Relationship of chemical fractions of heavy metals with microbial and enzyme activities in sludge and ash-amended acid lateritic soil from India

The influence of metals, Cd, Cr, Cu, Ni, Pb and Zn, on the microbial biomass and enzyme activities of an amended acid lateritic soil were investigated under field conditions receiving a one-time application of 52 t ha^–1 of sludge, coal ash and their mixtures at 1:3, 1:1 and 3:1 proportions, and including control and chemical fertilizer treatment at crop-specific recommended doses. Paddies and peanuts were grown in the experimental plots and soil was sampled twice after 6 months and 1 year after amendment application. The heavy metals in the soil were fractionated using sequential extraction and the increments in their concentrations in amended soil with respect to the control were determined. Concentrations of Cd, Ni and Zn were determined to have increased in their mobile fractions and were more pronounced in soil collected during the second sampling, which was associated with a decrease in soil organic carbon. The size of the microbial biomass carbon and the soil enzyme activities increased with the addition of an amendment and was highest at equal proportions of coal ash and sludge. Further increase in the proportion of sludge resulted in a significant decrease in biomass carbon. Simple correlation revealed significant and strong negative relations of mobile fractions of Cd and Ni with the ratio between microbial biomass C and organic carbon in soil, while the organic carbon content and the pH were positively correlated. The microbial activities were determined to be sensitive to the concentrations of some heavy metals in mobile fractions and therefore indicated possibilities of being useful as indicators for evaluation of toxic effects of sludge-borne metals on soil organisms.     

The Northern Cordilleran Mid-Cretaceous Plutonic Province: Ilmenite/Magnetite-series Granitoids and Intrusion-related Mineralisation

Abstract. Twenty-five Early and mid-Cretaceous (145–90 Ma) plutonic suites and belts are defined across Alaska and Yukon, in the northern North American Cordillera, on the basis of lithological, geochemical, isotopic, and geochronometric similarities. These features are combined with aeromagnetic characteristics, magnetic susceptibility measurements, and whole-rock ferric: ferrous ratios to ascertain the distribution of magnetite- and ilmenite-series plutonic belts. Magnetite-series plutonic belts are dominantly associated with the older parts of the plutonic episode and comprise subduction-generated metaluminous plutons that are distributed preferentially in the more seaward localities dominated by primitive tectonic elements. Ilmenite-series plutonic belts comprise slightly younger, slightly peraluminous plutons in more landward localities in pericratonic to continental margin settings. They were likely initiated in response to crustal thickening following terrane collision. The youngest plutonic belt forms a small, but significant, magnetite-series belts in the farthest inboard position, associated with alkalic plutons that were emplaced during weak extension.
Intrusion-related metallogenic provinces with distinctive metal associations are distributed, largely in accord with classical redox-sensitive granite-series. Copper, Au, and Fe mineralisation are associated with magnetite-series plutons and tungsten mineralisation associated with ilmenite-series plutons. However, there are some notable deviations from expected associations, as intrusion-related Ag-Pb-Zn deposits are few, and significant tin mineralisation is rare. Most significantly, many gold deposits and occurrences are associated with ilmenite-series plutons: these form the basis for the newly recognized reduced intrusion-related gold deposit model.     

A literary geography of Soweto

Humanist inspired literary geography offers one avenue of enquiry into the study of place. Its prime intention is to untangle the subjective, personalised construction and connotations of place meaning. African literature offers a rich source of information into the black urban experience. The presentation focuses upon the literary interpretation of Soweto, South Africa's largest black township. The Sowetan environment emerges as a landscape of placelessness in which the overwhelming emphasis by white and black writers alike is upon relating appalling conditions in an austere and hostile environment.     

Petrogenesis of a basalt-rhyolite tephra from the west-central Afar,Ethiopia

The Cindery Tuff is an unusual tephra fall deposit that contains evidence for the mixing of basaltic and rhyolitic liquids prior to eruption. It contains clear rhyolitic glass shards together with brown basaltic glass spheres and a broadly bimodal phenocryst assemblage. Brown glasses are ferrobasaltic in composition and are similar to the voluminous Pliocene tholeiites of the surrounding west-central Afar volcanic field; both are enriched in the light rare earth and incompatible elements and possess higher ⁸⁷Sr/⁸⁶Sr and lower ¹⁴³Nd/¹⁴⁴Nd than MORB. Rhyolitic glasses are subalkaline and, compared to the basaltic glasses, are strongly depleted in the compatible elements and enriched in the incompatible elements. Both glass types have similar incompatible element and isotopic ratios, and with the rhyolite glass showing a 2-fold parallel enrichment in rare earth element abundances over the basaltic glass. These observations suggest that the two glasses are genetically related.Rare glasses with intermediate compositions occur as phenocryst melt inclusions, as mantles on phenocrysts and as free pumice clasts. Their major element contents do not point to an origin by simple hybrid mixing of the basaltic and rhyolitic melts. Rather, major element mixing calculations indicate formation of the intermediate and rhyolite melts by fractionation of the observed phenocryst assemblage, using a starting composition of the observed basaltic glass. Model calculations from trace element data, though lacking from the intermediate glasses, support fractional crystallization. The bimodal mineral assemblage argues against an immiscible liquid origin for the contrasting glass compositions.     

An isotopic study of hydrocarbon generation processes

The sources of reservoired liquid hydrocarbons in Australia differ substantially from their Northern Hemisphere counterparts. Not only are Australian source rocks largely of terrigenous origin but the concepts accepted as defining the hydrocarbon potential of source rocks have recently been challenged. Although isotopic measurements on Australian source rocks and liquid hydrocarbon products closely parallel those published from elsewhere, new interpretations of these data have been made, particularly with regard to D/H ratios in coals. As interesting as such results may be, the most important findings relate to the origins and histories of methane, the higher gaseous hydrocarbons and carbon dioxide, and the interpretation of these data in terms of hydrocarbon genesis. Simple Northern Hemisphere concepts which characterize gases as being biogenic, oil-associated, etc., on the bases of their isotopic and chemical compositions are clearly not applicable to the Australian scene. Indeed justification of such precise classifications in the Northern Hemisphere on the available evidence is also questioned.Isotopic and compositional data from gases from the Cooper, Bowen, Sydney and Gippsland Basins and from the North West Shelf (Australia) are reviewed, and assessed in terms of generation pathways.     

Possible errors in helium analyses of soil gases by mass spectrometers having constant-pressure inlet systems

Published data suggest that soil gas helium concentrations of 5.28–5.34 ppm v/v over uranium and hydrocarbon deposits are significantly anomalous compared to the ambient atmospheric background of 5.24 ppm. However, analyses for helium by mass spectrometers having constant-pressure inlet systems, from which most of these data are derived, are subject to errors of equivalent magnitude. These errors arise when the major component composition of unknown and standard gases differ, for the different gases have different flow rates through the inlet system — relative rates being O₂ < dry air < water-saturated air < N₂ < CO₂ CH₄. Soil gas compositions can vary greatly and, compared to a dry air standard, the flow-rate of a water-saturated gas containing 10% biogenic CO₂ will increase, enhancing the apparent He content to 5.33 ppm. Accurate helium analyses can be achieved by using a constant-volume inlet and integrating the detector response over the period of the samples' passage through the detector.     

CASPIR: A cryogenic array spectrometer imager for the MSSSO 2.3 m telescope

CASPIR is a near-infrared spectrometer/imager being built for the Mount Stromlo and Siding Spring Observatories' 2.3 m telescope. The instrument is based on a SBRC 256×256 InSb detector array and uses AR-coated Sapphire, MgO, CaF₂, and BaF₂ optics to produce two imaging focal plane scales with 0.5/pixel and 0.25/pixel. Spectral resolving powers of 500 will be achieved through a 1×128 slit with three grisms designed for the J, H, and K bands. IJ, JH, and HK cross-dispersed échelle grisms will achieve resolving powers of 1100 through a 1×15 slit. Coronograph and imaging polarimetry modes will also be available. The various observing configurations are selected via five remotely controlled wheels. The instrument design and system architecture are discussed, and preliminary detector performance figures reported.     

Geographical Linked Data: The Administrative Geography of Great Britain on the Semantic Web

Ordnance Survey, the national mapping agency of Great Britain, is investigating how semantic web technologies assist its role as a geographical information provider. A major part of this work involves the development of prototype products and datasets in RDF. This article discusses the production of an example dataset for the administrative geography of Great Britain, demonstrating the advantages of explicitly encoding topological relations between geographic entities over traditional spatial queries. We also outline how these data can be linked to other datasets on the web of linked data and some of the challenges that this raises.     

Distribution and geochronology of Oregon Plateau (U.S.A.) flood basalt volcanism: The Steens Basalt revisited

The timing and petrogenesis of mid-Miocene flood basalt volcanism in the northwest United States has been extensively addressed, yet the chemical characteristics and temporal details of the Steens Basalt, exposed on the Oregon Plateau, are poorly defined. Steens Basalt volcanism has generally been accepted to have occurred at ∼ 16.6 Ma, coeval and/or just prior to the onset of Columbia River Basalt Group volcanism to the north. New major and trace element analyses and nine ⁴⁰Ar/³⁹Ar ages ranging from 15.51 ± 0.28 to 16.58 ± 0.18 Ma were obtained on Oregon Plateau flood basalt lava flows from stratigraphic sections in close proximity to Steens Mountain. Additionally, new ⁴⁰Ar/³⁹Ar ages were obtained on the uppermost and thirty-first lava flow down from the top of the ∼ 1 km section of Steens Basalt exposed at Steens Mountain and yield eruption ages of 16.59 ± 0.10 and 16.55 ±0.10 Ma, respectively. Field relations between these basalt sections suggest that multiple eruptive centers were present in the vicinity of Steens Mountain.