A new assessment model for evacuation vulnerability in urban areas

In the high-speed urbanization process of China, the urban population has been increasing significantly, leading to a high-density aggregation of population. However, the sharp increase in population density has not produced commensurate improvements in the road networks. On the contrary, the population increase induced a serious evacuation vulnerability, which cities experience during various hazards and catastrophic events. Therefore, research on evacuation vulnerability is important to urban planning. To assess the evacuation vulnerability, the optimal and worst scenarios should be considered because all possible evacuation plans occur between these extremes. However, most previous evacuation vulnerability studies are based on the worst-case scenario, only providing an upper bound of a potential evacuation assessment. To provide a more comprehensive theoretical basis for decision-makers to understand the consequences caused by all possible evacuations, this paper proposes an optimal evacuation vulnerability assessment model that provides the lower bound on potential evacuation difficulties. The model is solved by a stepwise spreading algorithm based on Graph Theory. Subsequently, to evaluate the effectiveness of the model, the study adopts the model to assess the evacuation capability of different road network topologies. A comparison with previous research was performed. The model was demonstrated in an application to the South Luogu Alley of Beijing, China. The significance of this paper is that the combination of our model with previous research may provide a more complete theoretical basis for an evacuation vulnerability assessment.     

Influence of urban expansion on the urban heat island effect in Shanghai

The urban heat island (UHI) effect resulting from rapid urbanization is attracting increasing attention among the global scientific community. This research analyzed the relationship between urban expansion and the UHI effect utilizing an integrated approach, including urban land interpretation and retrieving land surface temperature based on remote sensing, and spatial overlay analysis for revealing the relationship for different time periods between 1984 and 2014 in Shanghai, China. The results show that (1) the spatiotemporal changes in UHI are consistent with the expansion of urban land, and rapid urban expansion leads to an expansion of the UHI, in particular along roadways. (2) The mode of urban expansion is an important factor influencing the UHI effect. Urban sprawl (urban expansion in the edge-expansion way) is a form of typical expansion that leads to the rapid increase in the UHI. When the urban compactness ratio is less than 0.15, a compact design can effectively control the expansion rate of the UHI and mitigate its range of influence and intensity. However, when the urban compactness ratio is greater than 0.15, the urban design has a marked influence on the UHI ratio index: a more compact form produces a stronger UHI effect. So, finding an equilibrium between urban compactness ratio and urban expansion rate is good for effective urban management and planning.     

The characteristics of rill development and their effects on runoff and sediment yield under different slope gradients

Rill formation is the predominant erosion process in slope land in the Loess Plateau, China. This study was conducted to investigate rill erosion characteristics and their effects on runoff and sediment yielding processes under different slope gradients at a rate of 10°, 15°, 20° and 25° with rainfall intensity of 1.5 mm min-1 in a laboratory setting. Results revealed that mean rill depth and rill density has a positive interrelation to the slope gradient. To the contrary, width-depth ratio and distance of the longest rill to the top of the slope negatively related to slope gradient. All these suggested that increasing slope steepness could enhance rill headward erosion, vertical erosion and the fragmentation of the slope surface. Furthermore,total erosion tended to approach a stable maximum value with increasing slope, which implied that there is probably a threshold slope gradient where soil erosion begins to weaken. At the same time, the correlation analysis showed that there was a close connection between slope gradient and the variousindices of soil erosion: the correlation coefficients of slope gradient with maximal rill depth, number of rills and the distance of the longest rill from the top of the slope were 0.98, 0.97 and-0.98, respectively,indicating that slope gradient is the major factor of affecting the development of rills. Furthermore,runoff was not sensitive to slope gradient and rill formation in this study. Sediment concentration,however, is positively related to slope gradient and rill formation, the sediment concentrations increased rapidly after rill initiation, especially. These results may be essential for soil loss prediction.     

An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.     

The modeled atmospheric and oceanic response to the South China Sea SST anomaly

The sensitivity of the global atmospheric and oceanic response to sea surface temperature anomaly (SSTA) throughout the South China Sea (SCS) is investigated using the Fast Ocean-Atmosphere Model (FOAM). Forced by a warming SST, the experiment explicitly demonstrates that the responses of surface air temperature (SAT) and SST exhibit positive anomalous center over SCS and negative anomalous center over the Northern Pacific Ocean (NPO). The atmospheric response to the warm SST anomalies is characterized by a barotropical anomaly in middle-latitude, leading to a weak subtropical high in summer and a weak Aleutian low in winter. Accordingly, Indian monsoon and eastern Asian monsoon strengthen in summer but weaken in winter as a result of wind convergence owing to the warm SST. It is worth noting that the abnormal signals propagate poleward and eastward away in the form of Rossby Waves from the forcing region, which induces high pressure anomaly. Owing to action of the wind-driven circulation, an anomalous anti-cyclonic circulation is induced with a primary southward current in the upper ocean. An obvious cooling appears over the North Pacific, which can be explained by anomalous meridional cold advection and mixing as shown in the analysises of heat budget and other factors that affect SST.     

The Impact of Large-Scale Reclamation on Hydro-Dynamic Environment——A Case Study of Xinghua Bay

A hydro-dynamic model is established on basis of MIKE21 FM to simulate the hydro-dynamic characteristics of Xinghua Bay and investigate the influence of reclamation project on the tidal elevation and tidal currents. Tidal elevation data was obtained at the six tide gauge stations around the Xinghua Bay, and another six current stations were established to observe the tidal current velocity and direction. Validation shows that the model-simulated tidal elevation and tidal currents agree well with observations made at different stations. Predictions are made according to the reclamation project proposed in the regional marine planning of Hanjiang Industrial Park around the port in Putian City. The variations of hydro-dynamic factors, such as tide, current velocity and direction and tidal influx are obtained, and the adverse effect of reclamation on marine environment is discussed. It is shown that the tidal level inside the Xinghua Bay during high tide decreases after the reclamation project is completed. The tidal currents during flooding tide generally decrease in the southeast of the reclamation region, with the maximum decreasing amplitude reaching 0.44 m s^-1. On the other hand, the tidal currents during flooding tide increase around the southeast and southwest corners of the reclamation region. The tidal currents during ebb tide increase around the southeast and southwest corners of the reclamation region, with the maximum increasing amplitude attaining 0.18 m s^-1. The results in this paper can give some guidance for the marine environment management and the effective utilization of land in Putian.     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

西藏改则县多不扎地区上侏罗统对望山组的建立及意义

对望山组是发育在羌南板块南缘的一套岩石组合,以安山岩、流纹岩、玄武质凝灰岩为主,有少量的玄武安山岩夹层,具有明显的岩浆喷出相和沉积相韵律分布的特点。利用LA-ICP-MS同位素定年技术对对望山组安山岩中的锆石进行了U-Pb同位素测年,获得锆石的~(206)Pb/~(238)U年龄加权平均值为150.5±0.6Ma,表明对望山组的形成时代为晚侏罗世中晚期,在详细剖面测制和区域对比的基础上建立了对望山组。对望山组的建立对完善班公湖-怒江缝合带的地层系统、探讨班公湖-怒江洋的晚侏罗世构造演化具有重要的地质意义。