The anisotropy of cosmic ray arrival directions around 10 eV

Anisotropy in the arrival directions of cosmic rays with energies above 10¹⁷ eV is studied using data from the Akeno 20 km² array and the Akeno Giant Air Shower Array (AGASA), using a total of about 114 000 showers observed over 11 years. In the first harmonic analysis, we have found a strong anisotropy of 4% around 10¹⁸ eV, corresponding to a chance probability of 0.2% after taking the number of independent trials into account. with two-dimensional analysis in right ascension and declination, this anisotropy is interpreted as an excess of showers near the directions of the Galactic Center and the Cygnus region.     

Determination of Molybdenum, Antimony and Tungsten at sub μg g−1 Levels in Geological Materials by ID-FI-ICP-MS

We have developed a rapid and accurate method for the determination of Mo, Sb and W in geological samples using isotope dilution inductively coupled plasma-mass spectrometry with a flow injection system (ID-FI-ICP-MS). The chemical procedure requires HF digestion of the sample with a Mo-Sb-W mixed spike, subsequent evaporation and dissolution of Mo, Sb and W from Mg and Ca fluorides with HF. Recovery yields of Mo, Sb and W in the extraction were > 94% for samples of peridotite, basalt and andesite composition, with the exception of W in samples of peridotite composition for which recovery was 81%. No matrix effects were observed in the determination of the isotope ratios of Mo, Sb and W in solutions prepared from peridotite, basalt and andesite samples down to a dilution factor of 100. Detection limits of Mo, Sb and W in silicate materials were at the several ng g⁻¹ level. Analysis of the silicate reference materials PCC-1, DTS-1, BCR-1, BHVO-1, AGV-1 from the US Geological Survey and JP-1, JB-1, -2, -3, JA-1, -2, and -3 from the Geological Survey of Japan as well as the Smithsonian reference Allende powder yielded reliable Mo, Sb and W concentrations. The repeatability in the analysis of basalts and andesites was < 9%. This technique requires only 0.2 ml sample solution, and is therefore suitable for analyzing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates.     

Determination of Zirconium, Niobium, Hafnium and Tantalum at ng g-1 Levels in Geological Materials by Direct Nebulisation of Sample HF Solution into FI-ICP-MS

We have developed a rapid and accurate method to determine Zr, Nb, Hf and Ta (denoted as HFSE) in geological samples by inductively coupled plasma-mass spectrometry fitted with a flow injection system (FI-ICP-MS). The method involves sample decomposition by HF followed by HF dissolution of HFSE coprecipitated with insoluble M and Ca fluoride residues formed during the initial HF attack. This HF solution was directly nebulized into an ICP mass spectrometer. An external calibration curve method and an isotope dilution method (ID) were applied for the determination of Nb and Ta, and of Zr and Hf, respectively. Recovery yields of HFSE were > 96% for peridotite, basalt and andesite compositions, apart from Zr and Hf for peridotite (> 85%). No matrix effects for either signal intensities of HFSE or isotope ratios of Zr and Hf were observed in basalt, andesite and peridotite solutions down to a dilution factor of 100. Detection limits in silicate rocks were 40, 2, 1 and 0.1 ng g-1 for Zr, Nb, Hf and Ta, respectively. This technique required only 0.1 ml of sample solution, and thus is suitable for analysing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates. We also present newly determined data for the Zr, Nb, Hf and Ta concentrations in USGS silicate reference materials DTS-1, PCC-1, BCR-1, BHVO-1 and AGV-1, GSJ reference materials JB-1, -2, -3, JA-1, -2 and -3, and the Smithsonian reference Allende powder.     

Spatial distribution of sister species of vesicomyid bivalves Calyptogena okutanii and Calyptogena soyoae along an environmental gradient in chemosynthetic biological communities in Japan

Vesicomyid bivalves have a substantial biomass in deep-sea chemosynthetic biological communities in the Pacific. Using a novel multiplex-PCR (mPCR) method to identify the co-occurring vesicomyids in Sagami Bay, we analyzed the distribution of Calyptogena okutanii and Calyptogena soyoae along environmental gradients. All the known distributions of C. okutanii indicated the different preferences in salinity and temperature to those of C. soyoae, and in Sagami Bay, depth seemed to be an important environmental factor, too. Although the concentration of hydrogen sulfide in sediment was not examined, our results showed that the distributions of these two Calyptogena clams were affected by salinity and temperature.     

Litterfall of three subtropical mangrove species in the family Rhizophoraceae

This study was conducted to evaluate and compare the litterfall dynamics of three mangrove species in the family Rhizophoraceae: Rhizophora stylosa, Kandelia obovata, and Bruguiera gymnorrhiza, in Manko Wetland, Okinawa Island, Japan. Over 3?years, these species showed highest litterfall of leaves and stipules in summer and the lowest litterfall in winter. Litterfall of flowers and fruits peaked in July for R. stylosa, and in August and again in October?CNovember for K. obovata. Litterfall of flower buds, flowers, and propagules occurred throughout the year for B. gymnorrhiza, but was highest in summer. Litterfall of propagules was highest in September and May for R. stylosa and K. obovata, respectively. Kendall??s coefficient of concordance revealed that the monthly changes for leaf, stipule, flower, and fruit litterfalls of all the species were strongly and significantly concordant among the years. The conversion rate of flowers to propagules was 2.3?% in R. stylosa, 5.9?% in K. obovata, and 10.3?% in B. gymnorrhiza. Total annual litterfall in R. stylosa was significantly different from K. obovata and B. gymnorrhiza; however, the latter two species showed no significant differences. Leaves contributed the most to the total litterfall of all three species, and represented 58.4, 54.0, and 50.4?% of the total litterfall for R. stylosa, K. obovata, and B. gymnorrhiza, respectively. Except for branches and flower bud primordia, all other components of litterfall had clear annual cycles for all three species. Rhizophora stylosa and K. obovata showed a negative correlation between leaf production and reproductive organ production, but B. gymnorrhiza tended to increase leaf production with increasing reproductive organ production.     

Seismic vertical array analysis for phase decomposition

We propose a vertical array analysis method that decomposes complex seismograms into body and surface wave time histories by using a velocity structure at the vertical array site. We assume that the vertical array records are the sum of vertically incident plane P and S waves, and laterally incident Love and Rayleigh waves. Each phase at the surface is related to that at a certain depth by the transfer function in the frequency domain; the transfer function is obtained by Haskell's matrix method, assuming a 1-D velocity structure. Decomposed P , S and surface waves at the surface are estimated from the vertical array records and the transfer functions by using a least-squares method in the frequency domain; their time histories are obtained by the inverse Fourier transform. We carried out numerical tests of this method based on synthetic vertical array records consisting of vertically incident plane P and S waves and laterally incident plane Love and Rayleigh waves. Perfect results of the decomposed P , S , Love and Rayleigh waves were obtained for synthetic records without noise. A test of the synthetic records in which a small amount of white noise was added yielded a reasonable result for the decomposed P , S and surface waves. We applied this method to real vertical array records from the Ashigara valley, a moderate-sized sedimentary valley. The array records from two earthquakes occurring at depths of 123 and 148 km near the array (epicentral distance of about 31 km) exhibited long-duration later phases. The analysis showed that duration of the decomposed S waves was a few seconds and that the decomposed surface waves appeared a few seconds after the direct S -wave arrival and had very long duration. This result indicated that the long-duration later phases were generated not by multireflected S waves, but by basin-induced surface waves.     

Internal differentiation of Kutsugata lava flow from Rishiri Volcano,Japan: Processes and timescales of segregation structures' formation

Internal differentiation processes in a solidifying lava flow were investigated for the Kutsugata lava flow from Rishiri Volcano in northern Japan. In a representative 6-m thick lava flow that was investigated in detail in this study, segregation products darker than the host lavas manifested mainly in the form of pipes (vesicle cylinders) and layers (vesicle sheets), occurring around 0.5–2.3 m and 2.0–4.0 m above the base, respectively. Both the cylinders and sheets are significantly richer in incompatible elements such as TiO₂ and K₂O than the host lavas, which suggest that these products essentially represent residual melt produced during solidification of the lava flow. Field observation and the geochemical features of the lavas suggest that the vesicle cylinders grew upward from near the base of the flow by continuous feeding of residual melt from the neighboring host lavas to the heads of the cylinders. On the other hand, the vesicle sheets were produced in situ in the solidifying lava flow as fracture veins caused by horizontal compression. The vesicle cylinders have a remarkably higher MgO content (up to 8 wt.%) than the host lava (< 6 wt.%), whereas the vesicle sheets display MgO depletion (as low as 3.5 wt.%). The relatively high MgO content of the vesicle cylinders cannot be explained solely by the mechanical mixing of olivine phenocrysts with the residual melt. It is suggested that the vesicle cylinders were produced by the extraction of olivine-bearing interstitial melt from an augite-plagioclase network in the host lava, whereas the vesicle sheets were formed by the migration of the residual melt from a crystal network consisting of plagioclase, augite, and olivine in the host lava into platy fractures. We infer that this selective crystal fractionation for forming the vesicle cylinders resulted from processes in which abundant vesicles rejected from the upward-migrating floor solidification front prevented olivine crystals from being incorporated into the crystal network in the host lava. The vesicle cylinders are considered to have formed in ∼ 1 day after the lava flow came to rest, while relatively large vesicle sheets (> 1 cm thick) appeared much later (after ∼ 9 days). The formation of these segregation products was essentially complete within 20 days after the lava emplacement.     

Determination of Ge, As, Se and Te in Silicate Samples Using Isotope Dilution-Internal Standardisation Octopole Reaction Cell ICP-QMS by Normal Sample Nebulisation

A method for the determination of Ge, As, Se and Te in silicate samples using isotope dilution-internal standardisation (ID-IS) octopole reaction cell (ORC) ICP-QMS by normal sample nebulisation was developed. The method does not involve either hydride generation or ion exchange. Germanium, Se and Te were determined by isotope dilution (ID), and As was determined by ID-IS. A silicate sample with an added Ge-Se-Te spike was digested with an HF-HNO₃-HBr mixture, dried, re-dissolved with HF and the supernatant liquid was directly aspirated into an ORC-ICP-QMS instrument with He or H₂ gas. No matrix effects were observed down to a dilution factor (DF) of ∼ 70 for Ge, Se and Te and DF of ∼ 1000 for As, which resulted in 3s detection limits in silicates of 2, 1, 0.1 and 4 ng g⁻¹, respectively. Advantages of the method are the simple sample introduction as well as a capability of determining S, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by ID-IS-ICP-QMS/SFMS from the same solution. Furthermore, the total sample solution consumption was only 0.253 ml with DF = 2000. Therefore, only a 0.13 mg test portion was required. To demonstrate the applicability of this technique, Ge, As, Se and Te in eight silicate reference materials were determined, as well as S, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta in four carbonaceous chondrites.     

The 11 March 2011 Tohoku Tsunami Survey in Rikuzentakata and Comparison with Historical Events

On 11 March 2011, a moment magnitude M _w = 9.0 earthquake occurred off the Japan Tohoku coast causing catastrophic damage and loss of human lives. In the immediate aftermath of the earthquake, we conducted the reconnaissance survey in the city of Rikuzentakata, Japan. In comparison with three previous historical tsunamis impacting the same region, the 2011 event presented the largest values with respect to the tsunami height, the inundation area and the inundation distance. A representative tsunami height of 15 m was recorded in Rikuzentakata, with increased heights of 20 m around rocky headlands. In terms of the inundation area, the 2011 Tohoku tsunami exceeded by almost 2.6 times the area flooded by the 1960 Chilean tsunami, which ranks second among the four events compared. The maximum tsunami inundation distance was 8.1 km along the Kesen River, exceeding the 1933 Showa and 1960 Chilean tsunami inundations by factors of 6.2 and 2.7, respectively. The overland tsunami inundation distance was less than 2 km. The tsunami inundation height linearly decreased along the Kesen River at a rate of approximately 1 m/km. Nevertheless, the measured inland tsunami heights exhibit significant variations on local and regional scales. A designated “tsunami control forest” planted with a cross-shore width of about 200 m along a 2 km stretch of Rikuzentakata coastline was completely overrun and failed to protect the local community during this extreme event. Similarly, many designated tsunami shelters were too low and were overwashed by tsunami waves, thereby failing to provide shelter for evacuees—a risk that had been underestimated.     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.