Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

Boussinesq相位解析的海岸水动力学数学模型研究进展

由于在平衡计算效率和精度上具有优势,Boussinesq相位解析数学模型研究不断取得突破,已成为波浪和水流精细化模拟的较优解析方式,为海岸工程、环境、地质等问题提供了实用和高效的研究手段。本文对已有Boussinesq类模型的研究进行了评述,深入探讨其重要发展、实际应用和理论瓶颈,从高阶非静压修正、GPU准三维高性能算法编译、波浪破碎和泥沙运移沉积等4个方面提出未来可能的科学突破方向。     

Evolution Characteristics of Government-Industry-University-Research Cooperative Innovation Network for China’s Agriculture and Influencing Factors: Illustrated According to Agricultural Patent Case

Under the special background of China, the cooperative innovation between different government-industry-university-research institutes plays an increasingly important role in the agricultural field. However, the existing literature has paid little attention to it. Considering the cooperation patents, published in the agriculture field stemming from the Full-text Database of China Patents as the study object, the spatial and institutional attribute of the authors as the data source, and by combining the social network and spatial econometrics analysis, this paper analyzes the structure evolution characteristics of cooperative innovation networks of agricultural government-industry-university-research institute in the city level of China in 1985–2014, based on the triple helix theory, with the influence factors discussed. This shows that, 1) since 1985, China's agricultural innovation level has been substantially increased, but the development degree of the cooperative innovation network is low, and the patent cooperation mainly relies on authors in the same unit; 2) enterprises play a leading role in the agricultural cooperative innovation. The effect of the government and hybrid organizations driven by the government is not obvious; 3) the cooperative innovation in the province and city dominates, and a multi-pole pattern has been formed. The cooperative innovation network structure evolves from a single helix empty core and double helix multi core to a double helix hierarchical network; 4) the city's science, education funding and personnel investment are key factors determining the agricultural cooperative innovation, while the agricultural development of the city presents slight negative impacts on it. The spatial mismatch of supply and demand is present in the technical cooperative innovation of China's agriculture. Therefore, the science enhancement and education investment to big agricultural provinces should be promptly implemented.     

Hydrological Processes in the Huaihe River Basin,China: Seasonal Variations,Causes and Implications

Understanding streamflow changes in terms of trends and periodicities and relevant causes is the first step into scientific management of water resources in a changing environment. In this study, monthly streamflow variations were analyzed using Modified Mann-Kendall(MM-K) trend test and Continuous Wavelet Transform(CWT) methods at 9 hydrological stations in the Huaihe River Basin. It was found that: 1) streamflow mainly occurs during May to September, accounting for 70.4% of the annual total streamflowamount with Cv values between 0.16–0.85 and extremum ratio values between 1.70–23.90; 2) decreased streamflow can be observed in the Huaihe River Basin and significant decreased streamflow can be detected during April and May, which should be the results of precipitation change and increased irrigation demand; 3) significant periods of 2–4 yr were detected during the 1960 s, the 1980 s and the 2000 s. Different periods were found at stations concentrated within certain regions implying periods of streamflow were caused by different influencing factors for specific regions; 4) Pacific Decadal Oscillation(PDO) has the most significant impacts on monthly streamflow mainly during June. Besides, Southern Oscillation Index(SOI), North Atlantic Oscillation(NAO) and the Ni?o3.4 Sea Surface Temperature(Ni?o3.4) have impacts on monthly streamflow with three months lags, and was less significant in time lag of six months. Identification of critical climatic factors having impacts on streamflow changes can help to predict monthly streamflow changes using climatic factors as explanatory variables. These findings were well corroborated by results concerning impacts of El Nino-Southern Oscillation(ENSO) regimes on precipitation events across the Huaihe River Basin. The results of this study can provide theoretical background for basin-scale management of water resources and agricultural irrigation.     

ZnO压敏陶瓷冲击老化的电子陷阱过程研究

使用8/20 μs脉冲电流发生器对普通商用ZnO陶瓷压敏电阻片进行了最多5000次的冲击试验.测量了冲击前后试样的电气性能和介电特性,分析了冲击后小电流区的U-I特性和损耗角正切值tanδ随脉冲大电流的不断作用而发生的变化.实验发现压敏电压U1mA随冲击次数的增加经历增大—稳定—减小三个过程.认为正反偏Schottky势垒的中性费米能级的变化是影响样品小电流区的最根本原因.本文提出用试样的非线性系数α作为老化特征参数比传统的U     

基于闪锌矿晶体中受激电磁耦子散射产生可调谐太赫兹波的理论研究

基于受激电磁耦子散射原理,采用已报道的利用非线性光学参量振荡方法产生可调谐太赫兹波的实验条件作为理论分析的实验模型,以GaAs,GaP, InP,ZnTe晶体为代表,计算分析了在闪锌矿晶体中参量振荡产生太赫兹波的吸收、增益特性,对输出THz波的调谐特性给出了详尽分析.分析太赫兹波高效耦合输出的腔型结构,并与掺氧化镁铌酸锂晶体组成的太赫兹波参量振荡器做对比.     

非均一相互作用能对超薄膜生长影响的Monte Carlo模拟研究

利用Monte Carlo (MC)模拟技术研究了非均一的吸附原子与基底相互作用能在一定的生长条件下对超薄膜生长过程的影响.非均一相互作用能是由基底表面原子在垂直和水平方向上实际位置与理想晶格原子位置的偏差所造成.本文用高斯分布来表示这种非均一相互作用能.模拟结果表明:非均一相互作用能对超薄膜的生长过程及薄膜的形貌有显著的影响.这种影响同时受到生长条件的限制,在中等温度时相互作用能的非均一性对岛的个数、平均大小的影响最显著;温度的增加在一定程度上可抵御相互作用能的非均一性对薄膜生长的影响.     

低扩散系数对Pd77 Cu6 Si17合金易非晶化的影响

采用激光熔凝技术,研究了Pd₇₇Cu₆Si₁₇合金快速凝固组织的演变规律.研究表明:随着生长速度的增大,Pd₇₇Cu₆Si₁₇合金晶体生长组织形貌发生了Pd₃Si枝晶+共晶-ξ枝晶+共晶-共晶团簇-规则共晶-非晶的转变;共晶失稳即非晶形成的临界生长速度为6 mm/s,最小层片间距为35 nm.通过与Al-25 wt%Sm,Al-32.7 w     

Compact and tunable mid-infrared source based on a 2 μm dual-wavelength KTiOPO4 intracavity optical parametric oscillator

Using a double resonant KTiOPO₄ (KTP) intracavity optical parametric oscillator operating at degenerated point of 2 μm, we demonstrate a unique mid-infrared source based on difference frequency generation in GaSe crystal. The output tuning range is 8.42-19.52 μm, and a peak power of 834 W for type-I phase matching scheme and 730 W for type-II phase matching scheme are achieved. Experimental results show that this oscillator is a good alternative to the generator of a compact and tabletop mid-infrared radiation with a widely tunable range.     

Improved understanding of petroleum migration history in the Hongche fault zone,northwestern Junggar Basin (northwest China): Constrained by vein-calcite fluid inclusions and trace elements

Calcite veins and cements occur widely in Carboniferous and Permian reservoirs of the Hongche fault zone, northwestern Junggar Basin in northwest China. The calcites were investigated by fluid inclusion and trace-element analyses, providing an improved understanding of the petroleum migration history. It is indicated that the Hongche fault behaved as a migration pathway before the Early Cretaceous, allowing two oil charges to migrate into the hanging-wall, fault-core and footwall reservoirs across the fault. Since the Late Cretaceous, the Hongche fault has been sealed. As a consequence, meteoric water flowed down only into the hanging-wall and fault-core reservoirs. The meteoric-water incursion is likely an important cause for degradation of reservoir oils. In contrast, the footwall reservoirs received gas charge (the third hydrocarbon event) following the Late Cretaceous. This helps explain the distribution of petroleum across the fault. This study provides an example of how a fault may evolve as pathway and seal over time, and how reservoir diagenetic minerals can provide clues to complex petroleum migration histories.