Pristine and reacted surfaces of pyrrhotite and arsenopyrite as studied by X-ray absorption near-edge structure spectroscopy

Fe L-, S L-, and O K-edge X-ray absorption spectra of natural monoclinic and hexagonal pyrrhotites, Fe_1-xS, and arsenopyrite, FeAsS, have been measured and compared with the spectra of minerals oxidized in air and treated in aqueous acidic solutions, as well as with the previous XPS studies. The Fe L-edge X-ray absorption near-edge structure (XANES) of vacuum-cleaved pyrrhotites showed the presence of, aside from high-spin Fe²⁺, small quantity of Fe³⁺, which was higher for a monoclinic mineral. The spectra of the essentially metal-depleted surfaces produced by the non-oxidative and oxidative acidic leaching of pyrrhotites exhibit substantially enhanced contributions of Fe³⁺ and a form of high-spin Fe²⁺ with the energy of the 3d orbitals increased by 0.3–0.8 eV; low-spin Fe²⁺ was not confidently distinguished, owing probably to its rapid oxidation. The changes in the S L-edge spectra reflect the emergence of Fe³⁺ and reduced density of S s–Fe 4s antibonding states. The Fe L-edge XANES of arsenopyrite shows almost unsplit e_g band of singlet Fe²⁺ along with minor contributions attributable to high-spin Fe²⁺ and Fe³⁺. Iron retains the low-spin state in the sulphur-excessive layer formed by the oxidative leaching in 0.4 M ferric chloride and ferric sulphate acidic solutions. The S L-edge XANES of arsenopyrite leached in the ferric chloride, but not ferric sulphate, solution has considerably decreased pre-edge maxima, indicating the lesser admixture of S s states to Fe 3d orbitals in the reacted surface layer. The ferric nitrate treatment produces Fe³⁺ species and sulphur in oxidation state between +2 and +4.     

碎冰条件下单点系泊船舶动态响应特性研究

为了研究不同单点系泊位置对极地系泊船舶在来冰角度改变时动态响应的影响,运用离散元方法(DEM),计算了船舶在60%密集度下,冰速为1.0 m/s、冰厚为1 m时不同角度的船冰阻力,结合系泊分析软件二次开发功能,计算分析系泊船舶在不同来冰角度和不同系泊位置下受上述冰情影响下的响应。通过对模拟结果与试验结果的对比,认为离散元方法(DEM)的数值模拟结果与试验结果吻合较好;单点系泊位置为距船头L/4时,系泊船舶能以最快速、最稳定的方式对来冰方向的变化做出响应。     

文学地理学视野下香港文化认同

通过文本分析和档案分析的方法,立足文学地理学分析框架和研究范式,分析了香港70年代、过渡时期、后殖民时期三部文学界热门且公认具代表性的作品——《我城》《烦恼娃娃的旅程》和《后殖民食物与爱情》,解构了作品中“本土”“国家”和“全球”3个空间维度下再现的地理物象、空间想象、人物活动、地方文化,窥探其内部隐含的文化认同与身份意识问题。结果发现,由于香港社会历史和文化背景不断变迁等原因,香港的文化和身份意识处于不断重塑的状态。通过文本分析,发现香港文学作品中最早萌芽的是“本土”意识。西西的《我城》被认为是本土意识的发轫之作,其在港英政府和回不去的家这一夹缝中在“城”这一空间尺度上勾勒出浓浓的地方意识。其次,在中国恢复行使香港主权这一背景下,《烦恼娃娃的旅程》这一极具回归题材代表性的作品深刻地刻画了香港人在身份认同尺度升级过程中的迷惘。最后,也斯的《后殖民食物与爱情》通过“食物”为线索讲述了回归后的香港故事,为读者认识后殖民时期多元文化混杂下的香港社会提供了细致的观察。通过对三部文学作品的分析,发现港人经历了由殖民统治时期本土身份意识的觉醒以及对中国文化的归属,到回归过渡阶段身份意识的尺度升级及其不适,再到回归后多元文化的交织和协商,不仅在尺度上实现了由地方到国家再到全球化的身份意识塑造,而且在结构上存在中华文化、西方文化和香港本土文化不断协商与冲突的三重性。更为重要的是,通过文学地理视角的讨论,发现这样的文化和身份意识不是属于某个群体的特有特征,而是根植于香港社会的每一寸肌肤,不仅反映了小说作者对香港社会的细致观察,在一定程度上也反映了社会本身所面临的文化和身份困扰。     

用随机有限断层方法模拟2016-11-13新西兰Mw7.8地震

在未来大地震发震构造已知的前提下，提出用经验公式确定大地震断层长度、宽度、地震矩和滑动分布等参数，并用随机有限断层方法预测未来大地震。用随机有限断层方法模拟2016-11-13新西兰M_W7.8地震的12个基岩台站地震动时程和反应谱，并用模拟的频谱幅值与记录频谱幅值平均比值确定模拟误差。结果表明，在周期为0~10 s的范围内，模拟误差在0.92~1.08之间，不同频率模拟误差的标准差变化范围不超过1。95%的置信区间宽度随频率无明显变化，模拟结果反映了地震动记录的平均效果。用准随机方法重新获取新西兰大地震断层初始破裂点和位错滑动分布，模拟地震动并计算模拟误差随频率的变化，得到与最初模型相似的结论，从而进一步证实了本文提出的获取震源参数并用随机有限断层方法预测未来大地震的可靠性，且其特别适用于大地震远场模拟。     

Analytical modeling on consolidation of stiffened deep mixed column-reinforced soft soil under embankment

Stiffened deep mixed (SDM) column is a new ground improvement technique to improve soft soil, which can be used to increase bearing capacity, reduce deformation, and enhance stability of soft soil. This technique has been successfully adopted to support the highway and railway embankments over soft soils in China and other countries. However, there have been limited investigations on its consolidation under embankment loading. This paper developed an analytical solution for the consolidation of embankment over soft soil with SDM column in which core pile is equal to or shorter than outer DM column. The consolidation problem was simplified as a consolidation of composite soil considering the load shear effect of core pile. The developed solution was verified by a comparison with the results computed by three-dimensional (3-D) finite element analysis. A parametric study based on the derived solution was conducted to investigate influence factors—length of core pile, diameter of core pile, diameter of SDM column, modulus of DM column, and permeability coefficient of DM column—on the consolidation behavior of SDM column-supported embankment over soft soil. The developed solution was applied to a case history of SDM column-supported embankment, and a good agreement was found between the predictions and the field measurements.     

海上风机吸力式桶形基础承载特性研究综述

风机基础作为海上风机整体结构的重要组成部分,承受着上部风机所受到的风浪流荷载,并且对风机的安全性及可靠性至关重要。吸力式桶形基础由于其安装简单和可重复利用等优点,在海洋平台基础中得到了广泛应用,并逐步应用于海上风机基础中。但由于海上风机与海洋平台在海洋环境中的荷载工况有一定的差别,仍需要通过对其承载特性研究现状进行全面认识,以实现吸力式桶形基础在海上风机基础中的可靠应用。文中通过总结和评价现有研究对桶形基础在不同土体条件以及荷载条件下进行试验及数值模拟分析得到的研究结果,综述了静荷载和循环荷载作用下砂土和黏土中的吸力式桶形基础的承载特性研究现状,以及海上风机吸力式桶形基础的相关研究。文章展望了目前应用于海上风机基础的桶形基础仍缺乏的研究,为海上风机吸力式桶形基础的可靠应用及后续研究提供重要参考。     

边带分离型超导SIS接收机本振耦合噪声研究

超导SIS (Superconductor-Insulator-Superconductor)接收机因极低的接收机噪声温度成为毫米波和亚毫米波段射电天文观测的首选.本振系统耦合噪声也是接收机噪声的一部分,在多年的天文观测中,发现本振耦合噪声无法完全忽略,对天文观测的灵敏度有一定影响.采用两个不同种类的信号发生器作为本振系统初级信号源,测试了超导SIS接收机的噪声温度,发现信号发生器输出的基底噪声能够耦合到接收机内部,从而增加接收机噪声强度.分析研究了本振系统热噪声和信号发生器基底噪声对接收机噪声的影响.通过在信号发生器输入端加入窄带滤波器滤除其基底噪声,消除了信号发生器基底噪声引入的接收机噪声,降低了接收机的整体噪声,提高了望远镜的灵敏度.     

Efficient estimation of flood forecast prediction intervals via single‐ and multi‐objective versions of the LUBE method

Prediction intervals (PIs) are commonly used to quantify the accuracy and precision of a forecast. However, traditional ways to construct PIs typically require strong assumptions about data distribution and involve a large computational burden. Here, we improve upon the recent proposed Lower Upper Bound Estimation method and extend it to a multi‐objective framework. The proposed methods are demonstrated using a real‐world flood forecasting case study for the upper Yangtze River Watershed. Results indicate that the proposed methods are able to efficiently construct appropriate PIs, while outperforming other methods including the widely used Generalized Likelihood Uncertainty Estimation approach. Copyright © 2016 John Wiley & Sons, Ltd.