Analysis of individual fluid inclusions using synchrotron X-ray fluorescence microprobe: progress toward calibration for trace elements

A critical problem for conducting quantitative analysis of individual fluid inclusions using Synchrotron X-Ray Fluorescence (SXRF) technique relates to the standardization and the calibration of the X-ray spectra. In this study, different approaches have been tested for calibration purposes: (a) the use of chlorine when Cl content can be estimated either from melting point depressions of undersaturated fluid inclusions or from saturation limits for halite-bearing fluid inclusions, (b) the use of calcium from synthetic fluid inclusions of known CaCl₂ content as an external standard. SXRF analysis was performed on individual fluid inclusions from the Chivor and Guali emerald deposits, Columbia. These well-known samples contain a single fluid inclusion population for which detailed crush-leach analyses are available, thus providing a relevant compositional reference frame. Concentration estimates were also compared to Particle Induced X-ray Emission (PIXE) analysis carried out independently on the same fluid inclusions.Results of the calibration tests indicate that major (Cl, K, Ca, Fe, Mn) and trace element (Cu, Zn, As, Br, Rb, Sr, Ba, Pb) concentration estimates can be performed without precise knowledge of the analytical volume and the inclusion’s 3D geometry. Although the standard deviation of the SXRF results can be relatively high depending on the calibration mode used, mean concentration estimates for most elements are in good agreement with PIXE and crush-leach analysis. Elemental distributions within single fluid inclusions were also established. Associated correlation diagrams argue for the homogeneous distribution of most elements in the fluid inclusion. In contrast, Br shows a bimodal distribution interpreted to reflect a significant enrichment of the vapor portion of the inclusion fluid.     

Seleniferous minerals of palladium and platinum from ouro preto-bearing mineralisation in Brazil

Foram determinadas as composições químicas e as idades Rb–Sr de mica branca, feldspato potássico e de rochas totais das mineralizações de esmeraldas de Capoeirana e Belmont, de pegmatitos sem esmeraldas e dos gnaisses Borrachudos, Monlevade e Guanhães da região de Nova Era–Itabira–Ferros (Minas Gerais, Brazil). Os gnaisses graníticos Borrachudos, os gnaisses bandados Monlevade, seus respectivos pegmatitos e veios/schlieren pegmatóides, e os gnaisses Guanhães, adquiriram suas texturas e composições mineralógicas atuais há cerca de 1.9 Ga no contexto do evento Transamazônico.As rochas regionais encaixantes típicas das ocorrências de esmeraldas são os gnaisses Monlevade que pertencem a uma sequência metavulcano-sedimentar de tipo greenstone belt. O evento principal de formação de esmeraldas em Belmont e Capoeirana foi uma reação metassomática dos pegmatitos anatéticos ricos em Be com rochas ultrabásicas ricas em Cr durante o evento Transamazônico em torno de 1.9 Ga. Em Capoeirana nesse contexto os pegmatitos com feldspato potássico ricos em Be foram transformados em rochas de plagioclasio–quartzo. As idades Rb–Sr de cerca de 480 Ma de minerais das mineralizações de esmeralda resultaram da reequilibração de biotitas e feldspatos Transamazônicos durante o evento Brasiliano.Os pegmatitos não-metamórficos e sem esmeralda da região estudada foram formados no evento Brasiliano há 477±14 Ma. O grau de diferenciação dos pegmatitos, estudado em diagramas indicadores específicos como por exemplo Cs vs. K/Rb de micas brancas e feldspatos potássicos, varia desde pegmatitos cerámicos até muscovita-pegmatitos, à pegmatitos de metais raros e até berilíferos. Alguns dos pegmatitos apresentam marcante diferenciação interna.

On the Origin of S0 Stellar Populations

We investigate a one-zone chemo-photometric evolutionary model of truncated spiral galaxies with and without starbursts in order to explore the origin of the spectrophotometric properties of S0s. First, we show that 1) the tight U-V colour–magnitude (CM) relation cannot reject the model with a starburst and 2) the model with a starburst can explain the difference in the I-K colour–magnitude relation between S0 galaxies and spiral galaxies. Next, we demonstrate how we can distinguish the truncated spirals with a starburst from those without a starburst by using the CaII–Hδ/λ4045 diagram (proposed by Leonardi and Rose, 1996) and the 1550-V colour. This revised version was published online in July 2006 with corrections to the Cover Date.     

An enlarged cosmic shear survey with the William Herschel Telescope

We report the results of a cosmic shear survey using the 4.2-m William Herschel Telescope on La Palma, to a depth of   R = 25.8 ( z ≈ 0.8)  , over 4 deg². The shear correlation functions are measured on scales from 1 to 15 arcmin, and are used to constrain cosmological parameters. We ensure that our measurements are free from instrumental systematic effects by performing a series of tests, including a decomposition of the signal into E - and B -modes. We also reanalyse the data independently, using the shear measurement pipeline developed for the COMBO-17 survey. This confirms our results and also highlights various effects introduced by different implementations of the basic 'Kaiser–Squires–Broadhurst' shear measurement method. We find that the normalization of the matter power spectrum on 8  h ⁻¹ Mpc scales is  σ₈= (1.02 ± 0.15)(0.3/Ω _m )^1/2  , where the 68 per cent confidence limit error includes noise, sample variance, covariance between angular scales, systematic effects, redshift uncertainty and marginalization over other parameters. We compare these results with other cosmic shear surveys and with recent constraints from the Wilkinson Microwave Anisotropy Probe experiment.     

A Map of the Posidonia oceanica Beds of Marina ďElbu (Corsica, Mediterranean)

Abstract. A large-scale map of the Posidonia oceanica seagrass beds as well as other benthic substrata and communities was compiled for a cove of a marine reserve free from pollution and man-made disturbance. An extensive diving survey of the cove and the interpretation of aerial colour photographs were used. The greater part of the cove is occupied by the P. oceanica meadow. Patches of dead "matte" were observed at a depth of between 7 and 14 m. They may be the result of a natural hydrodynamic equilibrium between building and erosion.