Enzymatic synthesis of methyl-galactoaldehyde

Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide synthesis.     

The exact theory of inductive conductivity sensors for oceanographic application

The results of a general theoretical investigation of three commonly used types of inductive conductivity sensors, i.e., the single transformer, the double transformer, and the double transformer with an additional loop, are presented. The resulting formulas describe the dependence of the sensor output signal not only on the conductivity of the seawater but also on the parameters of the electrical circuit, among them the permeability of the transformer core(s), which-unlike the other parameters-shifts considerably during oceanographic in situ measurements. A mathematical discussion of these formulas shows that for certain circuit configurations, the sensor output is independent of changes in permeability. Most of these configurations form the basis of existing oceanographical conductivity sensors, among them the "classical" sensors developed by H. Hinkelmann [3], [4], and by N. L. Brown [14], while some others make evident further possibilities for eliminating the unwanted effects of shifting permeability. In the era of microelectronics, the latter might lead to a reassessment, especially of the single transformer-type sensor.     

Axial convergence in a well-mixed estuary

Transverse secondary circulations involving surface convergence, observed in a well-mixed estuary in North Wales, are made visible by the collection of surface material along an axial line which extends continuously for many kilometres through the estuary. The circulation and axial convergence, however, are seen only during the flood phase of the tide and no similar behaviour has been observed during the ebb phase.Convergent circulations in the estuary are associated with small but steady transverse density gradients in the cross-section, produced by non-uniform advection of the longitudinal gradient through the channel. A diagnostic model, using measured mean distributions of cross-sectional density, indicates surface transverse velocities (～0.1 ms^?1) similar to those observed in the estuary. The model further predicts appreciable transverse divergent currents at a fractional depth of 0.75: a prediction which has been tested in the estuary using a vertical array of accurately resolving current direction indicators.     

长江上游洪涝暴雨环流形势中期演变趋势分析

本文通过对1980年以来长江上游10次洪涝过程的500hpa环流形势分析,并用车比雪夫多项式对500hpa高度场进行展开,研究了各类洪涝过程的中期演变特征,发现代表不同洪涝过程环流形势变化的不同的车氏系数值都有明显的特征变化,结合欧洲中心中期数值预告96小时500hpa高度场的车氏系数分析,可为洪涝暴雨的中期预报提供一种新的思路。     

Consideration of time-correlated errors in a Kalman filter applicable to GNSS

An algorithm for considering time-correlated errors in a Kalman filter is presented. The algorithm differs from previous implementations in that it does not suffer from numerical problems; does not contain inherent time latency or require reinterpretation of Kalman filter parameters, and gives full consideration to additive white noise that is often still present but ignored in previous implementations. Simulation results indicate that the application of the new algorithm yields more realistic and therefore useful state and covariance information than the standard implementation. Results from a field test of the algorithm applied to the problem of kinematic differential GPS demonstrate that the algorithm provides slightly pessimistic covariance estimates whereas the standard Kalman filter provides optimistic covariance estimates.     

Age and early metamorphic history of the Sanbagawa belt: Lu–Hf and P–T constraints from the Western Iratsu eclogite

Two distinct age estimates for eclogite-facies metamorphism in the Sanbagawa belt have been proposed: (i) c.  120–110 Ma based on a zircon SHRIMP age for the Western Iratsu unit and (ii) c.  88–89 Ma based on a garnet–omphacite Lu–Hf isochron age from the Seba and Kotsu eclogite units. Despite the contrasting estimates of formation ages, petrological studies suggest the formation conditions of the Western Iratsu unit are indistinguishable from those of the other two units—all ∼20 kbar and 600–650 °C. Studies of the associated geological structures suggest the Seba and Western Iratsu units are parts of a larger semi-continuous eclogite unit. A combination of geochronological and petrological studies for the Western Iratsu eclogite offers a resolution to this discrepancy in age estimates. New Lu–Hf dating for the Western Iratsu eclogite yields an age of 115.9 ± 0.5 Ma that is compatible with the zircon SHRIMP age. However, petrological studies show that there was significant garnet growth in the Western Iratsu eclogite before eclogite facies metamorphism, and the early core growth is associated with a strong concentration of Lu. Pre-eclogite facies garnet (Grt1) includes epidote–amphibolite facies parageneses equilibrated at 550–650 °C and ∼10 kbar, and this is overgrown by prograde eclogite facies garnet (Grt2). The Lu–Hf age of c.  116 Ma is strongly skewed to the isotopic composition of Grt1 and is interpreted to reflect the age of the pre-eclogite phase. The considerable time gap ( c.  27 Myr) between the two Lu–Hf ages suggests they may be related to separate tectonic events or distinct phases in the evolution of the Sanbagawa subduction zone.     

Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

Evolution of Electric Currents Associated with Two M-Class Flares

Using one-minute cadence vector magnetograms from Big Bear Solar Observatory (BBSO), we analyze the temporal behavior of derived longitudinal electric currents associated with two flares on July 26, 2002. One of the events is an M1.0 flare which occurred in active region NOAA 10044, while the other is an M8.7 flare in the adjacent region 10039. Rapid changes of magnetic fields in the form of flux emergence are found to be associated with both of these events. However, the temporal behavior of electric currents are very different. For the M1.0 flare, the longitudinal electric current density drops rapidly near the flaring neutral line; while for the M8.7 flare, the current density rapidly increases, confirming the picture of the current-carrying flux emergence. We offer a possible explanation for such a difference: magnetic reconnection at different heights for the two events, near the photosphere for the M1.0 flare, and higher up for the M8.7 flare.