能量色散X射线荧光光谱法测定钼矿石中钼铅铁铜

建立了能量色散X射线荧光光谱法测定钼矿石中钼、铅、铁、铜的方法,讨论了粒度效应、矿物效应的影响因素,确定了采取粉末样品,用系列标准样品建立工作曲线,通过元素间相互校正消除基体效应,用内控标准样品考察了方法的精密度(RSD,n=11)为0.44%～15.4%。实际样品的测定结果和化学法相符,可满足日常分析工作需要。     

多接收器电感耦合等离子体质谱法测定镉标准溶液中镉的同位素组成

建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。     

西天山达巴特矿区火山岩的形成时代、构造背景及对斑岩型矿化的制约

本文通过对西天山地区比较典型的达巴特斑岩铜钼矿床矿区范围内出露的英安岩和花岗斑岩进行了系统的岩石地球化学分析,对流纹斑岩和花岗斑岩中的锆石进行了SHRIMPU—Pb定年研究,分别获得了315．9±5．9Ma和278．7±5．7Ma。岩石化学、微量以及稀土元素特征表明从英安岩到花岗斑岩,岩体具有明显的分异演化特征和很好的继承性。火山岩和次火山岩的精确定年为准确厘定火山岩形成的时限和地球动力学背景提供了依据。结合已有的Re-Os法获得的矿化年龄,表明晚石炭世末-早二叠世初（278．7±5．7Ma）,西天山地区进入板块碰撞-板内伸展阶段,由于深源岩浆侵位,在达巴特矿区形成了由花岗斑岩、流纹斑岩和流纹质角砾熔结凝灰岩组成的椭圆形火山机构,并导致相关矿床的形成。     

Zircon U–Pb and Hf isotopic study of gneissic rocks from the Chinese Altai: Progressive accretionary history in the early to middle Palaeozoic

Gneissic rocks in the Chinese Altai Mountains have been interpreted as either Paleozoic metasedimentary rocks or Precambrian basement. This study reports geochemical and geochronological data for banded paragneisses and associated gneissic granitoids collected along a NE–SW traverse in the northwestern Chinese Altai. Petrological and geochemical data suggest that the protoliths of the banded gneisses were possibly immature sediments with significant volcanic input and that the gneissic granitoids were derived from I-type granites formed in a subduction environment. Three types of morphological features can be recognized in zircons from the banded gneisses and are interpreted to correlate with different sources. Zircons from five samples of banded paragneiss cluster predominantly between 466 and 528 Ma, some give Neoproterozoic ages, and a few yield discordant Paleoproterozoic to Archean ages. Zircon Hf isotopic compositions indicate that both juvenile/mantle and crust materials were involved in the generation of the source rocks from which these zircons were derived. In contrast, zircons occur ubiquitously as elongated euhedral prismatic crystals in the four samples of the gneissic granitoids, and define single populations for each sample with mean ages between 380 and 453 Ma. The general absence of Precambrian inheritance and positive zircon ?Hf values for these granitoids suggest insignificant crustal contribution to the generation of the precursor magmas. Our data can be interpreted in terms of a progressive accretionary history in early to middle Palaeozoic times, and the Chinese Altai may possibly represent a magmatic arc built on a continental margin dominated by Neoproterozoic rocks.     

Evolution of subcontinental lithospheric mantle beneath eastern China: Re–Os isotopic evidence from mantle xenoliths in Paleozoic kimberlites and Mesozoic basalts

The ages of subcontinental lithospheric mantle beneath the North China and South China cratons are less well-constrained than the overlying crust. We report Re–Os isotope systematics of mantle xenoliths entrained in Paleozoic kimberlites and Mesozoic basalts from eastern China. Peridotite xenoliths from the Fuxian and Mengyin Paleozoic diamondiferous kimberlites in the North China Craton give Archean Re depletion ages of 2.6–3.2 Ga and melt depletion ages of 2.9–3.4 Ga. No obvious differences in Re and Os abundances, Os isotopic ratios and model ages are observed between spinel-facies and garnet-facies peridotites from both kimberlite localities. The Re–Os isotopic data, together with the PGE concentrations, demonstrate that beneath the Archean continental crust of the eastern North China Craton, Archean lithospheric mantle of spinel- to diamond-facies existed without apparent compositional stratification during the Paleozoic. The Mesozoic and Cenozoic basalt-borne peridotite and pyroxenite xenoliths, on the other hand, show geochemical features indicating metasomatic enrichment, along with a large range of the Re–Os isotopic model ages from Proterozoic to Phanerozoic. These features indicate that lithospheric transformation or refertilization through melt-peridotite interaction could be the primary mechanism for compositional changes during the Phanerozoic, rather than delamination or thermal-mechanical erosion, despite the potential of these latter processes to play an important role for the loss of garnet-facies mantle. A fresh garnet lherzolite xenolith from the Yangtze Block has a Re depletion age of ∼1.04 Ga, much younger than overlying Archean crustal rocks but the same Re depletion ages as spinel lherzolite xenoliths from adjacent Mesozoic basalts, indicating Neoproterozoic resetting of the Re–Os system in the South China Craton.     

塔里木西部地区古生代断裂活动的方式和机制

基于系统的地震剖面解释及其与塔中地区的对比,本文探讨了塔里木西部地区古生代断裂活动的方式和机制。玛东断裂带是一条宽阔的北东向盖层滑脱型褶皱冲断带,前展式向东南扩展,冲断作用发生在奥陶纪末。巴东断裂(吐土休克Ⅱ号断裂)为北西向基底卷入型冲断带,奥陶纪末和中二叠世末发生冲断。巴西断裂和塔参2井南断裂是海西期的正断层。塔里木古板块古生代的发育受邻侧的造山带演化制约,近东西向和北东向断裂奥陶纪末的冲断是继承基底构造发育的。塔中地区的近北西向断裂是晚寒武世的新生断裂,加里东运动可分为两幕:奥陶纪末的冲断(艾比湖运动)和晚志留-中泥盆世的冲断-走滑,后者向西明显减弱。塔里木西部的部分北西向断裂(如康西断裂)可归入塔中北西向断裂系。北东向的玛东断裂带是其西的向北(东)冲断的吐木休克断裂带与其东的向南偏东冲断的塔中8-1井——塔中5井断裂带之间的调节断层。     

藏南地区中生代硅质岩的地球化学特征及其成因意义

藏南地区中生代硅质岩包括蛇绿岩套硅质岩(与蛇绿岩共生)和非蛇绿岩套硅质岩两大类.本文重点分析日喀则地区彭错林、夏鲁以及泽当地区的罗布莎、江孜盆地宗卓组及四个剖面的硅质岩.其中,彭错林、夏鲁和罗布莎硅质岩与蛇绿岩共生,江孜盆地宗卓组为非蛇绿岩套硅质岩.分析表明:(1)藏南地区硅质岩剖面地球化学特征鲜明,具有一致性和多样性特点;(2)与蛇绿岩共生的彭错林、夏鲁、罗布莎硅质岩普遍具有高Si、高Fe、低Al特征,大部分微量元素相对于克拉克值亏损,稀土元素总量低,经北美页岩标准化后,Ce异常明显或不明显,重稀土相对轻稀土富集.硅质泥岩的∑REE要明显高于硅质岩;(3)非蛇绿岩套宗卓组硅质岩SiO2含量稍低,Al2O3、TiO2则相反.V、Th、Hf、Ta等不相容元素上亏损程度较小,部分样品含量可接近克拉克值.稀土总量相对较高,页岩标准化配分模式上体现为弱Ce正异常,负Eu异常,轻重稀土分异不明显的平坦型曲线图;(4)地球化学特征指示了,藏南地区硅质岩多数具有明显的热水沉积成因属性,同时有正常陆源组分的加入.其中,夏鲁硅质岩的热水沉积地球化学特征较为典型,而宗卓组硅质岩则表现出受陆源物质加入的影响显著的地球化学特点.     

北疆阿尔泰南缘泥盆系浅变质碎屑沉积岩地球化学特征及其形成环境

对于北疆阿尔泰地区泥盆纪所处的大地构造环境,目前仍旧存在不同观点。前人基于阿尔泰南缘泥盆纪火山岩地球化学研究,分别提出了活动大陆边缘和被动大陆边缘裂谷等不同构造观点。阿尔泰造山带南缘的泥盆纪浅变质碎屑沉积岩地球化学研究表明,该套浅变质碎屑沉积岩原岩主要为泥质或砂质沉积岩。尽管不同岩性样品主量元素含量不同,但其化学蚀变指数(CIA)小于75,成分变异指数(ICV)接近或小于1.0,斜长石蚀变指数(PIA)平均70,说明其源区物质比较新鲜,成熟度相对较低,化学风化作用较弱。同样,不同岩性样品微量元素含量差别较大,但表生过程中不活泼的微量元素比值却比较一致,轻稀土(LREE)中度富集(La_N/Yb_N=2.88～9.90),重稀土(HREE)比较平坦,并伴有明显的Eu负异常(Eu/Eu~*= 0.45～0.89)。绝大多数样品具有高的La/Sc(1～3)、La/Y(0.5～1)和Ti/Zr(10～35),以及较低的Sc/Cr(0.1～0.3)比值,类似于大陆岛弧相关环境碎屑沉积物。在La-Th-Sc和Th-Sc-Zr/10构造环境判别图解中,除一千枚岩样品外,其他所有样品均落入大陆岛弧区。以上地球化学特征明显不同于大洋岛弧和被动陆缘沉积物,说明该套浅变质碎屑沉积岩可能沉积于活动大陆边缘的大陆岛弧相关环境,为认识阿尔泰造山带泥盆纪岛弧增生构造演化过程提供了一个重要证据。     

黑龙江省金厂金矿床J0矿体流体地球化学研究

黑龙江省东宁县金厂金矿床是最新发现的特大型金矿床,目前探获黄金资源量86吨,它位于中亚造山带东端的吉黑成矿带,是与中生代中酸性岩浆活动有关的复杂成矿系统,矿化类型可能包括了斑岩型、爆破角砾岩型、浅成低温热液型.研究表明,高丽沟J0号矿体为爆破角砾岩型,热液成矿过程经历了早、中、晚3个阶段,分别形成以石英-黄铁矿、多金属硫化物-石英和碳酸盐为代表的矿物组合,中阶段矿物含自然金最多,次为早阶段矿物.初始成矿流体系统为高温、高盐度、高氧逸度、富CO2的岩浆热液;经减压沸腾,CO2等挥发分大量逸出,流体温度、盐度和氧逸度下降,导致大量金属硫化物及自然金快速沉淀;大气降水混入导致晚阶段流体低温、低盐度、贫CO2,对成矿贡献甚微.总体而言,成矿流体盐度高(11.70%～37.81%NaCl.eq),成矿作用发生在中-高温(238.3～425.7℃)的浅成环境(深633m～2736m).岩浆-流体成矿系统富CO2应发育于大陆碰撞造山带的伸展构造背景,而非大洋板块俯冲诱发的岩浆弧背景.