膜蒸馏处理糠醛废水的实验研究

采用中空纤维膜蒸馏技术研究了糠醛废水的膜蒸馏处理效果,考察了料液相的温度、醋酸浓度、流速、吸收液浓度等因素对处理效果的影响。结果表明：在温差为15℃、料液的浓度为0.306 mol/mL时,速度为8 mL/min;吸收液的质量浓度为25 g/L时,速度为3 mL/min。运行12 h后,料液的pH值由开始的1.9升高为5.1,醋酸的去除率为76.3％,糠醛的去除率为40.1％。此过程可降低料液中糠醛和醋酸的含量,减小了低分子量有机酸对微生物危害的影响,为后续生物处理奠定了基础。     

利用树轮密度重建新疆北部5-8月温度变化

利用新疆北部5个采样点的树轮密度年表主序列和新疆北部33个气象站观测气温平均值进行相关分析,结果显示其与新疆北部5-8月平均温度存在很强一致相关性,相关系数为0.667（p<0.001, n=49）。温度重建方程能够解释校准期（1960-2008年）内44.5%的温度变化方差。空间相关分析揭示该温度重建序列能够表征新疆北部过去353 a （1656-2008年）5-8月温度总体变化特征。重建序列揭示新疆北部5-8月平均温度大致经历了6个偏暖阶段,即1656-1664年、1667-1692年、1711-1734年、1804-1832年、1855-1956年、2000-2008年,中间为偏冷阶段,这些阶段中间多个小幅度变化。温度重建结果发现新疆北部温度变化与太阳活动、火山喷发有着紧密联系。温度重建序列与全球海温场的相关分析显示当西风带海区及热带大西洋地区的海温偏高时,研究区气温偏高。与海温、火山喷发和云量变化的相关分析都指示在西风环流的作用下,上述因子对于该地区温度变化有着重要影响。该温度重建序列在低频变化上与北半球气温具有显著正相关,说明中亚地区温度变化与北半球整体温度变化具有较好的一致性。     

吉林省辉南地区含金韧性剪切带的构造地质特征

吉林省辉南地区韧性剪切带岩石变形特征复杂多样。通过对剪切带内岩石的有限应变测量和变形环境的分析,认为本区韧性剪切带发育在地壳浅层次的低温低压环境,为逆冲推覆韧性变形,其变形变质作用相当于低绿片岩相,具有独特的构造组合和岩石变形特征,差异应力值为４５－５４ＭＰａ,剪切位移量约为１２．５ｋｍ,形成时间为中元古宙。     

H_2O_2增效TiO_2/凹凸棒石光催化体系降解亚甲基蓝

以钛酸四丁酯为前驱体,天然凹凸棒石为载体,采用溶胶凝胶法制备了TiO_2/凹凸棒石复合光催化剂,并用XRD、TEM对其进行表征.以亚甲基蓝染料为模拟污染物,采用300 W汞灯为紫外光源,以光催化实验来评价该催化剂的活性,并研究了H_2O_2的引入对光催化活性的影响.实验结果表明,H_2O_2能显著提高染料的脱色效率:亚甲基蓝的初始浓度为50 mg/L,催化体系为2 mmol/L H_2O_2+0.5 g/L TiO_2/凹凸棒石+UV(紫外线),光催化10 min后其脱色率为95%,相对于单独的0.5 g/L TiO_2/凹凸棒石+UV催化体系,其脱色率提高了约50%.全波段扫描显示,加入H_2O_2后,亚甲基蓝在290 nm对应的苯环吸收蜂急剧下降,665 nm对应的最大吸收峰则近乎消失,且没有新的吸收峰产生.     

盾构隧道施工地表变形分析与三维有限元模拟

随着地表建、构筑物密度与日俱增,在地铁建造过程中对地表环境的保护是一个越来越不容忽视的难题。盾构法隧道施工技术成功地应用于地铁施工之后,如何合理预测和控制盾构施工对地表变形的影响就成为了一个新课题。在查阅大量文献的基础上,总结前人的计算方法,利用有限元方法对某盾构隧道工程进行了三维的变形模拟分析,与实测的数据比较计算结果较为满意。     

原特提斯洋的俯冲、增生及闭合:阿尔金-祁连-柴北缘造山系早古生代增生/碰撞造山作用

分布在青藏高原北缘的阿尔金-祁连-柴北缘早古生代造山系被认为是原特提斯构造域最北部的构造拼合体。与其北侧具有长期增生历史的中亚造山系相比,特提斯造山拼合体被认为是各种来自冈瓦纳大陆北部大陆块体相互碰撞的产物。然而,与典型的阿尔卑斯和喜马拉雅碰撞造山带相比,阿尔金-祁连-柴北缘早古生代造山系包括有大量蛇绿岩、弧岩浆杂岩、俯冲-增生杂岩等,因此一些学者认为青藏高原北部的早古生代造山系为沿塔里木和华北克拉通边界向南逐渐增生的增生型造山带。但是,增生造山模式又很难解释南阿尔金-柴北缘地区普遍存在的与大陆俯冲有关的UHP变质岩、广泛分布的巴罗式变质作用和相关的岩浆作用,以及与碰撞造山有关的变形构造等。在本文中,通过对已有研究资料的综合总结,结合一些新的研究资料,我们提出在青藏高原东北缘的阿尔金-祁连-柴北缘造山系中,早古生代时期存在两种不同类型的造山作用,即增生和碰撞造山作用,其主要标志是北祁连-北阿尔金的HP/LT变质带、蛇绿混杂岩及与洋壳俯冲有关的构造岩浆作用,以及分布在柴北缘-南阿尔金与大陆俯冲和陆陆碰撞有关的UHP变质带、区域巴罗式变质作用、深熔作用、相关的岩浆活动及伸展垮塌作用等,并建立了一个反映原特提斯洋俯冲、增生、闭合及碰撞造山作用的构造模式。     

陕西小秦岭地区太华群的锆石U-Pb年龄和 Hf同位素组成

本文对陕西华山岩体南侧一个太华群黑云斜长片麻岩进行了地球化学、锆石U-Pb年龄和Hf同位素分析.地球化学分析显示其原岩为中酸性钙碱性花岗质岩石,稀土含量较低( ∑REE =83.13×10-6),但富集Pb和LILE元素(如Rb、Ba).锆石的176Hf/177Hf比值变化于0.281258～0.281404,具明显负的εHf(t)值(-6.86～- 11.23).锆石的Hf同位素模式年龄(2.96 ～3.24Ga)表明原岩是由中太古代地壳演化而来.对比显示小秦岭太华群黑云斜长片麻岩与鲁山地区的太华群具有相似的中太古代地壳源区,但它们的形成时代可能不同.锆石内部结构、Th/U比值以及定年结果显示小秦岭地区的太华群在～1.91Ga经历了一期重要的变质热事件,该事件与Columbia超大陆拼合时的全球性碰撞造山事件相关联.小秦岭太华群为华北克拉通块体南缘的地质单元,但各地区太华群在原岩组成、形成时代和变质时代上具有不同的特征,太华群应是一个杂岩体,至少可以解体为新太古代和古元古代两部分.     

青海共和县加当根斑岩铜矿床成矿流体特征及演化

加当根矿床是近几年新发现的研究程度较低的斑岩型铜矿床,文章对含矿斑岩、石英脉和绢英中的石英岩开展了详细的流体包裹体特征及氢、氧同位素组成研究.该矿床流体包裹体类型丰富,以大量发育含子晶多相包裹体为特征,子矿物种类多样,包括石盐、钾盐、石膏、黄铜矿、黄铁矿、赤铁矿等.石膏、赤铁矿的出现,暗示着岩浆结晶早期处于氧化环境.成矿流体由来自岩浆的高温、高盐度流体和以天水成因为主的中-高温、低盐度流体2个端员组分组成,高温、高盐度流体为主要载矿流体,形成温度＞ 440℃,w(NaCleq)为30％～82％,其是在浅成条件下于岩浆结晶的最后阶段从浅部岩浆中直接出溶形成的;中-高温、低盐度流体主要来源于天水或天水与晚期岩浆热液的混合,温度主要集中在220～360C,w(NaCleq)＜ 20％.石英流体包裹体氢、氧同位素研究表明流体混合在卸载成矿上的重要性,石英脉和绢英岩化阶段是含矿物质沉淀的主要阶段.脉石英的流体温度集中在280～440℃,绢英岩化蚀变石英中流体包裹体的均一温度介于240～340℃.     

Vertical structures of PM10 and PM 2.5 and their dynamical character in low atmosphere in Beijing urban areas

The vertical structures and their dynamical character of PM2.5 and PM10 over Beijing urban areas are revealed using the 1 min mean continuous mass concentration data of PM2.5 and PM10 at 8, 100, and 320 m heights of the meteorological observation tower of 325 m at Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP CAS tower hereafter) on 10―26 August, 2003, as well as the daily mean mass concentration data of PM2.5 and PM10 and the continuous data of CO and NO2 at 8, 100 (low layer), 200 (middle layer), and 320 m (high layer) heights, in combination with the same period meteorological field observation data of the meteorological tower. The vertical distributions of aerosols observed on IAP CAS tower in Beijing can be roughly divided into two patterns: gradually and rapidly decreasing patterns, I.e. The vertical distribution of aerosols in calm weather or on pollution day belongs to the gradually decreasing pattern, while one on clean day or weak cold air day belongs to the rapidly decreasing pattern. The vertical distributive characters of aerosols were closely related with the dynamical/thermal structure and turbulence character of the atmosphere boundary layer. On the clean day, the low layer PM2.5 and PM10 concentrations were close to those at 8 m height, while the concentrations rapidly decreased at the high layer, and their values were only one half of those at 8 m, especially, the concentration of PM2.5 dropped even more. On the clean day, there existed stronger turbulence below 150 m, aerosols were well mixed, but blocked by the more stronger inversion layer aloft, and meanwhile, at various heights, especially in the high layer, the horizontal wind speed was larger, resulting in the rapid decrease of aerosol concentration, I.e. Resulting in the obvious vertical difference of aerosol concentrations between the low and high layers. On the pollution day, the concentrations of PM2.5 and PM10 at the low, middle, and high layers dropped successively by, on average, about 10% for each layer in comparison with those at 8 m height. On pollution days, in company with the low wind speed, there existed two shallow inversion layers in the boundary layer, but aerosols might be, to some extent, mixed below the inversion layer, therefore, on the pollution day the concentrations of PM2.5 and PM10 dropped with height slowly; and the observational results also show that the concentrations at 320 m height were obviously high under SW and SE winds, but at other heights, the concentrations were not correlated with wind directions. The computational results of footprint analysis suggest that this was due to the fact that the 320 m height was impacted by the pollutants transfer of southerly flow from the southern peripheral heavier polluted areas, such as Baoding, and Shijiazhuang of Hebei Province, Tianjin, and Shandong Province, etc., while the low layer was only affected by Beijing's local pollution source. The computational results of power spectra and periods preliminarily reveal that under the condition of calm weather, the periods of PM10 concentration at various heights of the tower were on the order of minutes, while in cases of larger wind speed, the concentrations of PM2.5 and PM10 at 320 m height not only had the short periods of minute-order, but also the longer periods of hour order. Consistent with the conclusion previously drawn by Ding et al., that air pollutants at different heights and at different sites in Beijing had the character of "in-phase" variation, was also observed for the diurnal variation and mean diurnal variation of PM2.5 and PM10 at various heights of the tower in this experiment, again confirming the "in-phase" temporal/spatial distributive character of air pollutants in the urban canopy of Beijing. The gentle double-peak character of the mean diurnal variation of PM2.5 and PM10 was closely related with the evident/similar diurnal variation of turbulent momentum fluxes, sensible heat fluxes, and turbulent kinetic energy at various heights in the urban canopy. Besides, under the condition of calm weather, the concentration of PM2.5 and PM10 declined with height slowly, it was 90% of 8 m concentration at the low layer, a little lesser than 90% at the middle layer, and 80% at the high layer, respectively. Under the condition of weak cold air weather, the concentration remarkably dropped with height, it was 70% of 8 m concentration at the low layer, and 20%―30% at the middle and high layers, especially the concentration of PM2.5 was even lower.     

地震作用下含软弱夹层顺层岩质边坡表面放大效应研究

为了研究地震作用下含软弱夹层顺层岩质边坡表面的放大效应,借用FLAC3D软件,建立了含软弱夹层顺层岩质边坡动力分析数值模型;在合理考虑地震动输入、边界条件、网格划分与模型参数的基础上,分析了地震动峰值、频率、持时以及初动方向等因素影响下的边坡表面放大效应。研究结果表明：①地震动峰值、频率和初动方向对边坡表面放大效应的影响较显著,而地震动持时对边坡表面放大效应的影响微小;②随着地震动峰值的增加,放大效应由软弱夹层之上的坡面及坡顶面向坡肩点逐渐增大,坡肩点的放大效应最大;③当输入地震动频率小于边坡的自振频率时,边坡表面加速度放大倍数较小,且频率越小,放大倍数越小,当输入地震动频率大于边坡的自振频率时,边坡表面加速度放大倍数较大,且频率越大,放大倍数亦越大。