Energy sources for diagenesis: Evidence from the Black Sea

Complex investigations of recent and Drevnechernomorian (ancient Black Sea) sediments from the outer shelf, continental slope, and deep-water basin of the Russian Black Sea sector have been carried out using samples collected during cruise of the R/V Professor Shtokman organized by the Institute of Oceanology of the Russian Academy of Sciences (March 2009) and expedition of “YUZHMORGEO” (summer 2006). Rates of the main anaerobic processes during diagenesis (sulfate reduction, dark CO₂ fixation, methanogenesis, and methane oxidation) were studied for the first time in sediment cores of the studied area. Two peaks in the rate of microbial processes and two sources of these processes were identified: the upper peak near the water-sediment contact is related to the solar energy (OM substrate of the water column) and the lower peak at the base of the Drevnechernomorian sediments with high(>1000 μM) methane concentration related to the energy of anaerobic methane oxidation. The neogenic labile OM formed during this process is utilized by other groups of microorganisms. According to experimental data, the daily rate of anaerobic methane oxidation is many times higher than that of methanogenesis, which unambiguously indicates the migration nature of the main part of methane.     

Radium Isotopes and Nutrients in Razdolnaya River Estuary (Amur Bay,the Sea of Japan) in the Period of Summer Flood

Water Resources - The activity of dissolved radium isotopes 223Ra, 224Ra, 228Ra, the concentrations of nutrients: ammonium, nitrates, nitrites, phosphates, silicates, total nitrogen, and total...     

Rare-Earth Elements in the Atmospheric Precipitation of the City of Blagoveshchensk

The mineral composition, distribution and fractionation of rare-earth elements in dissolved and suspended forms (solid residue) of atmospheric precipitation were studied by analyzing the snow sampled over urbanized territory by the example of the city of Blagoveschensk. Electron-microscopic studies revealed the own minerals of rare-earth elements in dust aerosols. It is shown that the main sources of the atmospheric pollution by rare-earth elements were emissions of TPP (heat and power plants) and boiler houses. Contrasting geochemical anomalies of rare-earth elements were found in the snow cover of the city. The REE concentrations in the solid phase of snow are few orders of magnitude higher than those of the liquid phase. The snow solid phase provides insight into the REE behavior, because it directly reflects the impact of different anthropogenic sources. The characteristic feature of the REE distribution in the solid residue of snow is their LREE enrichment relative to MREE and HREE. The average HREE content is 10% of total REE. In the snow water–solid phase system, most samples show weak fractionation between LREE and HREE owing to the low total mineralization of the snow liquid phase and the small content of organic matter.     

Experimental Modeling of Platinum Biomineralization by Microscopic Fungi Isolated from a Lignite Deposit

Based on scanning electron microscopy, infrared spectroscopy, and X-ray photoelectron spectroscopy, it was shown that platinum sorption by the biomass of microscopic fungi occurs in several stages. Incipient interaction involves physical and chemical sorption and is followed by the reduction of adsorbed platinum ions to a zero-valence state at the expense of metabolic products of microorganisms and eventual aggregation of zero-valence particles to nanometer-sized forms. Model experiments revealed a high platinum sorption potential of the physiologically active biomass of microscopic fungi and their cell envelopes (chitin).     

Effect of the zonal E × B plasma drift on the electron number density in the low-latitude ionospheric F region at high solar activity near the December solstice

The variations in the electron number density of the ionospheric F2 layer maximum (NmF2) under the action of the zonal plasma drift in the geomagnetic west-geomagnetic east direction perpendicularly to the electric (E) and geomagnetic (B) fields during a geomagnetically quiet period on December 7, 1989, at high solar activity have been studied based on a three-dimensional nonstationary theoretical model of electron number densities and temperatures in the ionospheric F region. Calculated and measured NmF2 values for 12 low-latitude ionospheric sounding stations have been compared. When the zonal E × B plasma drift is ignored, the NmF2 values become smaller by up to a factor of 3 under nighttime conditions in the low-latitude ionosphere. The average effect of the zonal E × B plasma drift on NmF2 in the low-latitude ionosphere is larger during winter nights than under summer nighttime conditions.     

The Berelekh Mammoth “Graveyard”: New Chronological and Stratigraphical Data from the 2009 Field Season

To clarify unanswered questions of site formation, geology and the archaeology of the Berelekh geoarchaeological complex, a special survey was undertaken in 2009 of the area surrounding the site. Several geological units have been revealed. By establishing the spatial and temporal relationship of these deposits—as well as their age—we have reconstructed the formation history of the Berelekh bone bed. The mammoth bone deposit belongs to a paleochannel. Radiocarbon dating of mammoth remains at Berelekh demonstrates rapid accumulation during the Bølling warming. Human involvement in its formation is, at best, questionable, since there is no real overlap between the radiocarbon dates associated with past human activity, and those of the mammoth bone bed. This study confirms that humans used mammoth bone remains after the bone bed was deposited. Culturally, the Berelekh “site” does not have any relationship to the so‐called “Dyuktai culture.” Instead, the Berelekh archaeological finds (side notched stone pendants) show certain similarities to non‐microblade terminal Pleistocene assemblages found from Yenisei to Kamchatka. Additionally, the Berelekh complex presents a clear analogy with lithics found in Eastern Beringia. Teardrop‐shaped incomplete bifaces found in the assemblage are comparable to the Chindadn points of Alaska. The nature of this “Chindadn connection” is intriguing but it is the only visible cultural link between Western and Eastern Beringia.     

Major ion composition and carbonate equilibrium in the sediment pore water of the Razdol’naya River estuary of Amur Bay,the Sea of Japan

The complex study of the river water and pore solutions from the bottom sediments in the lower reaches of the Razdol’naya River was conducted in February 2010. The major ion composition of the waters indicates the submarine origin of the near-bottom and pore waters in the lower reaches of the Razdol’naya River in the winter. The river estuary extends upstream for more than 20 km. It was established that the studied sediments are reduced oozes containing pyrite, hydrotroilite, and iron monosulfide, which is direct evidence for sulfate-reduction in the sediments. The diagenesis of organic matter is the main reason for the considerable decrease in the amount of sulfates and the increase in the alkalinity of the sediment pore water. The sedimentary pore water sampled from the deep river pits is characterized by excess alkalinity that cannot be explained by sulfate-reduction and methane genesis. It was suggested that the chemical weathering of silicate minerals and the bacterial mineralization of salts of organic acids could result in the excess alkalinity of the sediment pore water.     

Biosorption of Chemical Elements from Multicomponent Solutions by Microfungal Biomass

Doklady Earth Sciences - Data on the species and strain specificity of micromycetes in the processes of toxic elements extraction from multicomponent solutions are obtained as results of modal...