The luminescence decay-time of Mn2+ activated calcite

Luminescence decay time data are presented for 17 samples of synthetic calcite and a natural calcite between room temperature and approximately 15 K. The majority of the samples have Mn concentration in the range 0.0001–0.01 atoms per formula unit (apfu). Their spectra are consistent with a single exponential decay. It was necessary to use a “stretched” exponential to obtain adequate fits to the spectra of two samples having Mn concentrations of 0.036 and 0.091 apfu. The decay time at room temperature ranges from approximately 40–57 ms. At low temperature the corresponding range is 51–120 ms, indicating that thermal quenching of the decay time takes place. The decay time is dependent on the concentration of Mn, reaching a maximum (at both room- and low-temperature) in the range 0.001–0.003 apfu. The composition dependence is greater at low temperature. The results are discussed in terms of the Mott-Seitz and multiphonon mechanisms of thermal quenching. It is concluded that the latter provides a better fit to the data and is more consistent with models of the luminescence process in calcite:Mn.     

Small-scale, nature-based tourism as a pro-poor development intervention: Two examples in Kwazulu-Natal, South Africa

Tourism is widely acknowledged as a key economic sector that has the potential to contribute to national and local development and, more specifically, serve as a mechanism to promote poverty alleviation and pro-poor development within a particular locality. In countries of the global South, nature-based tourism initiatives can make a meaningful impact on the livelihoods of the poor, in particular the subsistence based rural poor. Taking two examples in KwaZulu-Natal Province, South Africa, where small-scale tourism initiatives were developed recently in response to existing natural attractions in the context of coping with local economic crises, this paper broadly assesses the modest benefits to date, as well as drawbacks, in improving conditions of life.     

Crystallization of calc-alkaline andesite under controlled high-pressure hydrous conditions

A series of experimental runs has been conducted on a glass prepared from a natural island are calc-alkaline andesite from Fiji. The crystallization sequence was determined for the pressure interval 9–36 kb under anhydrous conditions and with 2, 5, and 10% by weight of water carefully added. Addition of water markedly lowers the liquidus, depresses the appearance of quartz and plagioclase in the crystallization sequence, and greatly enlarges the field of garnet-clinopyroxene crystallization above 25 kb. Amphibole crystallizes in hydrous runs up to 25 kb. Electron microprobe analyses of critical phases allows calculation of controls on crystal fractionation trends. For hydrous conditions at 5–15 kb amphibole-clinopyroxene dominate fractionation and a moderate decrease in Mg/Fe and a slight increase in K/Na occurs. At 15–25 kb garnet also affects the fractionation and a moderate decrease in Mg/Fe and an increase in K/Na results. Above 25 kb garnet-clinopyroxene control the fractionation and there is a slight decrease in Mg/Fe but a significant increase in K/Na and a pronounced silica enrichment. In terms of major element chemistry, the derivation of the Fijian dacites in the second period of eruption may be satisfactorily explained by the fractionation of hydrous andesite at pressures >25 kb. Alternatively the dacites may result from lower degrees of melting of the down-going hydrous lithosphere. Similarly other members of this eruptive period may be derived according to a model of eclogite-controlled fractional melting or crystallization. Models involving amphibole fractionation at lower pressures are less satisfactory for explaining compositions in the Fijian second period of eruption, but in other environments models including amphibole-controlled fractionation may form part of a continuum of melting processes in subduction zones.     

Herschel SPIRE fourier transform spectrometer: calibration of its bright-source mode

The Fourier Transform Spectrometer (FTS) of the Spectral and Photometric Imaging REceiver (SPIRE) on board the ESA Herschel Space Observatory has two detector setting modes: (a) a nominal mode, which is optimized for observing moderately bright to faint astronomical targets, and (b) a bright-source mode recommended for sources significantly brighter than 500 Jy, within the SPIRE FTS bandwidth of 446.7–1544 GHz (or 194–671 microns in wavelength), which employs a reduced detector responsivity and out-of-phase analog signal amplifier/demodulator. We address in detail the calibration issues unique to the bright-source mode, describe the integration of the bright-mode data processing into the existing pipeline for the nominal mode, and show that the flux calibration accuracy of the bright-source mode is generally within 2 % of that of the nominal mode, and that the bright-source mode is 3 to 4 times less sensitive than the nominal mode.     

Herschel SPIRE FTS spectral mapping calibration

The Herschel SPIRE Fourier transform spectrometer (FTS) performs spectral imaging in the 447–1546 GHz band. It can observe in three spatial sampling modes: sparse mode, with a single pointing on sky, or intermediate or full modes with 1 and 1/2 beam spacing, respectively. In this paper, we investigate the uncertainty and repeatability for fully sampled FTS mapping observations. The repeatability is characterised using nine observations of the Orion Bar. Metrics are derived based on the ratio of the measured intensity in each observation compared to that in the combined spectral cube from all observations. The mean relative deviation is determined to be within 2 %, and the pixel-by-pixel scatter is ～ 7 %. The scatter increases towards the edges of the maps. The uncertainty in the frequency scale is also studied, and the spread in the line centre velocity across the maps is found to be ～ 15 km s ^{? 1}. Other causes of uncertainty are also discussed including the effect of pointing and the additive uncertainty in the continuum.     

Seasonal variability of rainfall extremes

Monthly rainfall extremes have been analyzed for three stations in Southern Ontario. The double exponential probability distribution was fitted to the extreme values for each month considered, each duration selected, and sets of annual extremes. A station‐year approach yielded monthly and annual extreme value distributions for the lumped region of Southern Ontario. The analysis has revealed a pronounced seasonal pattern in the rainfall extremes – the amount of rain expected with a selected probability of occurrence during the summer being considerably greater than the rainfall that might be expected to be exceeded at the same probability level during the spring or fall. The extent of the seasonal variability was found also to vary with duration. The implications of the variability are seen to be significant for the estimation of the magnitude and frequency of floods.     

Galaxies in clusters: the observational characteristics of bow shocks, wakes and tails

The dynamical signatures of the interaction between galaxies in clusters and the intracluster medium (ICM) can potentially yield significant information about the structure and dynamical history of clusters. To develop our understanding of this phenomenon we present results from numerical modelling of the galaxy–ICM interaction, as the galaxy moves through the cluster. The simulations have been performed for a broad range of ICM temperatures ( kT _cl=1, 4 and 8 keV), representative of poor clusters or groups through to rich clusters.
There are several dynamical features that can be identified in these simulations. For supersonic galaxy motion, a leading bow shock is present, and also a weak gravitationally focused wake or tail behind the galaxy (analogous to Bondi–Hoyle accretion). For galaxies with higher mass replenishment rates and a denser interstellar medium (ISM), the dominant feature is a dense ram-pressure stripped tail. In line with other simulations, we find that the ICM/galaxy–ISM interaction can result in complex time-dependent dynamics, with ram-pressure stripping occurring in an episodic manner.
In order to facilitate this comparison between the observational consequences of dynamical studies and X-ray observations we have calculated synthetic X-ray flux and hardness maps from these simulations. These calculations predict that the ram-pressure stripped tail will usually be the most visible feature, though in nearby galaxies the bow shock preceding the galaxy should also be apparent in deeper X-ray observations. We briefly discuss these results and compare them with X-ray observations of galaxies where there is evidence of such interactions.     

Optical depth,size distribution and flux of dust from Owens Lake,California

A joint United States/Russian/French collaborative experiment was undertaken in March 1993 and March 1996. Projects LODE I and II (Lake Owens Dust Experiments) took place on the anthropogenically desertified playa (dry lakebed) and surrounding regions of Owens Lake, in east-central California. One of the five parts of Project LODE was to determine relationships between optical depth and flux of dust emitted from the dry lake. Project LODE II included subsequent dust plume measurements and size distributions obtained through April 1996, to further refine the flux measurements for distinct mineral aerosol source regions at Owens Lake. Size distributions of dust aerosol were determined and aerosol optical depths were calculated from sunphotometer solar extinction measurements taken downwind in plumes coming from the emissive areas of Owens Lake. This source was visually observed for 10 measured dust storms. The plume mass was calculated to be 1·5 × 10⁹ g using ground-based measurements and ≥1·6 × 10⁹ g from satellite data. Project LODE II results were found to be consistent with LODE I results for the south end of the playa, but flux values were found to be reduced for the northeastern portion of the playa by comparison. Vertical flux values estimated by sunphotometry were found to be consistent with values estimated via a micrometeorological method. Copyright © 1999 John Wiley & Sons, Ltd.     

Wall building stiffness and strength effect on content sliding in Wellington seismic conditions

A numerical study of unobstructed content sliding within several low‐to‐midrise reinforced concrete cantilever wall buildings designed to Wellington conditions in New Zealand is performed to validate the belief that increasing a building's strength and/or stiffness would result in more severe sliding response. It was shown that contents within stronger buildings experienced larger sliding response. If the building was designed to be strong, the sliding response of contents with a friction coefficient of 0.1 was smaller in stiffer buildings compared with those in flexible buildings. However, the trends start reversing with an increase in friction coefficient or a decrease in building strength. Overall, content sliding is not necessarily more severe in stiffer buildings, and in many cases, the opposite is true. This study's findings were compared against an existing parametric equation for estimating the maximum sliding displacement. This equation, which was originally derived for contents located within elastic frame buildings, was found to be more efficient than considering total floor accelerations alone but was underconservative by a mean of 17% for yielding multistorey buildings. A design procedure considering content sliding using the parametric equation and an example are provided. Copyright © 2016 John Wiley & Sons, Ltd.     

A modified morphodynamic model for investigating the response of rivers to short-term climate change

Near-future climate change will affect the discharge and base level of rivers and thus cause channel changes. The nature and pace of such changes can be simulated using morphodynamic models. As part of an investigation of how the changing hydrology of the St-Lawrence River, Quebec, Canada, will affect its tributaries we have made additions and modifications to a one-dimensional morphodynamic model developed for gravel-bed rivers (SEDROUT). The changes allow simulation of sand-bed rivers, variable discharge, downstream water level fluctuations, and flow and sediment routing in channels with islands. A revised formulation for calculating the grain size distributions of the surface and subsurface material is presented to allow for alternating sedimentation and erosion. We test the enhanced model using small-scale simulations and present-day conditions in four tributaries of the St-Lawrence River. The model is calibrated and validated for the tributaries and the capability to simulate river morphology over a 100-year period is tested. Good validation agreement on water level, cross-sectional mean velocity, and sediment transport rate is obtained for the four tributaries of the St-Lawrence River. With these modifications, modelling a very wide range of river morphodynamic problems is now possible.