Inflations prior to Vulcanian eruptions and gas bursts detected by tilt observations at Semeru Volcano,Indonesia

We examine the basic characteristics of inflations at Semeru Volcano, Indonesia, to clarify the pressurization process prior to two different styles of explosive eruptions: Vulcanian eruptions and gas bursts. Analysis of data obtained from tilt meters installed close to the active crater allows clarification of the common features and the differences between the two styles of eruptions. To improve the signal-to-noise ratio and to determine the mean characteristics of the inflations, we stack tilt signals obtained from eruptions of different magnitudes and evaluate the maximum amplitude of the seismic signal associated with these eruptions. Vulcanian eruptions, which explosively release large amounts of ash, are preceded by accelerating inflation about 200–300 s before the eruption, which suggests volume expansion of the gas phase. In contrast, gas bursts, which rapidly effuse water steam accompanied by explosive sounds, follow non-accelerating changes of inflation starting 20 s before each emission. Tilt amplitudes increase with the magnitude of eruptions for both eruption styles. This suggests that the volume and/or pressure of magma or gas stored in the conduit before eruptions controls the magnitude of volcanic eruptions. These results further suggest that the magnitude of eruptions can be predicted from geodetic measurements of volcano inflation.     

A new evolutionary scenario of intermediate-mass star-formation revealed by multi-wavelength observations of OMC-2/3

We have performed millimeter- and submilli- meter-wave survey observations using the Nobeyama millimeter array (NMA) and the Atacama Submillimeter Telescope Experiment (ASTE) in one of the nearest intermediate-mass (IM) star-forming regions: Orion Molecular Cloud-2/3 (OMC-2/3). Using the high-resolution capabilities offered by the NMA (∼several arcsec), we observed dust continuum and H¹³CO⁺(1–0) emission in 12 pre- and proto-stellar candidates identified previously in single-dish millimeter observations. We unveiled the evolutionary changes with variations of the morphology and velocity structure of the dense envelopes traced by the H¹³CO⁺(1–0) emission. Furthermore, using the high-sensitivity capabilities offered by the ASTE, we searched for large-scale molecular outflows associated with these pre- and proto-stellar candidates observed with the NMA. As a result of the CO(3–2) observations, we detected six molecular outflows associated with the dense gas envelopes traced by H¹³CO⁺(1–0) and 3.3 mm continuum emission. The estimated CO outflow momentum increases with the evolutionary sequence from early to late type of the protostellar cores. We also found that the 24 μm flux increases as the dense gas evolutionary sequence. We propose that the enhancement of the 24 μm flux is caused by the growth of the cavity (i.e. the CO outflow destroys the envelope) as the evolutionary sequence. Our results show that the dissipation of the dense gas envelope plays an essential role in the evolution of the IM protostars. The extremely high-sensitivity and high-angular resolution offered by ALMA will reveal unprecedented details of the inner ∼50 AU of these protostars, which will provide us a break through in the classic scenario of IM star/disk formation.     

Scientific role of ACA for low-mass star-formation study

We discuss the scientific role of the Atacama Compact Array (ACA), the Japanese contribution to the ALMA project, for low-mass star-formation study. Our recent observations of several low-mass protostellar envelopes in the submillimeter CS (J=7–6) and HCN (J=4–3) lines with the SMA and ASTE have revealed that these submillimeter emissions are more extended than ∼2000 AU and show different velocity structures from those traced by millimeter lines. These results suggest the importance of taking short-spacing informations the ACA can offer. Our comprehensive imaging simulations of these protostellar envelopes, as well as prestellar cores and debris disks, unprecedentedly demonstrate the scientific importance of ACA.     

Geology,Alteration, and Mineralization of the Kay Tanda Epithermal Gold Deposit,Lobo, Batangas,Philippines

The Kay Tanda epithermal Au deposit in Lobo, Batangas is one of the Au deposits situated in the Batangas Mineral District in southern Luzon, Philippines. This study aims to document the geological, alteration, and mineralization characteristics and to determine the age of the mineralization, the mechanism of ore deposition, and the hydrothermal fluid characteristics of the Kay Tanda deposit. The geology of Kay Tanda consists of (i) the Talahib Volcanic Sequence, a Middle Miocene dacitic to andesitic volcaniclastic sequence that served as the host rock of the mineralization; (ii) the Balibago Diorite Complex, a cogenetic intrusive complex intruding the Talahib Volcanic Sequence; (iii) the Calatagan Formation, a Late Miocene to Early Pliocene volcanosedimentary formation unconformably overlying the Talahib Volcanic Sequence; (iv) the Dacite Porphyry Intrusives, which intruded the older lithological units; and (v) the Balibago Andesite, a Pliocene postmineralization volcaniclastic unit. K‐Ar dating on illite collected from the alteration haloes around quartz veins demonstrated that the age of mineralization is around 5.9 ± 0.2 to 5.5 ± 0.2 Ma (Late Miocene). Two main styles of mineralization are identified in Kay Tanda. The first style is an early‐stage extensive epithermal mineralization characterized by stratabound Au‐Ag‐bearing quartz stockworks hosted at the shallower levels of the Talahib Volcanic Sequence. The second style is a late‐stage base metal (Zn, Pb, and Cu) epithermal mineralization with local bonanza‐grade Au mineralization hosted in veins and hydrothermal breccias that are intersected at deeper levels of the Talahib Volcanic Sequence and at the shallower levels of the Balibago Intrusive Complex. Paragenetic studies on the mineralization in Kay Tanda defined six stages of mineralization; the first two belong to the first mineralization style, while the last four belong to the second mineralization style. Stage 1 is composed of quartz ± pyrophyllite ± dickite/kaolinite ± diaspore alteration, which is cut by quartz veins. Stage 2 is composed of Au‐Ag‐bearing quartz stockworks associated with pervasive illite ± quartz ± smectite ± kaolinite alteration. Stage 3 is composed of carbonate veins with minor base metal sulfides. Stage 4 is composed of quartz ± adularia ± calcite veins and hydrothermal breccias, hosting the main base metal and bonanza‐grade Au mineralization, and is associated with chlorite‐illite‐quartz alteration. Stage 5 is composed of epidote‐carbonate veins associated with epidote‐calcite‐chlorite alteration. Stage 6 is composed of anhydrite‐gypsum veins with minor base metal mineralization. The alteration assemblage of the deposit evolved from an acidic mineral assemblage caused by the condensation of magmatic volatiles from the Balibago Intrusive Complex into the groundwater to a slightly acidic mineral assemblage caused by the interaction of the host rocks and the circulating hydrothermal waters being heated up by the Dacite Porphyry Intrusives to a near‐neutral pH toward the later parts of the mineralization. Fluid inclusion microthermometry indicates that the temperature of the system started to increase during Stage 1 (T = 220–250°C) and remained at high temperatures (T = 250–290°C) toward Stage 6 due to the continuous intrusion of Dacite Porphyry Intrusives at depth. Salinity slightly decreased toward the later stages due to the contribution of more meteoric waters into the hydrothermal system. Boiling is considered the main mechanism of ore deposition based on the occurrence of rhombic adularia, the heterogeneous trapping of fluid inclusions of variable liquid–vapor ratios, the distribution of homogenization temperatures, and the gas ratios obtained from the quantitative fluid inclusion gas analysis of quartz. Ore mineral assemblage and sulfur fugacity determined from the FeS content of sphalerite at temperatures estimated by fluid inclusion microthermometry indicate that the base metal mineralization at Kay Tanda evolved from a high sulfidation to an intermediate sulfidation condition.     

Low temperature mud-explosion of Mt. Yaké, Prefs. Nagano-Gifu,Central Japan,on 17th June 1962 as an example of endogenous katamorphism of volcanic rock at the destructive stage of the volcano

Mt. Yaké or Yaké-daké is a dissected dome-shaped volcano mainly composed of the biotite bearing augite-hypersthene-hornblende andesite lavas extruded on the high mountain ridge consisting of the granite and hard Palaeozoic rocks between two prefectures Nagano and Gifu in the central part of Japan. It had been almost in dormant state only with weak fumarole activity on and around its summit dome since the former active period from 1907 to 1932. Incandescent lava emission has never been recorded in the historic age. On 17th June 1962 at about 21 h 55 m, a sudden explosion took place on the northern side of the dome. After successive explosions a fissure, about 700 m in length, was formed. On 19th from the northeast end of the fissure, milky hot water suspending muddy material flowed out. The mud flow ran down on the slope along the dry gully and poured into the Lake Taisyo-iké, about 2.5 km east of the vent. The lake was formed in 1915-eruption when a tremendous mud flow dammed up Azusagawa, the river running through the valley east of the volcano. Ejected blocks were deposited on the area within 1 km from the vent. Ash was deposited about 1 cm in thickness on the area about 4 km east of the volcano. Several mud flows poured into the Lake Taisyo-iké and the River Azusagawa. But no red-hot ejecta was observed during the present eruption, and temperature near the vent was lower than 100°C. Thus the present eruption is said to be low temperature phreatic explosions. In suspensoids of the hot water and in clayey matter deposited around the new vent are contained the montmorillonites, which hove never been found in the rocks exposed on the volcano in spite of the detailed investigation of the writers over 10 years. On the other hand, the mineral is not expected to be formed in the altered rocks under oxydized state on the surface. It was fine, at least no rain, before and during the explosions and the mud flow ran down along the dry gully. So the hot water was purely derived from the inner part of the volcano and the mud flow was not brought about by rain fall after deposition of ejecta on the volcano. The mud flow must have been formed endogenously under the volcano where the katamorphism of the rocks forming the volcano had advanced owing to chemical action of volcanic gas in the long period before the eruption.     

Fluid Inclusion and Stable Isotope Study at the Southeastern Martabe Deposit: Purnama,Barani and Horas Ore Bodies,North Sumatra,Indonesia

The Martabe Au–Ag deposit, North Sumatra Province, Indonesia, is a high sulfidation epithermal deposit, which is hosted by Neogene sandstone, siltstone, volcanic breccia, and andesite to basaltic andesite of Angkola Formation. The deposit consists of six ore bodies that occurred as silicified massive ore (enargite–luzonite–pyrite–tetrahedrite–tellurides), quartz veins (tetrahedrite–galena–sphalerite–chalcopyrite), banded sulfide veins (pyrite–tetrahedrite–sphalerite–galena) and cavity filling. All ore bodies are controlled by N–S and NW–SE trending faults. The Barani and Horas ore bodies are located in the southeast of the Purnama ore body. Fluid inclusion microthermometry, and alunite‐pyrite and barite‐pyrite pairs sulfur isotopic geothermometry show slightly different formation temperatures among the ore bodies. Formation temperature and salinity of fluid inclusions of the Purnama ore body range from 200 to 260 C and from 6 to 8 wt.% NaCl equivalent, respectively. Formation temperature and salinity of fluid inclusions of the Barani ore body range from 200 to 220 °C and from 0 to 2.5 wt.% NaCl equivalent and those of the Horas ore body range from 240 to 275 °C and from 2 to 3 wt.% NaCl equivalent, respectively. The Barani and Horas ore bodies are less silicified and sulfides are less abundant than the Purnama ore body. A relationship between enthalpy and chloride content indicates mixing of hot saline fluids with cooler dilute fluids during the mineralization of each of the ore bodies. The δ¹⁸O values of quartz samples from the southeast ore bodies exhibit a wide range from +4.2 to +12.9‰ with an average value of +7.0‰. The δ¹⁸O values of H₂O estimated from δ¹⁸O values of quartz, barite and calcite confirm the oxygen isotopic shift to near meteoric water trend, which support the incorporation of meteoric water. Salinity of the fluid inclusions decrease from >5 wt.% NaCl equivalent in the Purnama ore body to <3 wt.% NaCl equivalent in the Barani ore body, indicating different fluid systems during mineralization. The δ³⁴S values of sulfide and sulfate in Purnama range from ? 4.2 to +5.5‰ and from +1.2 to +26.7‰, those in the Barani range from ? 4.3 to +26.4‰ and from +3.9 to +18.5‰ and those in the Horas ore body range from ? 11.8 to +3.5‰ and from +1.4 to +25.7‰, respectively. The δ³⁴S of total bulk sulfur in southeastern ore bodies (Σδ³⁴S) was estimated to be approximately +6‰. The estimated sulfur fugacity during formation of the Purnama and Horas ore bodies is relatively high. It was between 10^?4.8 and 10^?10.8 atm at 220 to 260 °C. Tellurium fugacity was between 10^?7.8 and 10^?9.5 atm at 260 °C and between 10^?9 and 10^?10.6 atm at 220 °C in the Purnama ore body. The Barani ore body was formed at lower fS₂, lower than about 10^?14 atm at 200 to 220 °C based on the presence of arsenopyrite and pyrrhotite in the early stage, and between 10^?14 and 10^?12 atm based on the existence of enargite and tennantite in the last stage. © 2016 The Society of Resource Geology     

Geochemistry and Fluid Inclusions Analysis of Vein Quartz in the Multiple Hydrothermal Systems of Mankayan Mineral District,Philippines

Several high‐sulfidation epithermal gold orebodies in the Mankayan Mineral District were formed in an environment that has been already affected by earlier porphyry‐type mineralization. This study reports the geologic and geochemical characteristics of the Carmen and Florence epithermal orebodies, which are located in the south of the Lepanto main enargite–gold orebody. The gold‐bearing epithermal quartz veins in the Carmen and Florence areas are of two types: (i) the enargite‐rich veins and (ii) the quartz–pyrite–gold (QPG) veins. The two types of veins are mainly hosted by the Cretaceous Lepanto Metavolcanics basement rocks, with minor veins cutting the Pleistocene Imbanguila Dacite Pyroclastics. The mineral assemblages and homogenization temperatures of fluid inclusions indicate that the Carmen and Florence orebodies were deposited by fluids varying from high to very high sulfidation state. The enargite and QPG epithermal veins of Carmen and Florence cut porphyry‐type quartz veinlet stockworks and veins that host polyphase hypersaline fluid inclusions that did not homogenize at or below 400°C. These high‐temperature quartz exhibits distinctly different mineral chemistry from the quartz of the QPG and enargite‐rich epithermal veins. In particular, the Ti content of quartz of the porphyry‐type veinlet stockwork is elevated (>100 ppm), whereas the Ti concentration of the epithermal vein quartz crystals are below detection limits. The Fe concentration of quartz is high in epithermal vein quartz (>300 ppm), whereas nearly undetected in the porphyry‐type stockwork veinlet quartz. Multiple generations of quartz with different mineral chemistry, fluid inclusions morphology, temperature, salinity and bulk gas compositions, and stable isotopic ratios indicate the variable hydrothermal conditions throughout the mineralization history of the Mankayan District. The temperature, pH, sulfidation state, oxidation state, and fluid composition vary among the orebodies in Carmen and Florence areas. Furthermore, the characteristics of earlier alteration affected the apparent characteristics of subsequent mineralization.     

Upward transport of iron at the west shelf edge–slope of the Okinawa Trough in the East China Sea

We studied the behavior of chemical substances in the upper 300 m of the water column across the continental shelf–slope interface in the East China Sea off the Okinawa Trough. The behaviors of iron, inorganic nutrients, and humic-like fluorescent dissolved organic matter were strongly influenced by the extensive water exchange between the East China Sea and the Kuroshio Current across the shelf break and slope via upwelling and frontal processes. We attributed the high humic-like fluorescent intensity at the subsurface of the shelf break and slope regions to the lateral supply of humic-like fluorescent dissolved organic matter from the shelf sediments to the outer shelf region due to the intrusion of shelf water into Kuroshio subsurface water. We found that the behavior of iron at the continental shelf–slope was remarkably different from the conservative mixing of inorganic nutrients and humic-like fluorescent dissolved organic matter. In deep and bottom waters at the shelf–slope, high total iron concentrations, which were closely related to water transmittance, possibly resulted from the swept transport of iron-rich resuspended sediments over the shelf floor from the slope by the invading Kuroshio Intermediate Water close to the bottom.     

Amplification of semidiurnal internal tide observed in the outer part of Tokyo Bay

Monitoring using a thermistor array and an acoustic Doppler current profiler was carried out in the outer part of Tokyo Bay from May 20 to November 30, 2006. Current fluctuations with tidal periods were amplified during the maximum temperature period in early September. The strong current interfered with fishing operations using set nets. Although the current fluctuation was speculated to be baroclinic motion from a phase relationship among fluctuations of temperature, current and sea level, empirical orthogonal function analysis showed the dominance of a barotropic structure. Such a discrepancy in the current structure was explained by an internal tide propagating along a deep canyon in the outer part of Tokyo Bay. Furthermore, amplification of the semidiurnal internal tide and the warming of the temperature field were found to be induced by the intrusion of Kuroshio warm water. The amplification mechanism was examined using a two-dimensional model with idealized topography. It was concluded that the large amplitude of the semidiurnal internal tide is resonantly generated in the deep canyon in the outer Tokyo Bay when stratification becomes strong and the period of the internal seiche approaches the semidiurnal period.     

Epithermal Gold Mineralization in the Trenggalek District,East Java,Indonesia

Gold‐mineralized quartz veins at the Trenggalek district of the Southern Mountains Range in East Java, Indonesia, are hosted by Oligo‐Miocene volcaniclastic and volcanic rocks, and are distributed close to andesitic plugs in the northern prospects (Dalangturu, Suruh, Jati, Gregah, Jombok, Salak, and Kojan) and the southern prospects (Sentul and Buluroto). The plugs are subalkaline tholeiitic basaltic‐andesite to calc‐alkaline andesite in composition. ⁴⁰Ar–³⁹Ar dating of a quartz‐adularia vein at the Dalangturu prospect yielded an age of 16.29 ± 0.56 Ma (2σ), and a crystal tuff of a limestone‐pyroclastic rock sequence at the southwest of the Dalangturu prospect was determined as 15.6 ± 0.5 Ma (2σ). Statistic overlap of ages suggests that the gold mineralization in the northern prospects took place in a shallow marine to subaerial transitional environment. Hydrothermal alteration of the host rocks is characterized by the replacement of quartz, illite and adularia. Quartz veins in surface outcrops are up to 50 cm wide in the northern prospects and up to 3 m wide in the southern prospects, showing a banded or brecciated texture, and are composed of quartz, adularia, carbonates with pyrite, electrum, sphalerite, galena, and polybasite. Gold contents of quartz veins are positively correlated with Ag, Zn, Pb, and Cu contents in both the northern and southern prospects. The quartz veins at the Jati, Gregah, and Sentul prospects have relatively lower gold‐silver ratios (Ag/Au = 23.2) compared to those at the Kojan, Dalangturu, Salak, and Suruh prospects (Ag/Au = 66.8). The quartz veins at the Dalangturu prospect are relatively rich in base metal sulfides. Ag/(Au+Ag) ratios of electrum in the Dalangturu prospect range from 45.2 to 65.0 at%, and FeS contents of sphalerite range from 1.2 to 6.4 mol%. Fluid inclusion microthermometry indicates ore‐forming temperatures of 190–200°C and 220–230°C at the Sentul and Kojan prospects, respectively. Widely variable vapor/liquid ratio of fluid inclusions indicates that fluid boiling took place within the hydrothermal system at the Sentul prospect. Salinities of ore‐fluids range from 0 to 0.7 wt% (av. 0.4 wt% NaCl equiv.) and from 0.5 to 1.4 wt% (av. 0.9 wt%) for the Sentul and Kojan prospects, respectively. The boiling of hydrothermal fluid was one of the gold deposition mechanisms in the Sentul prospect.