Immobilization of copper under an acid leach of colloidal pyrite waste rocks by a fixed-bed column

Colloidal pyrite waste rocks (CPWR) which are mainly composed of colloidal pyrite and siderite widely deposit in sulfide mines in the middle and lower reaches of the Yangtze River belt, China, especially in Tongling City, Anhui Province, China. In this paper, a fixed-bed column was used to investigate the weathering and oxidation of CPWR and its role in immobilizing low-concentration Cu (10 mg L^?1) under weakly acidic leach (pH = 5.0). The experimental results indicated that the breakthrough capacity was around 14.0 mg Cu g^?1 CPWR when Cu²⁺ breakthrough concentration was 0.5 mg L^?1. Sequential extraction of Cu and dithionite–citrate–bicarbonate extraction of free iron in the used CPWR after the column breakthrough indicated that Cu removal by CPWR consisted of the following processes: oxidation of pyrite and dissolution of siderite in CPWR, ferrous oxidation, and adsorption of Cu on ferric (hydr)oxides. This study shows the potential application of CPWR as an effective sorbent for the removal of low-concentration Cu from acid mine drainage.     

Simulating train moving loads in physical model testing of railway infrastructure and its numerical calibration

Ballastless high-speed railways have dynamic performances that are quite different from those of conventional ballasted railways. The essential dynamic characteristics of high-speed railways due to passing train wheels, such as the cyclic effect, moving effect, and speed effect, were put forward and discussed. A full-scale accelerated railway testing platform for ballastless high-speed railways was proposed in this study. The feasibility of the sequential loading method in simulating train moving loads, and the boundary effect of the proposed physical model of ballastless railways, was investigated using three-dimensional finite element models. A full-scale physical model, 5 m long, 15 m wide, and 6 m high, was then established according to practical engineering design methods. Using a sequential loading system composed of eight high-performance hydraulic actuators, loads of a moving train with highest speed of 360 km/h were simulated. Preliminary experimental results of vibration velocities were presented and compared with field measurements of the Wuguang high-speed railway in China. Results showed that the experimental results coincided with the field measurements, demonstrating that the full-scale accelerated railway testing platform can simulate the process of a moving train and realistically reproduce the dynamic behaviors of ballastless high-speed railways.