中国西南岩溶生态系统特征与石漠化综合治理对策

以贵州省为核心的中国西南岩溶区面临双重危机：生态恶劣,石漠化严重;人口贫困,全国1/3强的贫困县分布在该地区。石漠化综合治理需要从岩溶生态系统结构和运行规律出发,重点关注岩溶地下水的开发和可持续利用,水土保持和土壤改良,植被恢复和可适应性的经济植物选择,力求区域生态经济双赢、农民脱贫致富。     

石灰土中秸秆还田降解率及其对土壤肥力的影响

石灰土具有高的有机碳的积累,但营养成分的供给速率偏低,导致土壤贫瘠。本文通过室内模拟实验,研究相同来源玉米秸秆在岩溶土与非岩溶土中的降解情况,对秸秆降解率、土壤理化性质、土壤肥力等进行动态检测,结果表明：（1）总体上岩溶土秸秆降解速率比非岩溶土快。秸秆降解速度最快主要集中在最初60天,之后呈缓慢上升趋势,到98天基本达到平衡。非岩溶土降解峰值出现时间为第42天,岩溶土为第28天,峰值出现时间前者比后者滞后14天。总降解时间持续160天,岩溶土降解率为77%,非岩溶土为75%。（2）秸秆降解期间,土壤pH值前期有下降的趋势,后期慢慢回升,这与秸秆降解过程中不同时期降解产物变化规律相吻合。秸秆还田可以提高土壤肥力,其中速效氮和速效钾含量增加非常明显。（3）与岩溶土相比,全量检测结果显示各肥力指标在非岩溶土含量低,但升幅百分比高;有效态检测结果显示非岩溶土速效磷和速效钾含量高。说明秸秆还田一些营养元素有效态在非岩溶土中更易于释放,而岩溶土由于其土壤质地的特殊性,许多养分被土壤粘土矿物牢固结合,营养元素供给速率慢,但因此也易于养分全量的累积。     

安徽省含山县土地整理耕地质量评价及其变化研究

土地整理是改善土地利用条件,提高土地质量的有效措施,对土地整理后的耕地质量进行评价是土地整理重要工作之一。从耕地质量的内涵和土地整理项目的基本要求出发,选取耕地自然条件和耕地利用条件2个基本因素和12个影响因子,将特尔斐法与层次分析法相结合,确定各因子权重,构建基于土地整理的耕地质量评价指标体系。以安徽省含山县铜闸镇土地整理项目为例,采用传统的土壤调查与3S技术相结合的方法,分析土地整理复垦过程中耕地质量时空格局变化,得出整理前、后耕地质量的级别变化。研究结果表明,通过土地整理,研究区的耕地质量空间分布和级别发生了很大变化,整理后一级、二级、三级质量的土地比整理前分别增加了7.20%,11.95%和0.65%,四级、五级则分别减少了15.65%和4.16%,整理后的耕地质量总体水平是整理前的1.291倍。     

冀东孤山子超基性岩体矿物岩石地球化学及Sr-Nd-Pb同位素特征

孤山子超基性岩体位于华北克拉通北缘,主要由角闪石岩、辉长岩及辉石岩组成。本文通过角闪石、辉石、尖晶石的探针分析,角闪石岩、辉长岩的岩石地球化学及Sr-Nd-Pb同位素测试分析,研究孤山子超基性岩体地质地球化学特征,探讨其形成的构造环境。电子探针结果表明,角闪石属韭闪石亚族,具幔源特性;辉石属透辉石亚族,具弧堆晶岩特点;尖晶石属富Al尖晶石亚族,大量存在于辉石岩中。岩石地球化学及Sr-Nd同位素特征显示,孤山子超基性岩原岩浆几乎不受壳源物质的影响。低Mg#(0.44~0.55)及较高LREE/HREE(6.54~8.34),表明原岩浆分异程度较高。同时,全岩富集LREE、Rb、Sr、Ba等大离子亲石元素,亏损HREE、Cr、Ni、Nb、Ta、Zr、Hf等高场强元素,Sr、Nd同位素比值小,(87Sr/86Sr)ⅰ=0.70398~0.70430,εNd(t)=-1.60~-2.72,指示源岩为富集型地幔。孤山子超基性岩在晚古生代侵位于陆弧以南的沉积盆地中,地球化学特征介于弧堆晶岩和大陆裂谷岩浆岩之间。结合其大地构造背景及地球化学特征来看,孤山子超基性岩体应形成于陆缘弧后方局部伸展环境。     

The most frequent interfaces in olivine aggregates: the GBCD and its importance for grain boundary related processes

Rocks consist of crystal grains separated by grain boundaries that impact the bulk rock properties. Recent studies on metals and ceramics showed that the grain boundary plane orientation is more significant for grain boundary properties than other characteristics such as the sigma value or disorientation (in the Earth’s science community more frequently termed misorientation). We determined the grain boundary character distribution (GBCD) of synthetic and natural polycrystalline olivine, the most abundant mineral of Earth’s upper mantle. We show that grain boundaries of olivine preferentially contain low index planes, in agreement with recent findings on other oxides (e.g. MgO, TiO₂, Al₂O₃ etc.). Furthermore, we find evidence for a preferred orientation relationship of 90° disorientations about the [001] direction forming tilt and twist grain boundaries, as well as a preference for the 60° disorientation about the [100] axis. Our data indicate that the GBCD, which is an intrinsic property of any mineral aggregate, is fundamental for understanding and predicting grain boundary related processes.     

Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin,eastern central Europe

A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km³) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.     

Experimental petrology constraints on the recycling of mafic cumulate: a focus on Cr-spinel from the Rum Eastern Layered Intrusion,Scotland

The ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd decay systems are routinely used to determine garnet (Grt)–whole-rock (WR) ages; however, the ¹⁷⁶Lu–¹⁷⁶Hf age of garnet is typically older than the ¹⁴⁷Sm–¹⁴³Nd age determined from the same aliquots. Here we present experimental data for Lu³⁺ and Hf⁴⁺ diffusion in garnet as functions of temperature, pressure and oxygen fugacity and show that the diffusivity of Hf⁴⁺ in almandine/spessartine garnet is significantly slower than that of Lu³⁺. The diffusive closure temperature (T _C) of Hf⁴⁺ is significantly higher than that of Nd³⁺, and although this property is partly responsible for the observed ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd Grt–WR age discrepancies, the difference between the T _C-s of Lu³⁺ and Hf⁴⁺ could lead to apparent Grt–WR ¹⁷⁶Lu–¹⁷⁶Hf ages that are skewed from the age of Hf⁴⁺ closure in garnet. In addition, the slow diffusivity of Hf⁴⁺ indicates that the bulk of metamorphic garnets retain a substantial fraction of prograde radiogenic ¹⁷⁶Hf throughout peak metamorphic conditions, a phenomenon that further complicates the interpretation of ¹⁷⁶Lu–¹⁷⁶Hf garnet ages and invalidates the use of analytical T _C expressions. We argue that the diffusion of trivalent rare earth elements in garnet becomes much faster when their concentration level falls below a few hundred ppm, as in the experiments of Tirone et al. (Geochim Cosmochim Acta 69: 2385–2398, 2005), and further argue that this low-concentration mechanism is appropriate for modeling the susceptibility of ¹⁴⁷Sm–¹⁴³Nd garnet ages to diffusive resetting.     

The early Cambrian Chahmir shale-hosted Zn–Pb deposit,Central Iran: an example of vent-proximal SEDEX mineralization

The Chahmir zinc–lead deposit (1.5 Mt @ 6 % Zn + 2 % Pb) in Central Iran is one among several sedimentary-exhalative Zn–Pb deposits in the Early Cambrian Zarigan–Chahmir basin (e.g., Koushk, Darreh-Dehu, and Zarigan). The deposit is hosted by carbonaceous, fine-grained black siltstones, and shales interlayered with volcaniclastic sandstone beds. It corresponds to the upper part of the Early Cambrian volcano-sedimentary sequence (ECVSS), which was deposited on the Posht-e-Badam Block during back-arc rifting of the continental margin of Central Iran. Based on crosscutting relationships, mineralogy, and texture of sulfide mineralization, four different facies can be distinguished: stockwork (feeder zone), massive ore, bedded ore, and distal facies (exhalites with barite). Silicification, carbonatization, sericitization, and chloritization are the main wall-rock alteration styles; alteration intensity increases toward the proximal feeder zone. Fluid inclusion microthermometry was carried out on quartz associated with sulfides of the massive ore. Homogenization temperatures are in the range of 170–226 °C, and salinity is around 9 wt% NaCl eq. The size distribution of pyrite framboids of the bedded ore facies suggests anoxic to locally suboxic event for the host basin. δ³⁴S_(V-CDT) values of pyrite, sphalerite, and galena range from +10.9 to +29.8?‰. The highest δ³⁴S values correspond to the bedded ore (+28.6 to +29.8?‰), and the lowest to the massive ore (+10.9 to +14.7?‰) and the feeder zone (+11.3 and +12.1?‰). The overall range of δ³⁴S is consistent with a sedimentary environment where sulfide sulfur was derived from two sources. One of them was corresponding to early ore-stage sulfides in bedded ore and distal facies, consistent with bacterial reduction from coeval seawater sulfate in a closed or semiclosed basin. However, the δ³⁴S values of late ore-stage sulfides, observed mainly in massive ore, interpreted as a hydrothermal sulfur component, leached from the lower part of the ECVSS. Sulfur isotopes, along with the sedimentological, textural, mineralogical, fluid inclusion, and geochemical characteristics of the Chahmir deposit are in agreement with a vent-proximal (Selwyn type) SEDEX ore deposit model.     

Calcite Dissolution Kinetics

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.