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61.
Floating objects facilitate the dispersal of marine and terrestrial species but also represent a major environmental hazard in the case of anthropogenic plastic litter. They can be found throughout the world's oceans but information on their abundance and the spatio-temporal dynamics is scarce for many regions of the world. This information, however, is essential to evaluate the ecological role of floating objects. Herein, we report the results from a ship-based visual survey on the abundance and composition of flotsam in the German Bight (North Sea) during the years 2006 to 2008. The aim of this study was to identify potential sources of floating objects and to relate spatio-temporal density variations to environmental conditions. Three major flotsam categories were identified: buoyant seaweed (mainly fucoid brown algae), natural wood and anthropogenic debris. Densities of these floating objects in the German Bight were similar to those reported from other coastal regions of the world. Temporal variations in flotsam densities are probably the result of seasonal growth cycles of seaweeds and fluctuating river runoff (wood). Higher abundances were often found in areas where coastal fronts and eddies develop during calm weather conditions. Accordingly, flotsam densities were often higher in the inner German Bight than in areas farther offshore. Import of floating objects and retention times in the German Bight are influenced by wind force and direction. Our results indicate that a substantial amount of floating objects is of coastal origin or introduced into the German Bight from western source areas such as the British Channel. Rapid transport of floating objects through the German Bight is driven by strong westerly winds and likely facilitates dispersal of associated organisms and gene flow among distant populations.  相似文献   
62.
A least-squares inverse method is applied to the estimation of optimum kinetic parameters with statistical error bounds from concentration data obtained in isothermal hydrous pyrolysis experiments. The inverse method requires the specification of a data-parameter relationship (e.g., classical kinetic theory), the prior covariance matrices of data and parameter errors, as well as the prior central estimates of data and parameters. The reaction scheme considered is the common case of kerogen breakdown by Gaussian-weighted independent parallel first-order reactions and bitumen cracking by a single first-order reaction. The nonlinearity of the problem is reduced by a logarithmic transformation, which suggests a parameterization in terms of logarithmic concentrations, activation energies, and logarithmic Arrhenius factors. The linearized variance analysis is valid for the case studied, and the posterior covariance matrix reveals which parameters are constrained by the data. We find that the statistical errors in the average activation energy and the associated Arrhenius factor are strongly correlated. Hence, the parameters which determine the temperature dependence of the reaction rate have not been resolved independently. Furthermore, the kinetic results are very sensitive to the presence of a distribution of activation energies in kerogen breakdown. This distribution is not constrained by the data. As a consequence, neglecting the consideration of distributions of activation energies results in activation parameter values which are much too low. This is the major reason for the commonly encountered discrepancy between kinetic parameter values obtained from hydrous pyrolysis and micropyrolysis experiments, respectively.  相似文献   
63.
Zhang  Jiawen  Liesch  Tanja  Chen  Zhao  Goldscheider  Nico 《Hydrogeology Journal》2023,31(5):1197-1208

Karst areas contain valuable groundwater resources and high biodiversity, but are particularly vulnerable to climate change and human impacts. Land-use change is the cause and consequence of global environmental change. The releases of the Climate Change Initiative-Land Cover (CCI-LC) and World Karst Aquifer Map (WOKAM) datasets have made it possible to explore global land-use changes in karst areas. This paper firstly analyses the global karst land-use distribution in 2020, as well as the land-use transition characteristics between 1992 and 2020. Then, two indicators, proportion of land-use change and dominant type of land-use change, are proposed to identify the spatial characteristics of land-use change in global karst areas. Finally, three examples of land-use change in karst areas are analyzed in detail. Land-use types and proportions of the global karst areas from large to small are as follows: forest (31.78%), bare area (27.58%), cropland (19.02%), grassland (10.87%), shrubland (7.21%), wetland (1.67%), ice and snow (1.16%) and urban (0.71%). The total area of global karst land-use change is 1.30 million km2, about 4.85% of global karst surface. The land-use change trend of global karst is dominated by afforestation, supplemented by scattered urbanization and agricultural reclamation. The tropical climate has a higher intensity of land-use change. Regions of agricultural reclamation are highly consistent with the population density. These results reflect the impact of human activities and climate change on land-use changes in global karst areas, and serve as a basis for further research and planning of land resource management.

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64.
The analysis of the Th/U ratio in meteorites and the evolutionary ages of globular clusters favour values of the cosmic age of (19±5)×109 yr. This evidence together with a Hubble parameterH 0>70 km s–1 Mpc–1=(14×109 yr)–1 cannot be reconciled in a Friedmann model with =0. It requires a cosmological constant in the order of 10–56 cm–2, equivalent to a vacuum density v =10–29 g cm–3 The Friedmann-Lemaître models (>0) with a hot big-bang have been calculated. They are based on a present value of the baryonic matter density of 0=0.5×10–30 g cm–3 as derived from the primordial4He and2H abundances.For a Hubble parameter ofH 0=75 km s–1 Mpc–1, our analysis favours a set of models which can be represented by a model with Euclidean metric (density parameter 0=1.0, deceleration parameterq 0=–0.93, aget 0=19.7×109 yr) and by a closed model with perpetual expansion (0=1.072,q 0=–1.0, aget 0=21.4×109 yr). A present density parameter close to one can indeed be expected if the conjecture of an exponential inflation of the very early universe is correct.The possible behaviour of the vacuum density is demonstrated with the help of Streeruwitz' formula in the context of the closed model with an inflationary phase at very early times.  相似文献   
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In offshore waters of the German North Sea multiple stakeholder activity is increasing in both type and intensity. Newcomers such as wind farms make for additional claims and exclude, due to current legal constraints, other sectors, such as traditional fisheries. In this context, integrating marine aquaculture with designated wind farm areas might provide chances to combine two industries in the frame of a multiple-use concept. This paper takes up concerns and possible management framework requirements as expressed through interviews with the wind farm industry and the mussel harvesting sector when inquiring about such a multiple-use setting. The article closes with a discussion on two co-management strategies that might be appropriate for governing potential interacting wind farm–mariculture activities.  相似文献   
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Various land–atmosphere coupling mechanisms exist that may lead to large-scale impacts on climate and hydrology. Some of them are still less understood and not adequately represented in state-of-the-art climate modelling. But, as the current generation of climate models enables consideration and implementation of important coupling processes, the present study provides perspectives for the modelling of relevant climate–hydrology interactions. On a more short-term perspective, these comprise anthropogenic land use and especially irrigation, which has been shown that it may even affect remote regions. On a long-term perspective, the coupling of hydrology to carbon cycle and vegetation becomes important, specifically the dynamics of permafrost and wetlands. Here, we present a review of current knowledge combined with some exemplary studies from a large-scale point of view. Therefore, we focus on climate–hydrology interactions that are relevant on scales utilized in the current or forthcoming global and regional climate modelling exercises.  相似文献   
70.
Extensive published data sets and some new data on the clay mineral composition of surface sediments in the Aegean Sea, northeastern Mediterranean Sea, have been compiled in order to map the distribution patterns of clay mineral assemblages and to decipher source areas and transport paths. We distinguished six provinces, a Northwest Aegean Province, a Marmara-Dardanelles Province, a West Turkey Province, a Southeast Aegean Province, a Kithira Province and a Central Aegean Province. The clay mineral assemblages in the coastal and shelf areas carry the signature of the riverine sediment discharge from southeast Europe and Turkey, respectively. The southern Aegean Sea is probably influenced by the River Nile discharge and transport of clay minerals by surface currents. The clay minerals in the central Aegean Sea form a mixed assemblage comprising components of the other assemblages. A dispersion and dilution of clay minerals by surface currents is obvious.  相似文献   
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