Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Provenance of the Bosnian Flysch

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.     

Croatia as a Danube country

Among the three principal regional units of Croatia, i.e. the elongated and spacious Adriatic littoral (with numerous islands), the relatively small and narrow mountainous belt (the Croatian transit doorway) and the Pannonian/peri-Pannonian region, the latter is the largest and accounts for 54 percent of the surface area and 66 percent of the population of Croatia (1991 census). It is part of the Pannonian (or Carpathian) basin, or the central Danube basin, so that Croatia is simply by its position a Danube country. Its Danube character is also highlighted by the fact that the Pannonian/peri-Pannonian region of Croatia through the Sava and Drava Rivers is directly linked to the navigable Danube, which is the historical and ethnic eastern boundary of Croatia. Croatia is an old historical Danube nation and country, although it has nominally appeared as a state after the break-up of Yugoslavia, and its international recognition as an independent state (1992).     

Hierarchical decomposition of variance with applications in environmental mapping based on satellite images

A quadtree-based image segmentation procedure (HQ) is presented to map complex environmental conditions. It applies a hierarchical nested analysis of variance within the framework of multiresolution wavelet approximation. The procedure leads to an optimal solution for determining mapping units based on spatial variability with constraints on the arrangement and shape of the units. Linkages to geostatisiics are pointed out, but the HQ decomposition algorithm does not require any homogeneity criteria. The computer implementation can be parameterized by either the number of required mapping units or the maximum within-unit variance, or it can provide a spectrum of significances of nested ANOVA. The detailed mathematical background and methodology is illustrated by a salt-affected grassland mapping study (Hortobágy, Hungary), where heterogeneous environmental characteristics have been sampled and predicted based on remotely sensed images using these principles.     

Energy balance of simple elastodynamic sources

Complete relations are derived for energy and energy flux of elastic waves generated by an isotropic and double-couple source in a perfectly elastic, homogeneous, isotropic, and unbounded medium. In the energy balance of elastodynamic sources near-field waves play an essential role, transforming static energy into wave energy, andvice versa. For explosive and dislocation sources, the sources surface radiates a positive wave energy that is partially distributed to the medium transforming into static energy. For implosive and antidislocation sources, the source surface generates elastic waves, but it does not necessarily imply that it also radiates a positive wave energy. The energy transported by waves can originate in gradual transformation of the static-to-wave energy during propagation of waves through a stressed medium.On leave from Geophysical Institute, Czech Academy of Sciences, Boní II/1401, 41 31, Praha 4 Czech Republic     

Redefining active volcanoes: a discussion

The analysis of the current definitions of active volcanoes indicates that they are empirical, conventional, inaccurate, nongeological, and arbitrarily constraining. Redefinition is therefore needed. One possible approach is to refine the current empirical definitions. A statistically reasonable and practical redefinition using a geologically based time convention-Holocene or 10000 years-is suggested. A set of time conditions according to volcano typology-i.e. 1000; 10000 and 100000 years for high-frequency basaltic shields, andesitic-dacitic composite volcanoes and low-frequency large silicic calderas, respectively-as further refinement of the empirical definition is also envisaged. Devising a phenomenological definition as a theoretical approach is another possibility, but in practice extant diagnostic means are still unsatisfactory to discriminate accurately between dormant and extinct volcanoes. As a consequence of the redefinition, a classification of volcanoes according to their eruptive status is proposed. Redefinition of active volcanoes might increase accuracy in the usage of basic terms in volcanology and influence volcanic hazard assessment and risk mitigation projects.     

Dynamics of the plasmasphere in the dusk sector as observed in the outer ionosphere

Summary Direct measurements of the thermal plasma parameters in the topside ionosphere reveal variations of the plasmasphere boundary in the dusk sector. The ACTIVE satellite's near-polar orbits at altitudes of 500 – 1800 km around winter solstice 1989 were used to study the bulge region of the plasmasphere during intervals with different levels of geomagnetic agitation. The narrow, sharply defined trough in electron concentration corresponding to the plasmapause under quiet conditions situated at L = 6 – 7 moved to lower L-values with increasing geomagnetic activity. This narrow trough can be found in all main ion constituents. During periods of moderate geomagnetic activity, following the onset of a weak magnetic storm, a portion of the plasmaspheric bulge region was separated from the main plasmaspheric body. This can be seen in the outer ionosphere as an inner narrow trough at lower L-value. Troughs in light ions need no longer coincide with this in electron concentration. He⁺ is the most sensitive constituent reflecting the dusk sector plasmaspheric situation at this altitude.Dedicated to the Memory of Professor Karel P     

Paleogeothermal gradient in the boskovice furrow

Summary A coalification data set from the first seam of the Rosice-Oslavany coal district in the Boskovice furrow was used to estimate the temperature gradient prevailing within the furrow during Autunian sedimentation. An appreciable scatter of the data reflects the complicated history of the sedimentary region. The northern part of the district displays a higher degree of coalification. The results of the evaluation suggest that the region ceased to subside in the upper Autunian, and that the extent of the post-Autunian erosion does not exceed 500 metres. This version of the burial history, which is consistent with geological data, yields a temperature paleogradient of 76 mK/m for the northern part and of 72 mK/m for the southern part of the district. The gradients estimated are higher than those prevailing during the Carboniferous sedimentation in the Central Bohemian Basin (45 – 53 mK/m), lower than values found for the Ostrava Formation in the Upper Silesian Basin during its Namurian A sedimentation (about 95 mK/m), but comparable with values evaluated for the Karviná Formation of the same basin deposited during the Namurian B - C and Westphalian A (60 – 77 mK/m).Dedicated to the Memory of Professor Karel P     

Behavioural-geographical aspects of environmental quality

The behavioural approach in human geography accentuates the view of quality of the environment through man and his value orientations. The quality of environment from the point of view of human experience raises behavioural-geographical questions that are the core of the presented topic. Aspects of environmental imaginations and sensations as well as human value system are presented as variables affecting the structure of the perceived environment and human spatial behaviour. In this context, the authors present results of two behavioural studies that correspond to new models of man and environment from the viewpoint of a behavioural approach. The suggested humanistic approach in behavioural geography emphasizes above all the emotional aspect of the relationship between man and environment, which through environmental values, spatial sensations, and meanings, leads to human spatial behaviour.     

Ab initio calculated electron densities for tetrahedral sheet [H2Si2O5]∞ in phyllosilicates

Periodic ab initio Hartree-Fock LCAO calculations have been carried out on the two dimensional sheet of SiO₄ tetrahedra, representing one of the basic constituting units of layer silicates, using Huzinaga's DZP basis sets. The influence of the basis set on the chemical bonding picture is characterized by Mulliken atomic charges and by electron density maps. Silicon atomic charges +1.6 ¦e¦ are more realistic than those +2.4 ¦e¦ reported for smaller basis sets. The silicon d orbital population is found to be 0.6 in close agreement with molecular data. Electron density maps indicate the absence of charge density in the center of the ditrigonal cavity. The charge buildup of nonbonding basal oxygen orbitals is directed mainly downwards perpendicular to the sheet plane.