The generation kinetics of natural gases in the Kela-2 gas field from the Kuqa Depression, Tarim Basin, northwestern China

The Kela-2 gas field, found in the Kuqa Depression of the Tarim Basin, northwestern China, is a large-sized dry gas field (C1 /C1-5 =0.992 0.999) and characterized by ultra-high pressure (pressure factor up to 2.0 2.2). The pyrolysis experiment was carried out under isothermal gold-tube closed system, with samples collected from the Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Depression. The result of gas yield showed that the Middle and Lower Jurassic source rocks have higher gas generation potential than the Triassic source rocks. The kinetic modeling of gas generation and methane carbon isotope fractionation suggested that the Kela-2 gases belong to the products of high-over mature stages and were mainly derived from the Middle and Lower Jurassic coal-bearing strata. The Triassic source rocks made a minor contribution to the Kela-2 gases. The Kela-2 gases chiefly generated from coal-bearing source rocks with R o values from 1.3% to 2.5%, and thus primarily accumulated after 5 Ma.     

煤矸石山的危害及植被生态重建途径探讨

长期的采矿活动使煤矿区大量的煤矸石堆积形成煤矸石山,成为矿区环境污染和恶化的主要因素之一。煤矸石山对矿区造成的危害主要包括引发火灾、破坏矿区景观、污染环境、形成地质灾害等。提出了植被生态重建治理煤矸石山的措施,其主要技术手段包括煤矸石山立地条件分析、山地整形、基质改良、植物种类选择和栽培等。通过合理的规划设计,最终实现矸石山稳定的植被生态系统。      

SPATIALLY DISTRIBUTED WATER SURFACE TEMPERATURE MODELING FOR THE GREAT LAKES

1　INTRODUCTIONA Growing concern over the potential effects of a possible change in the future climatecontinues to motivate research into cycles,variability,and trends in the temperatures of theGreat L akes.These temperatures have a major influence on the water balance of the GreatL akes watershed through evaporation and the forcing of atmospheric effects.Before a futuretemperature structure and cycle can be estimated,the present water temperature climatologymust be sucessfully simulated…     

藏、汉对比视角下的城市空间环境认知研究——以中国西藏日喀则市为例

以分布式认知理论为基础,采用质性研究法、数量分析法以及GIS空间分析技术,探讨日喀则市藏族、汉族居民对城市空间环境认知的异同性。研究表明,藏族对城市空间环境的认知得分高于汉族对城市空间环境的认知得分。藏族、汉族对城市空间环境的认知水平可分为高、中、低3类。认知空间呈现圈层结构与混合结构模式,可分为藏汉一致性、藏族独立以及汉族独立3种认知空间类型。影响居民对城市空间环境的认知因素有共性因素和差异性因素。景观走廊质量、宜居性、基础设施两项是藏族居民关注的主要影响因素,汉族居民更关注公共服务设施的服务能力以及对当地文化的融入感。     

基于支持向量机的GNSS时间序列预测

在深度学习的理论框架下,针对预测全球卫星导航系统(GNSS)时间序列,传统的经验风险最小化预测模型误差大精度低,泛化性能差且对历史数据的经验依赖大的问题.提出一种采用结构风险最小化原则的基于支持向量机(SVM)的时间序列预测模型.通过和多层的BP神经网络预测模型预测效果比较,结果证明SVM预测模型拥有更好的时间序列预测效果.     

Theoretical study on the reactivity of sulfate species with hydrocarbons

The abiotic, thermochemically controlled reduction of sulfate to hydrogen sulfide coupled with the oxidation of hydrocarbons, is termed thermochemical sulfate reduction (TSR), and is an important alteration process that affects petroleum accumulations in nature. Although TSR is commonly observed in high-temperature carbonate reservoirs, it has proven difficult to simulate in the laboratory under conditions resembling nature. The present study was designed to evaluate the relative reactivities of various sulfate species in order to provide greater insight into the mechanism of TSR and potentially to fill the gap between laboratory experimental data and geological observations. Accordingly, quantum mechanics density functional theory (DFT) was used to determine the activation energy required to reach a potential transition state for various aqueous systems involving simple hydrocarbons and different sulfate species. The entire reaction process that results in the reduction of sulfate to sulfide is far too complex to be modeled entirely; therefore, we examined what is believed to be the rate limiting step, namely, the reduction of sulfate S(VI) to sulfite S(IV). The results of the study show that water-solvated sulfate anions are very stable due to their symmetrical molecular structure and spherical electronic distributions. Consequently, in the absence of catalysis, the reactivity of is expected to be extremely low. However, both the protonation of sulfate to form bisulfate anions () and the formation of metal-sulfate contact ion-pairs could effectively destabilize the sulfate molecular structure, thereby making it more reactive.Previous reports of experimental simulations of TSR generally have involved the use of acidic solutions that contain elevated concentrations of relative to . However, in formation waters typically encountered in petroleum reservoirs, the concentration of is likely to be significantly lower than the levels used in the laboratory, with most of the dissolved sulfate occurring as , aqueous calcium sulfate ([CaSO₄]_(aq)), and aqueous magnesium sulfate ([MgSO₄]_(aq)). Our calculations indicate that TSR reactions that occur in natural environments are most likely to involve bisulfate ions () and/or magnesium sulfate contact ion-pairs ([MgSO₄]_CIP) rather than ‘free’ sulfate ions () or solvated sulfate ion-pairs, and that water chemistry likely plays a significant role in controlling the rate of TSR.     

渐进制度变迁模式下中国城市转型测度的空间分异

以中国286个地级及以上行政单元为研究对象,基于2003~2013年的劳动力、企业等制度指标,采用空间插值等方法,探讨了中国城市制度转型水平及其效应机制。研究表明：① 空间上,制度转型结果及其效应总体上在2003~2013年都表现为从东部沿海向内陆地区的梯度衰减模式。时间上,制度转型及其引发的效应整体上表现为逐步强化,其中,制度转型效应表现为由2003年的“零星分布”向2008年“线状蔓延”进而向2013年“面状拓展”的空间演化特征。② 以城市群为核心的相关区域,其制度转型结果与效应大致呈现为圈层结构模式。③ 中西部地区（除成渝城市群外）的制度转型结果及其效应高值中心大都为单个城市。④ 制度转型对城市转型效应影响显著,且随着时间的推移明显增强。     

山东海化集团排污对附近海域环境影响及防治对策

对山东海化集团所排放污染物的调查与监测表明，其废水排放量为1738万t/a，其中石油类为135t/a，悬浮物为1425t/a，氨氮为469t/a，化学耗氧量为3476t/a。海上监测资料显示，海化集团附近海域中挥发酚、油类、COD的含量超过国家二类水质标准，平均污染指数分别为：2．30、1．56、1．22，比正常状况分别提高了0．28、0．18、0．37。分析结果表明，海化集团尽管是排放达标企业，但由于企业生产规模巨大，污染物排海量依然很大，排污对其附近海域生产了一定影响。文章同时提出了有关污染防治对策。     

坐底式整平船对流场影响的试验研究

通过整平船在长江口南导堤 Se段工程对流场影响的模型试验 ,得出各断面在不同潮位、流速、流向情况下 ,只有导堤和有整平船作业时会对周围流场有影响 ,为施工方案的比选以及施工中应采取的措施提供了可靠的依据。     

Uncertainty and joint probability of sea ice loads

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