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The systematic UBV observations of six variable post-AGB supergiants in 1991–1999 are presented. Their variability is analyzed. The coolest stars V1027 Cyg and V354 Lac exhibit bimodal pulsations with variable amplitudes. Apart from pulsations, the hotter stars V887 Her and IRAS 19386+0155 show light variations associated with a stellar wind. A variable stellar wind appears to be mainly responsible for the photometric variations in the still hotter stars SAO 163075 and IRAS 20572+4919. Distinct trends in the yearly mean brightness have been found in three of the six supergiants studied, with the trend amplitude being independent of the spectral range. They are interpreted as the result of dust envelopes composed of large grains with R=A V /E(B?V)≥7 becoming optically thin. 相似文献
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An experimental study on the origin of ferric and ferrous carbonate-silicate melts, which can be considered as the potential metasomatic oxidizing agents and diamond forming media, was performed in the (Ca,Mg)CO3-SiO2-Al2O3-(Mg,Fe)(Cr,Fe,Ti)O3 system, at 6.3 GPa and 1350–1650 °C. At 1350–1450 °C and ?O2 of FMQ + 2 log units, carbonate–silicate melt, coexisting with Fe3 +-bearing ilmenite, pyrope-almandine and rutile, contained up to 13 wt.% of Fe2O3. An increase in the degree of partial melting was accompanied by decarbonation and melt enrichment with CO2, up to 21 wt.%. At 1550–1650 °C excess CO2 segregated as a separate fluid phase. The restricted solubility of CO2 in the melt indicated that investigated system did not achieve the second critical point at 6.3 GPa. At 1350–1450 °C and ?O2 close to CCO buffer, Fe2 +-bearing carbonate–silicate melt was formed in association with pyrope-almandine and Fe3 +-bearing rutile. It was experimentally shown that CO2-rich ferrous carbonate-silicate melt can be an effective waterless medium for the diamond crystallization. It provides relatively high diamond growth rates (3–5 μm/h) at P,T-conditions, corresponding to the formation of most natural diamonds. 相似文献
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Summary
Anhydrous iron, aluminum and fluorine-rich paralavas were found in the burned spoil-heaps of the Chelyabinsk coal basin, Russia.
The rocks contain tridymite, anorthite, ferroan fluorine-bearing cordierite, fluorine-bearing mullite, periclase, fluorapatite,
micas of the F-biotite–F-phlogopite series, fluortopaz, fluorite, and sellaite. The fluorine-rich minerals formed as a result
of local thermal reactions of sedimentary carbonates and silicates with gaseous fluorine. During coal combustion fluorine
concentrates in the annealed ankeritic marls where the increase of F is hundreds of times over its concentration in the initial
sedimentary rocks. The formation of MgF2 and CaF2 promotes local melting at relatively low temperatures (T < 1000 °C) with the residuum consisting of two immiscible liquids.
One crystallises as the fluorides, the other as fluorine-substituted analogues of the hydrosilicates, which under the extremely
dry conditions, produce minerals containing extremely high F-contents.
Received April 10, 2000; revised version accepted February 24, 2001 相似文献
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Alexander?G.?SokolEmail authorView authors OrcID profile Anatoly?A.?Tomilenko Taras?A.?Bul’bak Alexey?N.?Kruk Pavel?A.?Zaikin Ivan?A.?Sokol Yurii?V.?Seryotkin Yury?N.?Palyanov 《Contributions to Mineralogy and Petrology》2018,173(6):47
Interactions in a Fe–C–O–H–N system that controls the mobility of siderophile nitrogen and carbon in the Fe0-saturated upper mantle are investigated in experiments at 6.3–7.8 GPa and 1200–1400 °C. The results show that the γ-Fe and metal melt phases equilibrated with the fluid in a system unsaturated with carbon and nitrogen are stable at 1300 °C. The interactions of Fe3C with an N-rich fluid in a graphite-saturated system produce the ε-Fe3N phase (space group P63/mmc or P6322) at subsolidus conditions of 1200–1300 °C, while N-rich melts form at 1400 °C. At IW- and MMO-buffered hydrogen fugacity (fH2), fluids vary from NH3- to H2O-rich compositions (NH3/N2?>?1 in all cases) with relatively high contents of alkanes. The fluid derived from N-poor samples contains less H2O and more carbon which mainly reside in oxygenated hydrocarbons, i.e., alcohols and esters at MMO-buffered fH2 and carboxylic acids at unbuffered fH2 conditions. In unbuffered conditions, N2 is the principal nitrogen host (NH3/N2?≤?0.1) in the fluid equilibrated with the metal phase. Relatively C- and N-rich fluids in equilibrium with the metal phase (γ-Fe, melt, or Fe3N) are stable at the upper mantle pressures and temperatures. According to our estimates, the metal/fluid partition coefficient of nitrogen is higher than that of carbon. Thus, nitrogen has a greater affinity for iron than carbon. The general inference is that reduced fluids can successfully transport volatiles from the metal-saturated mantle to metal-free shallow mantle domains. However, nitrogen has a higher affinity for iron and selectively accumulates in the metal phase, while highly mobile carbon resides in the fluid phase. This may be a controlling mechanism of the deep carbon and nitrogen cycles. 相似文献