Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances

We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases.     

Single-station ellipticity retrieval and its joint inversion with dispersion curve,for a borehole test site

To obtain the shear wave velocity profile for engineering application to near-subsurface, many geophysical techniques are used. The dispersion curve alone is unable to provide deeper shear wave velocity information for deep soil deposit; therefore, a joint inversion of dispersion curves with the horizontal over vertical (H/V) (i.e., apparently ellipticity) curve is recommended. The H/V curve obtained from the microtremor recording contains a major part of Love wave contribution to the noise wavefield horizontal component. Due to this presence of Love wave fraction, the H/V curve does not completely replicate the ellipticity of Rayleigh wave. In this study, we try to compare the Rayleigh wave ellipticity obtained from the borehole velocity model to the H/V curve obtained at the same locality from seismic ambient noise recording. Two different techniques available for the Love effect minimization are tested and compared with the borehole ellipticity. Finally, the joint inversion of H/V and dispersion curve is made, which shows great correspondence with the previous measurement at the site.     

How old is Luzia? Luminescence dating and stratigraphic integrity at Lapa Vermelha,Lagoa Santa,Brazil

During an excavation in the 1970s, a disarticulated female human skeleton, later nicknamed Luzia, was discovered at 12m depth at Lapa Vermelha rockshelter in central Brazil. Radiocarbon dating of associated charcoal suggested an age of 11.4‐16.4 ka for the skeleton. The scattering of the skeletal parts, some uncertainty about the exact provenience of the skeleton, and evidence of pervasive insect turbation in the archaeological layers have raised doubts about the accuracy of the age. Luminescence dates for the depositional ages of the sediments at Lapa Vermelha are reported here. Single‐grain optically stimulated luminescence (OSL) of quartz along with grain‐size, chemical and micro‐morphological analyses of the sediments were employed to assess stratigraphic integrity, particularly the degree of sediment mixing. These various lines of evidence point to high stratigraphic integrity with little mixing at Lapa Vermelha. Sediments closest to where Luzia was recovered give OSL ages ranging from 12.7 to 16.0 ka, thus not refuting the original dates. © 2010 Wiley Periodicals, Inc.     

Boundary-Layer Stress Instabilities in Neutral,Rotating Turbulent Flows

Boundary-layer instabilities are studied by analyzing the results of laboratory simulations of wall turbulence in a shear-driven rotating flow. The experiments were carried out in the Turin University Laboratory rotating water tank, where a circular flow was generated by either increasing (spin-up) or decreasing (spin-down) the rotation speed of the platform. The flow was measured using a Particle Image Velocimetry technique and the developed turbulence analyzed. Two cases were accounted for, in the former the measurements were performed over a smooth surface (bottom of the tank), while in the latter a rough-to-smooth transition was considered. The turbulent boundary layer developed inside the tank is analyzed by means of vertical profiles of mean and turbulent quantities and on the basis of drag coefficients. Then turbulent structures developed in the different cases are shown and discussed in terms of the vorticity fields. Finally, an analysis based on the concept of swirling strength was carried out to select among the vortex extremes those associated with a coherent structure.     

Behaviour of metals and nutrients in soils and groundwater of a karst polje

The Croatian south part of the country is mainly composed of strongly krastified carbonate rocks. Also in this south part of Croatia is lacking of large depressions and poljes with thick covers. Some karst poljes and depressions may have thick covers, like for example the Vransko polje. The Vransko polje is characterised by an intensive agricultural activity. At the centre of the polje is located a karst spring (Turanjsko jezero), which is used for the water supply of the town Biograd and its surroundings. Total metals, nutrients (nitrate, ammonia, phosphate), organic matter content and cation exchange capacity (CEC) were measured in soil samples collected from the polje. Metals and nutrients were also measured in the water samples of channel Kotarka (which is passing through the area) and three springs (Turanjsko jezero, Kakma and Tinj). Measured total concentrations of metals of soil samples were treated by R-cluster multivariate statistical analysis. The result of statistical analysis showed grouping of metals with similar behaviour. Content of metals and nutrients were low in the spring samples but high in the water sample of the channel Kotarka, because the channel drains the water from the surroundings. Although agricultural activity in the Vransko polje is high, there is no high anthropogenic influence on groundwater and soil. They are both of good quality.     

Reduced-order optimal control of water flooding using proper orthogonal decomposition

Model-based optimal control of water flooding generally involves multiple reservoir simulations, which makes it into a time-consuming process. Furthermore, if the optimization is combined with inversion, i.e., with updating of the reservoir model using production data, some form of regularization is required to cope with the ill-posedness of the inversion problem. A potential way to address these issues is through the use of proper orthogonal decomposition (POD), also known as principal component analysis, Karhunen–Loève decomposition or the method of empirical orthogonal functions. POD is a model reduction technique to generate low-order models using ‘snapshots’ from a forward simulation with the original high-order model. In this work, we addressed the scope to speed up optimization of water-flooding a heterogeneous reservoir with multiple injectors and producers. We used an adjoint-based optimal control methodology that requires multiple passes of forward simulation of the reservoir model and backward simulation of an adjoint system of equations. We developed a nested approach in which POD was first used to reduce the state space dimensions of both the forward model and the adjoint system. After obtaining an optimized injection and production strategy using the reduced-order system, we verified the results using the original, high-order model. If necessary, we repeated the optimization cycle using new reduced-order systems based on snapshots from the verification run. We tested the methodology on a reservoir model with 4050 states (2025 pressures, 2025 saturations) and an adjoint model of 4050 states (Lagrange multipliers). We obtained reduced-order models with 20–100 states only, which produced almost identical optimized flooding strategies as compared to those obtained using the high-order models. The maximum achieved reduction in computing time was 35%.     

The 1669 eruption at Mount Etna: chronology,petrology and geochemistry,with inferences on the magma sources and ascent mechanisms

 Analysis of the petrochemical characters of the 1669 Etnean lavas shows that they can be grouped into two sets: SET1 lavas were erupted from 11 to 20 March and are more primitive in composition than SET2, erupted later until the end of activity. Both sets may be interpreted as the result of crystallization under different conditions of two primary magmas which are compositionally slightly distinct and which fractionate different volumetric proportions of minerals. To explain why more mafic lavas (SET1) were erupted earlier than more acid ones (SET2), we argue that new deeper magma rose up into a reservoir where residing magma was fractionating. Density calculations demonstrate that new magma is less dense and may originate a plume, rapidly rising through the residing magma which is cooler and more volatile-depleted than the new magma. Calculations of uprise velocity assuming laminar flow are consistent with this hypothesis. Received: 20 November 1995 / Accepted: 2 August 1996     

Tectonic activation,source area stratigraphy and provenance changes in a rift basin: the Early Cretaceous Tucano Basin (NE‐Brazil)

Changes in sandstone and conglomerate maturity in tectonically active basins can be considered either as the product of climatic change or of tectonic restructuring of the feeder drainage system. Besides these regional controls, changes in the configuration of local sources can expressively affect basin fill composition. The Early Cretaceous fluvial successions of the Tucano Basin, a rift basin in northeastern Brazil related to the South Atlantic opening, contain one such case of abrupt change in maturity, marked by the passage from pebbly sandstone and conglomerate rich in quartz and quartzite fragments (Neocomian to Barremian São Sebastião Formation) to more feldspathic pebbly sandstone and conglomerate bearing pebbles of varied composition (Aptian Marizal Formation). Systematic analysis of stratigraphic and spatial variation in palaeocurrents and composition of pebbles and cobbles from both units, integrated with the recognition of fluvial and alluvial fan deposits distribution, revealed an abrupt decrease in maturity during the passage from the São Sebastião Formation to the Marizal Formation. This change is explained by exhumation of basement rocks and erosional removal of originally widespread Silurian to Jurassic sandstone and conglomerate units which were a major source of reworked vein quartz and quartzite pebbles to the São Sebastião Formation. Basin border faults activation during the deposition of the Marizal Formation caused adjacent basement uplift above the local erosional base level at the basin borders, whereas during the São Sebastião Formation deposition, the basin border fault scarps probably exposed mineralogically mature sedimentary units. The proposed model has important implications for interpreting changes in sediment maturity in rift basin successions, as similar results are expected where activation of basin border faults occurs after the erosional removal of older sedimentary or volcanic units that controlled syn‐rift successions composition.     

Mechanisms for ground-surface fracturing and incipient slope failure associated with the 2001 eruption of Mt. Etna, Italy: analysis of ephemeral field data

During the July–August 2001 eruption of Mt. Etna development of extensional fractures/faults and grabens accompanied magma intrusion and subsequent volcanic activity. During the first days of the eruption, we performed an analysis of attitude, displacement and propagation of fractures and faults exposed on the ground surface in two sites, Torre del Filosofo and Valle del Leone, located along the same fracture system in the region surrounding the Valle del Bove depression on the eastern flank of Mt. Etna. Fractures and faults formed as the consequence of a shallow intruding dyke system that fed the several volcanic centres developed along the fracture system. The investigated sites differ in slope attitude and in geometrical relationships between fractures and slopes. In particular, the fracture system propagated parallel to the gentle slope (<7° dip) in the Torre del Filosofo area, and perpendicular to the steep slope (25° dip) in the Valle del Leone area. In the Torre del Filosofo area, slight graben subsidence and horizontal extension of the ground surface by about 3 m were recorded. In the Valle del Leone area, extensional faulting forming a larger and deeper graben with horizontal extension of the ground surface by about 10 m was recorded. For the Valle del Leone area, we assessed a downhill dip of 14° for the graben master fault at the structural level beneath the graben where the fault dip shallows. These results suggest that dyke intrusion at Mount Etna, and particularly in the region surrounding the Valle del Bove depression, may be at the origin of slope failure and subsequent slumps where boundary conditions, i.e. geometry of dyke, slope dip and initial shear stress, amongst others, favour incipient failures.