Revision and recalibration of existing shock classifications for quartzose rocks using low‐shock pressure (2.5–20 GPa) recovery experiments and mesoscale numerical modeling

A combination of shock recovery experiments and numerical modeling of shock deformation in the low‐shock pressure range from 2.5 to 20 GPa for two dry sandstone types of different porosity, a completely water‐saturated sandstone, and a well‐indurated quartzite provides new insights into strongly heterogeneous distribution of different shock features. (1) For nonporous quartzo‐feldspathic rocks, the traditional classification scheme (Stöffler 1984 ) is suitable with slight changes in pressure calibration. (2) For water‐saturated quartzose rocks, a cataclastic texture (microbreccia) seems to be typical for the shock pressure range up to 20 GPa. This microbreccia does not show formation of PDFs but diaplectic quartz glass/SiO₂ melt is formed at 20 GPa (~1 vol%). (3) For porous quartzose rocks, the following sequence of shock features is observed with progressive increase in shock pressure (1) crushing of pores, (2) intense fracturing of quartz grains, and (3) increasing formation of diaplectic quartz glass/SiO₂ melt replacing fracturing. The formation of diaplectic quartz glass/SiO₂ melt, together with SiO₂ high‐pressure phases, is a continuous process that strongly depends on porosity. This experimental observation is confirmed by our concomitant numerical modeling. Recalibration of the shock classification scheme results in a porosity versus shock pressure diagram illustrating distinct boundaries for the different shock stages.     

Glacial history of the Greenland Ice Sheet and a local ice cap in Qaanaaq,northwest Greenland

In this study, we present new information on the glacial history of the Greenland Ice Sheet (GrIS) and a local ice cap in Qaanaaq, northwest Greenland. We use geomorphological mapping, ¹⁰Be exposure dating of boulders, analysis of lake cores, and ¹⁴C dating of reworked marine molluscs and subfossil plants to constrain the glacial history. Our ¹⁴C ages of reworked marine molluscs reveal that the ice extent in the area was at or behind its present‐day position from 42.2 ± 0.4 to 30.6 ± 0.3k cal a BP after which the GrIS expanded to its maximum position during the Last Glacial Maximum. We find evidence of early ice retreat in the deep fjord (Inglefield Bredning) at 11.9 ± 0.6 ka whereas the Taserssuit Valley was deglaciated ~4 ka later at 7.8 ± 0.1k cal a BP. A proglacial lake record suggests that the local ice cap survived the Holocene Thermal Maximum but moss kill‐dates reveal that it was smaller than present for a period of time before 3.3 ± 0.1k until 0.9 ± 0.1k cal a BP, following which the ice in the area expanded towards its Little Ice Age extent. Copyright © 2019 John Wiley & Sons, Ltd.     

Impacts of irrigation on dry season precipitation in India

There is a lack of observed data-based studies examining the role of enhanced soil moisture conditions (due to irrigation) on the prevailing precipitation. Therefore, in the present study, we have examined the impacts of the Green Revolution (GR) related expansion of irrigation and changes in dry season (the rabi (November to May) and the zaid (March to June)) precipitation in India. The results for some regions indicated decreasing and increasing trend in precipitation during the pre- and post-GR periods, respectively. For example, in eastern Madhya Pradesh, the pre- and post-GR precipitation trends for the zaid season were ?0.45 and 2.40?mm?year^?1, respectively. On the other hand, some regions reported lower rate of decline in precipitation during the post-GR period. This paper suggests that both positive and lower declining trend during the post-GR period were linked to increased precipitation due to the introduction of irrigation. The study has found up to 69?mm (121%) increase in total amount of precipitation for growing seasons during the post-GR period. Moreover, a 175% increase in average precipitation was also recorded. All irrigated regions show a notable increase in precipitation during post-GR growing seasons. It was found that differences in growing season average precipitation between the pre- and post-GR periods were statistically significant for most of the regions. For further verification of results, the MM5 and Noah land surface model were applied. These applications show changes in precipitation and various precipitation controlling factors due to changes in soil moisture.     

Effects of an Acute Hypoxic Event on Microplankton Community Structure in a Coastal Harbor of Southern California

Fish mortality and hypoxic events occur in many coastal and inland systems and may result from natural or anthropogenically mediated processes. The effects of consequent changes in water biogeochemistry have been investigated for communities of benthic invertebrates and pelagic metazoans. The responses of micro-plankton assemblages, however, have remained largely unstudied. The northern basin of King Harbor, a small embayment within Santa Monica Bay, CA, USA, suffered a massive fish kill in March 2011 as a consequence of acute hypoxia. Dissolved oxygen concentrations < 0.1 ml?l^?1 were measured in the northern basin of the harbor for several days following the mortality event, and a strong spatial gradient of oxygen was observed from the northern basin to waters outside the harbor. The microplankton community within King Harbor differed significantly from a diatom-dominated community present in neighboring Santa Monica Bay. The latter region appeared unaffected by physicochemical changes, induced by the fish kill, that were observed within the harbor. A trophic shift was observed throughout King Harbor from a photoautotrophic-dominated assemblage to one of heterotrophic forms, with relative abundances of bacterivorous ciliates increasing by more than 80 % in the most impacted part of the harbor. Significant changes in community structure were observed together with dramatically reduced photosynthetic yield of the remaining phytoplankton, indicating severe physiological stress during the extreme hypoxia.     

Dynamics of xenobiotic transformation processes in soil systems: A zero-dimensional system model applied to ethylenethiourea

A zero-dimensional model for the environmental fate of ethylenethiourea (ETU) in soils was formulated. The relevant physicochemical transformation processes were derived from published data, and their dynamics analyzed. Corresponding kinetic submodels for sorption, photodegradation, abiotic oxidation and biodegradation were then developed based on assumptions on the dominant process mechanisms. These submodels, and the overall model of biotic degradation in soil, were applied to literature data with determination coefficients of R² > 0.9, validating the assumed process dynamics.