Fayalite-sekaninaite paralava from the Ravat coal fire (central Tajikistan)

We studied ferrous paralava, a high-temperature rock, produced by complete fusion of the sedimentary protolith in the Ravat natural coal fire which has been on for over two thousand years. The paralava was sampled from the Fan-Yagnob coal deposit at the Kukhi-Malik site in the vicinity of former Ravat Village in central Tajikistan. This rock contains fayalite, sekaninaite, hercynite, Ti-magnetite, tridymite, and siliceous glass. Low-Ca pyroxene (clinoferrosilite), globules of sulfides (mainly pyrrhotite) and Fe-Ti oxides, secondary greenalite (after fayalite) and hematite are minor. Paralava includes xenoliths of partially molten clinkers (up to 20 vol.%) composed of mullite, cordierite, tridymite, and relict detrital quartz. We found relatively high Fe contents (100?Fe/(Fe+Mg) > 60) in mafic minerals, high K₂O enrichment (up to 1.4 wt.%) in sekaninaite, and an unusually low CaO content (0.5 wt.%) in the rock. The Ravat paralava appears to be derived from a mixture of pelitic rocks (50–70%) and iron-rich rocks (30–50%), but without participation of calcareous material, which explains the low CaO and the absence of plagioclase and Ca-bearing pyroxene. The primary melt was as hot as >1210 °C, and the coal-fired fayalite-sekaninaite paralava crystallized at 1200–1100 °C, at a relatively low oxygen fugacity (near the QFM buffer), outside the zone of active aeration. Large-scale crystallization of ferrospinels and fayalite led to increasing Al₂O₃ and SiO₂ in the melt whence sekaninaite and tridymite crystallized as later phases. The residual melt progressively acquired a more silicic-aluminous composition, rich in K₂O, CaO, and P₂O₅, and became quenched to glass at >1080–1090 °C, when temperature dropped abruptly, possibly, by roof collapse or opening of large cracks, as it usually happens in underground coal fires.     

Paragenesis of unusual Fe-cordierite (sekaninaite)-bearing paralava and clinker from the Kuznetsk coal basin,Siberia, Russia

Sekaninaite (X_Fe > 0.5)-bearing paralava and clinker are the products of ancient combustion metamorphism in the western part of the Kuznetsk coal basin, Siberia. The combustion metamorphic rocks typically occur as clinker beds and breccias consisting of vitrified sandstone–siltstone clinker fragments cemented by paralava, resulting from hanging-wall collapse above burning coal seams and quenching. Sekaninaite–Fe-cordierite (X_Fe = 95–45) is associated with tridymite, fayalite, magnetite, ± clinoferrosilite and ±mullite in paralava and with tridymite and mullite in clinker. Unmelted grains of detrital quartz occur in both rocks (<3 vol% in paralavas and up to 30 vol% in some clinkers). Compositionally variable siliceous, K-rich peraluminous glass is <30% in paralavas and up to 85% in clinkers. The paralavas resulted from extensive fusion of sandstone–siltstone (clinker), and sideritic/Fe-hydroxide material contained within them, with the proportion of clastic sediments ≫ ferruginous component. Calculated dry liquidus temperatures of the paralavas are 1,120–1,050°C and 920–1,050°C for clinkers, with calculated viscosities at liquidus temperatures of 10^1.6–7.0 and 10^7.0–9.8 Pa s, respectively. Dry liquidus temperatures of glass compositions range between 920 and 1,120°C (paralava) and 920–960°C (clinker), and viscosities at these temperatures are 10^9.7–5.5 and 10^8.8–9.7 Pa s, respectively. Compared with worldwide occurrences of cordierite–sekaninaite in pyrometamorphic rocks, sekaninaite occurs in rocks with X_Fe (mol% FeO/(FeO + MgO)) > 0.8; sekaninaite and Fe-cordierite occur in rocks with X_Fe 0.6–0.8, and cordierite (X_Fe < 0.5) is restricted to rocks with X_Fe < 0.6. The crystal-chemical formula of an anhydrous sekaninaite based on the refined structure is | \textK_0.02 |(\textFe_1.54^{2 +} \textMg_0.40 \textMn_0.06 )_{\Upsigma 2.00}^M [(\textAl_1.98 \textFe_0.02^{2 +} \textSi_1.00 )_{\Upsigma 3.00}^T1 (\textSi_3.94 \textAl_2.04 \textFe_0.02^{2 +} )_{\Upsigma 6.00}^T2 \textO₁₈ ]. \left| {{\text{K}}_{0.02} } \right|({\text{Fe}}_{1.54}^{2 + } {\text{Mg}}_{0.40} {\text{Mn}}_{0.06} )_{\Upsigma 2.00}^{M} [({\text{Al}}_{1.98} {\text{Fe}}_{0.02}^{2 + } {\text{Si}}_{1.00} )_{\Upsigma 3.00}^{T1} ({\text{Si}}_{3.94} {\text{Al}}_{2.04} {\text{Fe}}_{0.02}^{2 + } )_{\Upsigma 6.00}^{T2} {\text{O}}_{18} ].     

Diamond formation in the system MgO–SiO2–H2O–C at 7.5 GPa and 1,600°C

Diamond crystallization has been studied in the SiO₂–H₂O–С, Mg₂SiO₄–H₂O–С and H₂O–С subsystems at 7.5 GPa and 1,600°C. We found that dissolution of initial graphite is followed by spontaneous nucleation of diamond and growth of diamond on seed crystals. In 15-h runs, the degree of graphite to diamond transformation [α = M_Dm/(M_Dm + M_Gr)100, where M_Dm is mass of obtained diamond and M_Gr mass of residual graphite] reached 100% in H₂O-rich fluids but was only 35–50% in water-saturated silicate melts. In 40-h runs, an abrupt decrease of α has been established at the weight ratio H₂O/(H₂O + SiO₂) ≤ 0.16 or H₂O/(H₂O + Mg₂SiO₄) ≤ 0.15. Our results indicate that α is a function of the concentration of water, which controls both the kinetics of diamond nucleation and the intensity of carbon mass transfer in the systems. The most favorable conditions for diamond crystallization in the mantle silicate environment at reliable PT-parameters occur in the fluid phase with low concentration of silicates solute. In H₂O-poor silicate melts diamond formation is questionable.     

Composition of a carbonatitic melt in equilibrium with lherzolite at 5.5–6.3 GPa and 1350°C

Generation of ultra-alkaline melts by the interaction of lherzolite with cardonatites of various genesis was simulated at the P–T parameters typical of the base of the subcratonic lithosphere. Experiments with a duration of 150 h were performed at 5.5 and 6.3 GPa and 1350°C. The concentrations of CaO and MgO in melts are buffered by the phases of peridotite, and the concentrations of alkalis and FeO depend on the composition of the starting carbonatite. Melts are characterized by a low (<7 wt %) concentration of SiO₂ and Ca# from 0.40 to 0.47. It is demonstrated that only high-Mg groups of carbonatitic inclusions in fibrous diamonds have a composition close to that of carbonatitic melts in equilibrium with lherzolite. Most likely, the formation of kimberlite-like melts relatively enriched in SiO₂ requires an additional source of heat from mantle plumes and probably H₂O fluid.     

Tropical cyclone Ivan’s tornado cluster in the Mid-Atlantic region of the United States on 17–18 September 2004

This paper presents a case study of a cluster of tornadoes produced by tropical cyclone (TC) Ivan in the Mid-Atlantic region of the United States on 17–18 September 2004. Ivan produced 118 tornadoes between 15 and 18 September, but 57 of these occurred in a period of only 10 h on the last two days. The number of tornadoes that occurred in this event is anomalous when compared to regional tornado climatology and to other TC tornado events. Furthermore, a significantly large number of the tornadoes, when compared to other TC tornadoes, were rated strong according to the Fujita Scale, and they were anomalously long- and wide-tracked. Ivan was in a synoptically favorable environment when these tornadoes were produced, and the tornadoes occurred in a favorable local-scale environment near a front with spatially overlapping shear and buoyancy.     

Mud Volcanic Fluids of the Kerch–Taman Region: Geochemical Reconstructions and Regional Trends: Communication 2. Genesis of Mud Volcanic Gases and Regional Geochemical Trends

Lithology and Mineral Resources - The chemical and isotopic signatures of mud volcanic fluids were determined for 42 mud volcanoes of the Kerch–Taman region (Crimea–Caucasus district)....     

The Use of Radar and Gauge Measurements to Estimate Areal Precipitation for Several Czech River Basins

Two methods estimating areal precipitation for selected river basins in the Czech Republic are compared. The methods use radar precipitation (the radar-derived precipitation estimate based on column maximum reflectivity) and data from 81 on-line rain gauges routinely provided by the Czech Hydrometeorological Institute. Data from a dense network of climatological rain gauges (the average inter-station distance is approximately 8 km), the measurements of which are not available in real time, are utilized for the verification. The mean areal precipitation, which is used as the ground truth, is obtained by the weighted interpolation of the dense rain gauge network. The accuracy of the methods is evaluated by the root-mean-square-error.The first, pixel-related method merges radar precipitation with rain gauge data to obtain adjusted pixel values. The adjusting procedure combines radar and gauge values in one variable that is interpolated into all radar pixels. The adjusted pixel precipitation is calculated from radar precipitation and from the value of the combined variable. The areal estimates are determined by adding the corresponding pixel values. The second method applies a linear regression model to describe the relationship between the areal precipitation (dependent variable) and its estimates, which are determined from (i) non-adjusted radar precipitation and (ii) on-line rain gauge measurements interpolated into pixels. Classical linear regression, ridge regression and robust regression models are tested.Both the methods decrease the average areal error in comparison with the reference method, which uses the on-line rain gauge data only. The decrease is about 10% and 15% for the pixel-related and regression methods, respectively. When the estimates of the pixel-related method are included as predictors into the regression method then the improvement of accuracy is almost 25%.     

Die geologische Methodik

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