On the influence of magnetic fields on level populations

The influence of magnetic fields on the energy level populations of atoms is firstly studied by analysing the Stokes profiles of Fe  i 6302.5 forming in the solar magnetized atmosphere, with the aid of a departure factor defined to evaluate the deviation from the normal Boltzmann distribution without a magnetic field. This factor is directly related to the ratio of line-source function to the continuum one. The relationship between the departure and the magnetic field reveals an effect that the magnetic field induces an exponential increase in the level population of the lower level of Fe  i 6302.5 (Landé factor   g = 2.5  ) with the field strength. This indicates that the magnetic field can cause the redistribution of populations of those levels whose Landé factors are non-zero. Therefore, this effect should be included in the calculation of the statistical equilibrium. Secondly, an experiment utilizing the Hg5461 line in the laboratory on the Earth is carried out to reveal that the exponential relation is independent of variations in temperature, and the excitation is completely magneto-induced. Finally, the exponential relation is explained by taking account of the magnetic energy in the Boltzmann distribution.     

SOHM-4与MHM-2010氢原子频标的特点比较

基于对已投入国家授时中心守时运转的SOHM-4型与MHM-2010型氢原子频标的长期关注,对这两种氢原子频标的性能作了较详细的比较和分析。讨论了它们共同的优点、各自的特长和不足之处,还给出了稳定度的测试结果。     

利用降水平均递增率求山地最大降水高度

本文引入降水平均递增率的概念,改进了文献中的计算方法,可以一次求出山地降水量与海拔的经验关系式中全部参数的最佳值,其中包括山地最大降水高度。并用实例说明了本法的步骤及特点。     

Distinct climate change synchronous with Heinrich event one, recorded by stable oxygen and carbon isotopic compositions in stalagmites from China

Uranium-series dating of oxygen and carbon isotope records for stalagmite SJ3 collected in Songjia Cave, central China, shows significant variation in past climate and environment during the period 20-10 ka. Stalagmite SJ3 is located more than 1000 km inland of the coastal Hulu Cave in East China and more than 700 km north of the Dongge Cave in Southwest China and, despite minor differences, displays a clear first-order similarity with the Hulu and Dongge records. The coldest climatic phase since the Last Glacial Maximum, which is associated with the Heinrich Event 1 in the North Atlantic region, was clearly recorded in SJ3 between 17.6 and 14.5 ka, in good agreement in timing, duration and extent with the records from Hulu and Dongge caves and the Greenland ice core. The results indicate that there have been synchronous and significant climatic changes across monsoonal China and strong teleconnections between the North Atlantic and East Asia regions during the period 20-10 ka. This is much different from the Holocene Optimum which shows a time shift of more than several thousands years from southeast coastal to inland China. It is likely that temperature change at northern high latitudes during glacial periods exerts stronger influence on the Asian summer monsoon relative to insolation and appears to be capable of perturbing large-scale atmospheric/oceanic circulation patterns in the Northern Hemisphere and thus monsoonal rainfall and paleovegetation in East Asia. Climatic signals in the North Atlantic region propagate rapidly to East Asia during glacial periods by influencing the winter land-sea temperature contrast in the East Asian monsoon region.     

电感耦合等离子体质谱法同时测定地下水中硼溴碘

建立了电感耦合等离子体质谱法同时测定地下水中B、Br、I的方法。选定φ=2%(体积分数)的稀NH3.H2O介质消除碘的记忆效应。采用干扰较少的10B和79Br同位素。B、Br、I在0~10 000 ng/mL呈良好的线性关系。方法的检出限为10B 0.176 ng/mL,79Br 0.876ng/mL,127I 0.132 ng/mL;精密度(RSD,n=12)为10B 2.86%,79Br 3.36%,127I 2.69%;10B的阶梯加标回收率为94.6%~101.5%,79Br为98.3%~104.9%,127I为96.5%~102.0%。     

多接收器电感耦合等离子体质谱法测定镉标准溶液中镉的同位素组成

建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。     

内蒙古苏莫查干敖包特大型萤石矿床地质特征及成因

苏莫查干敖包矿床是迄今为正在全球范围内找到的最大规模单一萤石矿床.萤石矿体大多呈层状、似层状和透镜状沿下二叠统碳泥质板岩(夹灰岩透镜体)与流纹质火山岩接触带分布,并且与中生代花岗岩类侵入岩体具有密切的空间分布关系.流纹质火山岩和花岗岩的锆石SHRIMP U-Pb年龄值分别为(276±10)Ma和(138±4)Ma,它们分别是海西晚期和燕山中期酸性岩浆活动的产物.萤石矿体主要由4种类型矿石所构成,即石英-萤石型、石英-硫化物-萤石型、萤石-石英型和方解石-石英-萤石型.矿物组分有萤石、石英(蛋白石、玉髓)、方解石、绢云母和绿泥石,个别样品中有磁铁矿、黄铁矿、磁黄铁矿、黄铜矿、闪锌矿、毒砂和锡石.围岩蚀变自矿体中心向外分别为绢云母化、硅化、碳酸盐化和高岭石化.钕、锶和铅同位素分析结果表明,萤石矿床是多期次和多阶段岩浆热液活动的产物,成矿作用分别发生在海西晚期和燕山中期,并以后者为主.海西晚期富碱质酸性岩浆喷发活动为层纹状和条带状矿体以及矿源层的形成创造了有利条件.相比之下,燕山中期花岗质岩浆侵入活动不仅为细晶质、伟晶质和角砾状矿体的形成提供了物质、动力和热力来源,而且是成矿流体对流循环的"发动机".苏莫查干敖包矿床属于与花岗岩类深成侵入岩体有关的热液型萤石矿床,成岩(矿)物质来自壳、幔混合源,其中壳源组分占有绝对优势.     

内蒙古敖包吐萤石矿床的Sr、Nd、Pb同位素地球化学特征

敖包吐萤石矿床是内蒙古北部苏莫查干地区单一萤石矿集区中的一个代表性矿床,产于早二叠世大石寨组火山-沉积岩与早白垩世敖包吐花岗岩的接触带上。文章通过分析该矿床岩、矿石的微量元素和稀土元素,揭示出萤石的成矿作用可分为2个阶段,即交代作用和充填作用。交代作用过程中大石寨组的结晶灰岩可能为萤石的形成提供了部分Ca来源,萤石矿石的稀土元素配分模式与海水基本类似,具有Ce负异常;成矿作用后期主要表现为充填作用,形成颗粒粗大的萤石,表现为重稀土元素富集的特征,并随着萤石的沉淀析出,稀土元素总量逐渐下降,反映出成矿流体经历了较长期的演化过程。各地层单元、花岗岩体和萤石矿石的Sr、Nd、Pb同位素研究表明,萤石的放射性同位素组成具有壳、幔源混合的特点,成矿物质来源具有多源性。早白垩世敖包吐花岗岩可能是萤石中F的主要来源,而大石寨组的结晶灰岩则可能提供了Ca。另外,Pb、Nd同位素的极大不均一性,有可能是成矿流体在运移过程中对艾力格庙群放射性组分的选择性吸收的结果。萤石成矿作用与钾玄岩的时空关系暗示了萤石的成矿过程可能是中国东部岩石圈减薄和下地壳的置换地质事件的结果。在构造转型的过程中,燕山中期富碱的酸性花岗岩浆的活动分异出富含F的成矿流体,与幔源流体混合,沿区域重新活化的深大断裂和大石寨组的层间破碎带上升,交代其间的灰岩透镜体,从而形成敖包吐中型萤石矿床。     

塔里木盆地满加尔凹陷西缘奥陶系柯坪塔格组下段海相砂岩准层序成因与意义

通过精细岩芯描述、单井沉积微相分析与地震相、测井相综合研究,认为在塔里木盆地满加尔凹陷西缘奥陶系柯坪塔格组下段顶部含油气砂体中,发育3种类型的准层序：①粒级由底部粗—中下部细—上部粗的、反映整体向上变浅的海侵滞留沉积—海泛泥岩—滨岸沉积准层序,羊屋2井5460~5468 m含油气段位于该准层序内;②粒级向上变粗的滨外泥岩—临滨－前滨沉积,顶部受风暴影响的准层序,跃南2井6503~6512 m含油气段位于该准层序内;③粒级向上变细的潮下带—潮间带沉积的准层序,吉南1井5465~5486 m含油气段属于此准层序。发育于羊屋2井中的第一种准层序内含油气砂体在时间上属于较早的准层序3,发育于跃南2井、哈得13井中的第二种准层序与吉南1井中的第三种准层序内的含油气砂体属于稍晚的准层序4。早期沉积的、发育于羊屋2井顶部的第一种准层序是有利储层发育段,该井区以北靠近柯坪塔格组下段顶面尖灭线附近的准层序3时期沉积的临滨相储层是油气聚集成藏的有利部位。     

不整合运移通道类型及输导油气特征

在对不整合空间结构特征研究的基础上,提出了油气沿不整合运移的通道类型:宏观上,存在由不整合面之上底砾岩和不整合面之下半风化岩石两种高效运载层组合成的双运移通道型和单运移通道型两种通道类型;微观上,底砾岩连通孔隙、半风化岩石构造卸荷风化裂缝系统及溶蚀孔洞系统可作为油气运移的主要通道。通过对不整合面上、下岩石物性分析,认为半风化岩石“孔洞缝”系统较底砾岩连通孔隙有更高的输导油气的能力。研究结果表明,不同的运移通道类型具有不同的输导油气特征。在地史时期,构造裂缝系统和溶蚀孔洞系统一直是不整合输导油气的主要通道;对于软地层构成的不整合来说,开始应是卸荷、风化裂缝系统和底砾岩连通孔隙共同构成不整合输导油气的主要通道,当上覆沉积载荷达到一定程度后,主要是底砾岩连通孔隙起输导油气通道作用;对于脆硬地层构成的不整合来说,卸荷、风化裂缝系统和底砾岩连通孔隙一直是不整合输导油气的主要通道。