微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷

建立了微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷的分析方法。用正交试验设计结合单因素试验优化了样品粒度、提取温度、提取时间、固液比等微波提取条件，研究了共存离子对无机砷测定的干扰情况。方法的线性范围为0．25～40．0μg/g，无机砷的检出限为0．05μg/g，样品加标回收率为92．9％～105．0％。方法的精密度（RSD，n=11）为0．3％。与水浴提取法相比，微波辅助提取法具有快速、高效的优势。方法已用于分析3个不同产地有代表性土壤中无机砷含量。     

锡在流体和花岗质硅酸盐熔体间分配行为的实验研究

锡的成矿与花岗岩有着密切关系。为深入了解不同的岩浆组成及流体变化对锡分配行为的影响,以不同化学组成的凝胶和不同的流体分别作为初始固液相,进行了锡在流体与花岗质熔体间的分配行为实验研究。实验温度为850℃,压力为100 MPa。结果显示,当液相为0.1 mol/L的HCl时,熔体组成的变化对锡的分配行为有着明显的影响,锡在流熔体间的分配系数DSn随熔体中碱质(Na2O K2O)含量、钠钾(Na/K)和碱铝(AlK/Al)摩尔比的增加而减小;在固相(富钾过碱质熔体)不变的前提下,DSn随流体相中HCl浓度的增加而增大,而流体相中HF及K 、Na 浓度的改变对DSn影响不大;流体Cl-浓度和酸度升高有利于锡分配进入流体相。     

肺炎性假瘤的CT诊断与鉴别诊断

目的: 分析肺炎性假瘤的CT表现.方法: 对32例经手术病理证实的肺炎性假瘤的CT及临床资料进行回顾性分析.结果: 病灶多位于肺胸膜下,广基地与胸膜相连;多呈圆形或类圆形,边缘光滑,直径2-5cm,密度均匀;边缘可见粗长毛刺,棘状突起或浅分叶;可有淋巴结肿大.结论: 全面综合地分析肺炎性假瘤的CT表现特征,结合肺内感染病史,肺炎性假瘤的正确诊断与鉴别诊断是很有帮助.     

无线电磁法（WEM）在地球物理勘探中的初步应用

无线电磁法(WEM)是上世纪90年代发展起来的一种新的人工源电磁探测技术,它通过一个固定大功率发射台发射0.1~300 Hz超低频/极低频电磁信号来探测地下地质结构.国内对WEM法的应用已做了大量的理论和实际试验工作,例如,大功率发射台辐射的电磁场计算,不同距离电磁信号发射接收试验,油田深部结构探测试验等.从试验的结果看,WEM法在提高电磁测深数据质量上具有很大的优势.     

芙蓉锡矿田骑田岭花岗岩黑云母矿物化学组成及其对锡成矿的指示意义

芙蓉锡矿田骑田岭复式岩体主要由早阶段角闪石黑云母花岗岩和晚阶段黑云母花岗岩组成.电子探针分析结果表明角闪石黑云母花岗岩中的黑云母属于铁黑云母,黑云母花岗岩中的黑云母属于铁叶云母.相对于黑云母花岗岩,角闪石黑云母花岗岩中黑云母的MgO、TiO2含量偏高,Al2O3含量偏低.矿物化学研究结果显示,角闪石黑云母花岗岩中黑云母的结晶温度、氧逸度(logfO2)分别为680℃～740℃、-16.00～-15.31,黑云母花岗岩中黑云母的结晶温度、氧逸度分别为530℃～650℃、-19.20～-17.50.从角闪石黑云母花岗岩到黑云母花岗岩,岩浆结晶温度和氧逸度逐渐降低.与花岗岩有关的共存流体性质的研究发现,与角闪石黑云母花岗岩共存的热液流体log(fH2O/fHF)fluid,log(fH2O/fHCl)fluid,log(fHF/fHCl)fiuid值分别为4.22～4.39,2.78～3.24,-1.82～-1.73,而与黑云母花岗岩共存的热液流体log(fH2O/fHF)fluid,log(fH2OfHCl)fluid,log(fHF/fHCl)fluid值分别为3.27～3.53,2.85～3.22,-0.75～-0.22,可见与两种岩石类型共存热液流体的性质存在明显差异,且热液中Cl、Sn含量变化与岩浆结晶分异指数呈正相关关系.骑田岭岩体从角闪石黑云母花岗岩到黑云母花岗岩,随着岩浆的演化.岩浆结晶期后分异出的热液流体向富Cl和Sn方向演化.芙蓉锡矿田的成矿流体应主要来源于黑云母花岗岩岩浆结晶期后分异出的岩浆热液.     

WebGIS研究与实现

阐述了一种WebGIS的研究思想和实现方法。通过运用C Builder开发GIS地图服务器、运用矢量标记语言(VML)结合ASP.NET实现GIS浏览器、运用Java Servlet结合Socket通讯技术解决GIS地图服务器和GIS浏览器之间信息传递,采用自定义XML作为数据交换语言,从而自主实现了WebGIS的全过程,此实现方式可用于GIS数据和其他图形数据的发布,不受限于任何商业GIS平台,具备WebGIS平台的雏形。此实现方法可以解决海量空间数据发布、图形编辑等当前WebGIS难点技术,并利用该方法成功实现了沈阳市突发性环境污染应急监测系统和辽宁省1∶10 000土地利用现状库的Web发布。     

南岭山地高速公路雾区恶劣能见度研究

使用2003年10月-2005年3月南岭山地京珠高速公路粤北段云岩雾区路段5套能见度仪的每分钟能见度资料和3套自动气象站的每分钟温度、湿度、风向、风速等气象要素资料, 分析研究了南岭山地高速公路雾区浓雾的能见度特征.结果表明, 南岭山地高速公路雾区各月雾日频率以1月最多, 近一半的天数都有雾; 3月次之, 7月最少.11月到次年5月雾日占全年雾日的80%以上, 形成明显的"雾季".南岭山地高速公路雾区浓雾存在日变化, 雾的频率在一天内凌晨最高, 午后最低, 明显比辐射雾的日变化小, 说明夜间辐射降温虽然不是南岭山地高速公路雾区起雾的主要原因, 但还是起到了一定的加强作用.虽然南岭山地雾区大气中含有丰富的凝结核, 南岭山地形成浓雾还是需要较高的相对湿度, 相对湿度至少要达到91%以上才能形成雾.在雾区出现5.2 m/s的大风时仍然有雾, 有雾时90%以上的风速在3 m/s以下, 有几乎一半的浓雾出现时风速在2 m/s左右, 这与辐射雾形成时大都是静小风的情况形成了鲜明对照.南岭山地高速公路雾区浓雾受地形影响比较大, 迎风坡出现雾的频率比背风坡高.     

Effect of Atmospheric Haze on the Deterioration of Visibility over the Pearl River Delta

The studies on the effect of atmospheric aerosol on climate and environment are hot issues in the current circle of international science and technology. In recent years the pollution of aerosol is getting worse and worse over the Pearl River Delta. The clouds of aerosol occur all year round, with heavy pollution area located at the western side at the mouth of Pearl River. The haze weather mainly occurs from October to April next year, resulting in visibility deterioration. From the beginning of 1980s, visibility dramatically deteriorated, obviously increasing haze weather, in which there are three big fluctuations, showing the periods of pollutions of dust, sulphate and dust, fine particle from photochemical process and sulphate and dust accompanying with the development of economy respectively. The long-term tendency of visibility caused by fog and light fog does not show a tendency due to human activities or economic development, which mainly shows the interannual and interdecadal variation of climate. The deterioration of visibility has close relation to the fine particles over Pearl River Delta, with half of PM10 overpass the limited value set by national second graded standard (150μg m-3), meanwhile, all values of PM2.5 overpass the day-mean limited value of American national standard (65μg m-3), especially from October to January next year, monthly mean values of PM2.5 almost reach two times of standard value, indicating the fine particle concentration is very high. The ratio of PM2.5 to PM10 is also very high, reaching 58%-77%, higher especially in dry season than in rainy season. Thus it is the fine particle pollution in aerosol pollution over the Pearl River Delta. Compared with the data of 15 years ago, the ratio of fine particle to aerosol has obviously increased.     

黑龙江老祚山金矿区片麻状花岗岩锆石U-Pb年龄、Hf同位素特征及其地质意义

黑龙江老柞山金矿床是佳木斯地块中北部的大型热液叠加夕卡岩型矿床.对矿区东矿带赋矿片麻状花岗岩进行了LA-ICP-MS的U-Pb定年和Hf同位素分析，共获得3组年龄，分别为697.1±8.0、703.0±8.8和484.7±2.7 Ma.其中前2组为捕获的锆石年龄，暗示佳木斯地块南缘可能存在新元古代的结晶基底.第三组锆石年龄代表片麻状花岗岩结晶年龄.锆石原位Hf同位素测试显示，片麻状花岗岩的ε_Hf（t）值为-2.4~+3.6，T_DM2为1620~1390 Ma，指示片麻状花岗岩原岩可能是中元古代陆壳物质重熔.结合区域构造演化，认为片麻状花岗岩可能形成于晚泛非-早加里东期的碰撞造山作用，是麻山群深熔岩浆结晶作用的产物.     

Average Annual Temperature Changes in the Holocene in China

In 1876 Blytt proposed a post-glacial climatic classification, maintaining that the then temperature fluctuated 1- 2℃ higher or lower than that today. Lamb (1969) held that in Europe " the axis of the subtropical high pressure belt was generally displaced north by about 10° latitudes" during the Hypsithermal and that the temperature was three to six times higher than that in the postglacial period.In China, there appear relict beachrocks (living fossils) in tropical tidal zones from the Bohai Bay (40° N) to coastal areas in South China. Many relict tropical marine fossils were discovered, such as Ostrea gigas in Tianjin (which is larger than that found today in Hainan), Placuna placenta in Zhejiang and Spondylus sp. in Fujian. In Hebei, Henan and Zhejiang provinces and Guilin of Guangxi, such tropical fossil animals as Elephas maximus and Rhinoceros sp, were discovered, and in Hebei and Jiangsu provinces such fresh water fossils as Unio douglasiae were found. Their living species are still seen in So