源区的西昆仑山民有相当的高度,随着山系的隆升,基底岩石被暴露和剥蚀。