新疆贝勒库都克A型花岗岩锆石U-Pb年龄、地球化学及锡成矿

新疆东准噶尔卡拉麦里地区是一个重要的锡成矿带,分布有多种类型花岗岩。贝勒库都克岩体位于锡成矿带中部,由黑云母正长花岗岩和黑云母二长花岗岩组成。本文通过精确的LA-ICP-MS锆石U-Pb测年获得贝勒库都克含锡黑云母正长花岗岩年龄为283±2Ma,MSWD=0.14(95%置信度),时代属于早二叠世,这与东准噶尔后碰撞深成岩浆活动的范围(330~265Ma)相吻合。岩石地球化学研究表明,贝勒库都克岩体富硅(SiO2=75.25%~76.67%),低铝(Al2O3=11.91%~12.86%),贫镁(MgO=0.02%~0.18%)和钙(CaO=0.39%~0.89%),富碱(Na2O+K2O=8.08%~8.97%),K2O>Na2O,NK/A=0.86~0.95(平均0.92),A/NCK=0.97~1.02,富集Rb、K等大离子亲石元素及Zr、Hf等高场强元素,Ba,Nb,Sr强烈亏损,δEu=0.01~0.11,其FeOt/MgO(12.71~84.51,平均34.55)和10000Ga/A1(2.97~4.20)值大,HFSE元素(Zr+Nb+Ce+Y=191.8×10-6~353.3×10-6)含量高,明显不同于典型的I型和S型花岗岩,基本属于典型的铝质A型花岗岩。年代学和地球化学综合研究表明,贝勒库都克铝质A型花岗岩是壳幔混合成因,是准噶尔地区后碰撞幔源岩浆底侵作用导致大陆地壳垂向生长过程的记录者。贝勒库都克铝质A型花岗岩Sn的含量高(6.0×10-6~19.5×10-6,个别为80.0×10-6),铝质A型花岗岩是成矿热液的直接母体,而富Sn的流体相最终形成了贝勒库都克锡矿床,锡矿与铝质A型花岗岩是同期地质事件的产物。     

Geochemical characteristics,cooling history and mineralization significance of Zhangtiantang pluton in South Jiangxi Province,P.R. China

The zircon SHRIMP dating of the Zhangtiantang granite gave an age of 159±7 Ma., which shows that the granite was produced at the early Late Jurassic. The Ar-Ar plateau ages of biotite and K-feldspar from the Zhangtiantang pluton are 153.2±1.1 Ma and 135.8±1.2 Ma, respectively. The Ar-Ar anti-isochrone ages of biotite and K-feldspar are 152.5±1.7Ma and 135.4±2.7Ma, respectively. The ages represent the isotopic closure ages of minerals in the pluton. The Zhangtiantang granites are regarded as peraluminous crust-derived type granites to possess the typical geochemical characteristics of calc-alkaline rocks on continental margin, with enriched Si, K, Al (average value of A/CNK as 1.18), HREE, Rb, U, and Th, heavily depleted V, Cr, Co, Ni, Ti, Nb-Ta, Zr, Sr, P, and Ba, strongly negative Eu and common corundum normative (average value of C as 1.84). The εNd_(t) values of the Zhangtiantang granite are −5.84 to −7.79, and t _2DM values are 1.69 to 1.83 Ga, which indicates partial melting of continental-crust metamorphic sedimentary rocks during the Middle Proterozoic. The cooling history of the Zhangtiantang granitic pluton indicates that the cooling velocity of pluton was faster (about 67°C/Ma) from zircon (158 Ma) to biotite (152 Ma), and was slower (about12°C/Ma) from biotite (152.5 Ma) to K-feldspar (135.8 Ma). It can be deduced that the temporal gap (about 10 Ma) between the granite formmation and W-Sn mineralization in South China may be related to ordinary magma-hydrothermal processes by the variational cooling curve of the pluton. The Zhangtiantang pluton was formed in a compressive setting, with differentiation evolution and mineralization occurring in a relative relaxation setting.     

南秦岭佛坪隆起的成因探讨——构造解析的证据

通过对佛坪隆起基底及其周围地区构造面理和线理的系统测量和统计,恢复其古应力场,揭示区域构造应力场的分布规律,进而探讨佛坪隆起的成因机制。研究结果表明,佛坪隆起主体及其北部龙草坪隆起区外围地层中的构造片理呈外倾的封闭环状展布,结合古构造应力场分析,证明佛坪基底抬升主要生成于穹状隆起,这种穹状隆升与该区岩浆侵入活动密切相关。综合区域构造解析与古应力场分析表明,佛坪穹隆是在早期近垂向的穹状隆升的基础上,叠加了后期南北向挤压构造才奠定了其基本构造面貌。     

甘肃河西走廊早期冶炼活动及影响的炭屑化石记录

炭屑化石的显微结构研究是根据木材的解剖特征（组成木材的细胞与组织的形态和排列方式）确定燃烧植物的类型,重建古植被和古环境,探讨人类活动对环境的影响。火石梁和缸缸洼青铜冶炼点位于河西走廊西北部、黑河流域下游巴丹吉林南缘沙地中,散布了大量的炭屑化石遗存。通过炭屑化石3个切面（横切面、径切面和弦切面）显微结构特征研究,比对现代切片标本和木材解剖图版,识别和确定炭屑化石的木材种属,确定 2100～1860BC期间的青铜冶炼所用木材为柽柳、杨属、柳属、蓼科4种乔灌木植物,火石梁和缸缸洼地区大量乔、灌群落生长要比目前荒漠生态环境优越的多。先民的青铜冶炼活动导致乔木和灌木植物被大量砍伐,植被盖度急剧降低,对生态环境产生重大影响,是1900BC左右杨属、柳属和蓼科乔灌木植物基本消失的主要原因。     

淮河流域地下水资源调查评价与利用研究

在查明淮河流域地下水各含水岩组的水文地质特征、水资源总量、开采现状及存在的环境地质问题的基础上,对该区域地下水资源开发利用潜力进行了详细的评价,并提出了相应的治理措施及促进地下水资源可持续利用的对策,为该区未来更长时期水资源的合理配置和以水资源的可持续利用支撑经济社会的可持续发展提供科学依据。     

吉林延边地区浅成热液金(铜)矿床的~(40)Ar/~(39)Ar激光探针测年与成矿时代讨论

延边地区是中国东北部陆缘浅成热液金铜矿床发育的地区之一,广泛发育着浅成热液金矿床、中温热液金(铜)矿床和中深成中高温热液富金铜矿床(类斑岩型);富金铜矿床的成矿时代发生在105～102 Ma,为了进一步确定浅成热液金矿床与中深成中高温热液富金铜矿床的成矿动力学背景,采用流体包裹体的~(40)Ar/~(39)Ar激光探针定年法,对该区典型浅成热液金矿床进行了精细的年代学测定,获得刺猬沟金矿床、五星山金矿床和杜荒岭金矿床的脉石矿物石英流体包裹体的~(40)Ar/~(39)Ar等时线年龄分别为(141±7)Ma、(123±7)Ma和(107±6)Ma,其中刺猬沟金矿床((141±7)Ma)和五星山金矿床((123±7)Ma)的脉石矿物石英流体包裹体含有过剩放射性成因~(40)Ar,而杜荒岭金矿床((107±6)Ma)的脉石矿物石英流体包裹体几乎不含或含极少量过剩放射性成因~(40)Ar。结合最新获得的相关地质体的精细年代学成果,认定该区浅成热液金矿床成矿作用均发生在早白垩世晚期,或发生在早白垩世晚期火山喷发、浅成岩浆就位之后,其形成环境与富金铜矿床一致,为古太平洋板块向亚洲大陆正北向俯冲转入Izanagi-Farallon板块西向俯冲的构造转换期。     

Cracking mechanisms during galena mineralization in a sandstone-hosted lead–zinc ore deposit: case study of the Jinding giant sulfide deposit, Yunnan, SW China

There are two types of lead–zinc ore bodies, i.e., sandstone-hosted ores (SHO) and limestone-hosted ores (LHO), in the Jinding giant sulfide deposit, Yunnan, SW China. Structural analysis suggests that thrust faults and dome structures are the major structural elements controlling lead–zinc mineralization. The two types of ore bodies are preserved in two thrust sheets in a three-layered structural profile in the framework of the Jinding dome structure. The SHO forms the cap of the dome and LHO bodies are concentrated beneath the SHO cap in the central part of the dome. Quartz, feldspar and calcite, and sphalerite, pyrite, and galena are the dominant mineral components in the sandstone-hosted lead–zinc ores. Quartz and feldspar occur as detrital clasts and are cemented by diagenetic calcite and epigenetic sulfides. The sulfide paragenetic sequence during SHO mineralization is from early pyrite to galena and late sphalerite. Galena occurs mostly in two types of cracks, i.e., crescent-style grain boundary cracks along quartz–pyrite, or rarely along pyrite–pyrite boundaries, and intragranular radial cracks in early pyrite grains surrounding quartz clasts. The radial cracks are more or less perpendicular to the quartz–pyrite grain boundaries and do not show any overall (whole rock) orientation pattern. Their distribution, morphological characteristics, and geometrical relationships with quartz and pyrite grains suggest the predominant role of grain-scale cracking. Thermal expansion cracking is one of the most important mechanisms for the generation of open spaces during galena mineralization. Cracking due to heating or cooling by infiltrating fluids resulted from upwelling fluid phases through fluid passes connecting the SHO and LHO bodies, provided significant spaces for crystallization of galena. The differences in coefficients of thermal expansion between pyrite and quartz led to a difference in volume changes between quartz grains and pyrite grains surrounding them and contributed to cracking of the pyrite grains when temperature changed. Combined thermal expansion and elastic mismatch due to heating and subsequent cooling resulted in the radial and crescent cracking in the pyrite grains and along the quartz–pyrite grain boundaries.     

Palynological records of Holocene monsoon change from the Gulf of Tonkin (Beibuwan), northwestern South China Sea

Palynological records in cores C4 and B106 from the Gulf of Tonkin reveal signals of paleo-monsoon and paleoenvironmental change during the late Pleistocene and Holocene. Before ∼ 13.4 cal kyr BP, the Gulf of Tonkin was exposed to the atmosphere and covered by grassland. Starting at ∼ 11.7 cal kyr BP, the Gulf of Tonkin was inundated by brackish water, indicated by the appearance of the brackish algae Cleistosphaeridium, Sentusidinium and Spiniferites, a decrease of herb content, and an increase of Pinus. After Hainan Island was completely separated from the Leizhou Peninsula by Qiongzhou Strait at ∼ 8.5 cal kyr BP, a continuous marine sedimentary environment was found. The current patterns were similar to those of the present, with a general trend of current homogenization reflected by gradually decreasing quantities of Quercus pollen and a narrowing gap between the palynological concentrations of the southern and northern parts of the region. The data suggest that three short periods of strengthened winter monsoons and currents were centered at ∼ 6.0 cal kyr BP, ∼ 2.7 cal kyr BP and ∼ 0.2 cal kyr BP and that two short periods of strengthened summer monsoons and currents were centered at ∼ 7.5 cal kyr BP and ∼ 3.4 cal kyr BP.     

Zircon U–Pb ages and tectonic implications of Paleozoic plutons in northern West Junggar,North Xinjiang,China

North Xinjiang, Northwest China, is made up of several Paleozoic orogens. From north to south these are the Chinese Altai, Junggar, and Tian Shan. It is characterized by widespread development of Late Carboniferous–Permian granitoids, which are commonly accepted as the products of post-collisional magmatism. Except for the Chinese Altai, East Junggar, and Tian Shan, little is known about the Devonian and older granitoids in the West Junggar, leading to an incomplete understanding of its Paleozoic tectonic history. New SHRIMP and LA-ICP-MS zircon U–Pb ages were determined for seventeen plutons in northern West Junggar and these ages confirm the presence of Late Silurian–Early Devonian plutons in the West Junggar. New age data, combined with those available from the literature, help us distinguish three groups of plutons in northern West Junggar. The first is represented by Late Silurian–Early Devonian (ca. 422 to 405 Ma) plutons in the EW-striking Xiemisitai and Saier Mountains, including A-type granite with aegirine–augite and arfvedsonite, and associated diorite, K-feldspar granite, and subvolcanic rocks. The second is composed of the Early Carboniferous (ca. 346 to 321 Ma) granodiorite, diorite, and monzonitic and K-feldspar granites, which mainly occur in the EW-extending Tarbgatay and Saur (also spelled as Sawuer in Chinese) Mountains. The third is mainly characterized by the latest Late Carboniferous–Middle Permian (ca. 304 to 263 Ma) granitoids in the Wuerkashier, Tarbgatay, and Saur Mountains.As a whole, the three epochs of plutons in northern West Junggar have different implications for tectonic evolution. The volcano-sedimentary strata in the Xiemisitai and Saier Mountains may not be Middle and Late Devonian as suggested previously because they are crosscut by the Late Silurian–Early Devonian plutons. Therefore, they are probably the eastern extension of the Early Paleozoic Boshchekul–Chingiz volcanic arc of East Kazakhstan in China. It is uncertain at present if these plutons might have been generated in either a subduction or post-collisional setting. The early Carboniferous plutons in the Tarbgatay and Saur Mountains may be part of the Late Paleozoic Zharma–Saur volcanic arc of the Kazakhstan block. They occur along the active margin of the Kazakhstan block, and their generation may be related to southward subduction of the Irtysh–Zaysan Ocean between Kazakhstan in the south and Altai in the north. The latest Late Carboniferous–Middle Permian plutons occur in the Zharma–Saur volcanic arc, Hebukesaier Depression, and the West Junggar accretionary complexes and significantly postdate the closure of the Irtysh–Zaysan Ocean in the Late Carboniferous because they are concurrent with the stitching plutons crosscutting the Irtysh–Zaysan suture zone. Hence the latest Late Carboniferous–Middle Permian plutons were generated in a post-collisional setting. The oldest stitching plutons in the Irtysh–Zaysan suture zone are coeval with those in northern West Junggar, together they place an upper age bound for the final amalgamation of the Altai and Kazakhstan blocks to be earlier than 307 Ma (before the Kaslmovian stage, Late Carboniferous). This is nearly coincident with widespread post-collisional granitoid plutons in North Xinjiang.     

超微量钐同位素的热表面电离质谱分析

采用双带测量方式,法拉第杯和离子计数器同时接收与跳峰接收相结合,建立了超微量钐同位素的热表面电离质谱的测量方法。优化了制样程序和质谱测量程序,研究了蒸发带电流对离子流强度的影响,考察了从纳克至微克不同样品用量的测量效果及其中Nd、Eu干扰核素的情况。对4 ng~2μg的天然丰度钐样品进行了同位素比值分析,相对标准偏差均小于1.1%。