230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.     

Arc-type and intraplate-type ridge basalts formed at the trench-trench-ridge tripIe junction: Implication for the extensive sub-ridge mantle heterogeneity

Abstract ' In situ basalts' represent the ridge magmatism at and close to the ancient trench-trench-ridge triple junction. Such basalts in the Amami, Mugi, and Setogawa accretionary complexes, Southwest Japan, were described and analysed. The geochemical data show that the ' in situ basalts' include all the types of basalts, ranging from alkali basalts and high-alumina basalts to tholeiites, and the compositions tend towards intermediate and silicic rocks. The data also reveal that the ridge basalts are indistinguishable both from the island arc and intraplate basalts, no affinities with mid-ocean-ridge basalts. The sub-ridge mantle adjacent to the triple junction had a component of sub-arc mantle, and this mantle heterogeneity can be generated by the formation of a slab window.     

Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.     

Production of the Blood Pressure Lowing Peptides from Brown Alga （ Undaria pinnatifida ）

Brown alga （ Undaria pinnatifida） was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme （ACE） was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats （SHRs）. The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ＇ Amano＇ （from Bacillus stearothermophilus） at the concentration of 10 （mg protein） （kg body weight）^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans.     

Non-Gaussian cosmic microwave background temperature fluctuations from peculiar velocities of clusters

We use numerical simulations of a (480 Mpc  h ⁻¹)³ volume to show that the distribution of peak heights in maps of the temperature fluctuations from the kinematic and thermal Sunyaev–Zeldovich (SZ) effects will be highly non-Gaussian, and very different from the peak-height distribution of a Gaussian random field. We then show that it is a good approximation to assume that each peak in either SZ effect is associated with one and only one dark matter halo. This allows us to use our knowledge of the properties of haloes to estimate the peak-height distributions. At fixed optical depth, the distribution of peak heights resulting from the kinematic effect is Gaussian, with a width that is approximately proportional to the optical depth; the non-Gaussianity comes from summing over a range of optical depths. The optical depth is an increasing function of halo mass and the distribution of halo speeds is Gaussian, with a dispersion that is approximately independent of halo mass. This means that observations of the kinematic effect can be used to put constraints on how the abundance of massive clusters evolves, and on the evolution of cluster velocities. The non-Gaussianity of the thermal effect, on the other hand, comes primarily from the fact that, on average, the effect is larger in more massive haloes, and the distribution of halo masses is highly non-Gaussian. We also show that because haloes of the same mass may have a range of density and velocity dispersion profiles, the relation between halo mass and the amplitude of the thermal effect is not deterministic, but has some scatter.