Secondary metabolites of a deep sea derived fungus Aspergillus versicolor CXCTD-06-6a and their bioactivity

In order to obtain novel secondary metabolites, a deep sea inhabiting fungus Aspergillus versicolor CXCTD-06-6a was investigated. One new diketopiperazine brevianamide W(1a), as well as five known diketopiperazine alkaloids, diketopiperazine V(1b), brevianamide Q(2), brevianamide R(3), brevianamide K(4), and brevianamide E(5), were isolated from the Et OAc extract of the fermentation broth. Their structures were elucidated by spectroscopy techniques(NMR, MS). The six compounds exhibited moderate radical scavenging activity against DPPH with clearance ratio of 55.0%(1a and 1b), 53.7%(2), 46.2%(3), 61.4%(4) and 19.3%(5) at a concentration of 13.9 μmol L-1, respectively; while the positive control ascorbic acid showed a ratio of 70.3% at the concentration of 28.4 μmol L-1.     

Detrital Zircon U-Pb Geochronology of the Xilin Group:Constraints for the Early Paleozoic Tectonic Evolution of the Songliao Massif

The Xilin Group, composed of the Chenming, Laodaomiaogou, Qianshan and Wuxingzhen formations, is one of the Early Paleozoic terranes in the eastern Songliao Massif, mainly consisting of thick layers of fine clastic and carbonate rocks. This study presents LA-ICP-MS zircon U-Pb geochronological data for the Laodaomiaogou and Qianshan formations, further constraining their provenance and the Early Paleozoic tectonic evolution of the Songliao Massif on the eastern Central Asian Orogenic Belt. Most zircons from the Laodaomiaogou and Qianshan formations show magmatic oscillatory zoning and high Th/U ratios (0.26–2.41). Zircon U-Pb dating results indicate that the detrital zircons from the silty mudstone of the Laodaomiaogou Formation yield peak ages of 634 Ma, 775 Ma, 820 Ma, 880 Ma and 927 Ma, as well as multi-episodic Archean to Paleoproterozoic and Mesoproterozoic ages (1405–643 Ma), implying its deposition time is younger than ~634 Ma. Furthermore, the occurrence of Early Cambrian fossils indicates that the Laodaomiaogou Formation was deposited during the late stage of the Early Cambrian (~514 Ma). The zircons from the K-bentonite of the Qianshan Formation show four peak ages of 444 Ma, 471 Ma, 489 Ma and 518 Ma and the youngest age peak of 444 ± 4 Ma (n = 6) indicates that the Qianshan Formation was deposited during the Late Ordovician. In addition, the peak ages of the detrital zircons in the silty mudstone of the Qianshan Formation are 472 Ma and 498 Ma, as well as two other concordant points with 207Pb/206Pb apparent ages of 1824 Ma and 1985 Ma. The dating results in this study, together with published data, indicate the absence of Pan-African magmatic events in the Songliao Massif prior to the initial deposition of the Xilin Group, in contrast to those distributed widely in the Jiamusi Massif. Taken together, we conclude that the depositional provenance of the Laodaomiaogou and Qianshan formations was derived from the Songliao Massif. Furthermore, the characteristics of the detrital zircon age composition and rock associations indicate that the Laodaomiaogou Formation formed in a passive continental margin environment, in contrast to the Qianshan Formation, which formed in an active continental margin environment. The above results also imply that the Songliao and Jiamusi massifs might not have collided before the Late Ordovician.     

伪随机源时间域航空电磁响应系统辨识

在时间域航空电磁系统中,采用高频伪随机序列作为激励源是实现浅层高分辨地质探测的有效途径。为了提高大地脉冲响应的辨识精度,在基本相关辨识方法的基础上,本文提出了一种基于时间域循环相关计算的高精度辨识方法,通过消除旁瓣效应影响和在时间域下求解维纳-霍夫方程获取大地脉冲响应。数值模拟仿真结果表明,辨识大地响应相对误差均方根为2.2×10^-7,早期大地响应辨识误差小于10^-10。该高精度辨识方法具有较好的噪声压制能力,在观测时间较短时,单周期辨识提升的信噪比为8.7 dB,优于同等条件下线性叠加降噪方法提升的信噪比6.1 dB。     

东北地区中等地震前地磁空间相关性异常特征初步分析

应用黑龙江、吉林、内蒙古和辽宁等省的地磁总场强度F北京时21点绝对观测值,研究了其空间相关性在东北地区几次中等地震前的变化.结果显示,在这些地震前地磁总场F的空间相关性会出现下降变化,本文初步给出了判定异常的指标.     

黑龙江及周边地区中强地震前加卸载响应比特征分析

选取所研究区域地震能量的贝尼奥夫应变(相当于室内岩石实验中的声发射)作为响应,以黑龙江及其周边地区2005年以来14次ML 5.0以上地震作为震例,检验卸载响应比理论的预测效果,提取异常特征,初步总结该方法的时、空、强预测指标,发现具有一定的预报效能。     

新疆磁海铁矿床Fe-O-S同位素和元素地球化学示踪

新疆磁海铁矿位于北山构造-成矿带西端,以磁海矿段为主要组成部分,铁矿体主要为透镜状、似层状,围岩以辉绿岩为主,二者接触线截然且平直;另外一种矿体产在基性岩体与地层接触带的石榴子石透辉石矽卡岩岩体内,整个矽卡岩岩体即为铁矿体。通过野外矿床特征与矿相学研究,成矿过程可分为:(1)矿浆期,以磁铁矿+单斜辉石+普通角闪石的近同时产出为特征;(2)矽卡岩期,先期以石榴子石+透辉石+磁铁矿为特征,后期以透闪石/阳起石+石英+磁黄铁矿+黄铜矿+黄铁矿的组合为特征。通过对矿浆期及矽卡岩期典型矿物的地球化学及Fe、S、O同位素结果分析,认为矿浆期铁质具有幔源特征,矽卡岩期成矿流体对矿浆期具有继承性。通过与前人研究结果对比分析,认为磁海成矿可能形成于塔里木地区二叠纪地幔柱背景,含矿母岩浆可能为地幔柱的分支。     

新疆昭苏布合塔铜(金)矿化区花岗质岩石锆石U-Pb年龄、地球化学特征及其成因

布合塔铜（金）矿化区位于新疆昭苏境内,大地构造位于那拉提构造带北缘西段。矿化区主要被二长花岗岩及石英闪长岩呈岩株状侵入,在花岗岩体边缘及与围岩接触带内均有铜（金）矿化。研究区2种岩体的锆石 LA-ICP-MS U-Pb测年结果分别为（434.5±4.6）Ma（二长花岗岩）、（445.7±5.1）Ma（石英闪长岩）,为晚奥陶世—早志留世;元素地球化学测试结果显示,二者均属过铝质钾玄岩系列;二长花岗岩A/CNK值为1.35~1.42,石英闪长岩A/CNK值为1.47~1.71,具S型花岗岩特征;二者稀土元素特征较为相近,均显示轻稀土相对富集、具Eu负异常（δEu=0.67~0.80）,微量元素均显示富集Ba、Th、U,亏损Nb、Ta等;地球化学分析表明,岩浆源岩主要为变杂砂岩,以部分熔融作用为主。结合区域大地构造背景及相关研究,总体认为该矿化区花岗质岩浆是由中天山板块与伊犁板块碰撞闭合之后的中下地壳部分熔融而成。     

贵州卡林型金矿的发现及其意义

贵州是我国率先发现有工业价值微细浸染型金矿──卡林型金矿的省区。它的发现不仅彻底改变了贵州金资源贫乏的面貌，开创了黄金生产的新篇章，而且为全国金的找矿提供了宝贵的借鉴，具有重要的指导作用，促进了同类型金矿在有关省区的不断发现。本文就该类型金矿及其重要产区的发现予以查证记述的基础上，对其金矿发现的特点做了归纳，进而对发现的价值意义进行了概略论叙。     

东濮凹陷上古生界石千峰组致密砂岩储层特征

东濮凹陷上古生界石千峰组发育一套厚度较大且具有勘探潜力的河流-湖泊相致密砂岩。采用岩心观察、薄片鉴定、扫描电镜、阴极发光、X衍射全岩及黏土矿物分析等技术手段,对东濮凹陷上古生界石千峰组致密砂岩储层的岩石学特征、物性特征和成岩作用进行了分析。结果表明:储层岩石类型主要为岩屑长石砂岩和长石岩屑砂岩;孔隙度2%~10%,渗透率(0~1)10^-3m²,整体上表现出特低孔超低渗特点;成岩作用主要为压实、压溶、胶结、溶蚀和交代作用。样品古地温、镜质体反射率(R_o,%)和X衍射黏土矿物分析结果进一步证实研究区石千峰组砂岩储层属于中成岩阶段A期。