Three-dimensional hydrostratigraphical modelling to support evaluation of recharge and saltwater intrusion in a coastal groundwater system in Vietnam

Saltwater intrusion is generally related to seawater-level rise or induced intrusion due to excessive groundwater extraction in coastal aquifers. However, the hydrogeological heterogeneity of the subsurface plays an important role in (non-)intrusion as well. Local hydrogeological conditions for recharge and saltwater intrusion are studied in a coastal groundwater system in Vietnam where geological formations exhibit highly heterogeneous lithologies. A three-dimensional (3D) hydrostratigraphical solid model of the study area is constructed by way of a recursive classification procedure. The procedure includes a cluster analysis which uses as parameters geological formation, lithological composition, distribution depth and thickness of each lithologically distinctive drilling interval of 47 boreholes, to distinguish and map well-log intervals of similar lithological properties in different geological formations. A 3D hydrostratigraphical fence diagram is then generated from the constructed solid model and is used as a tool to evaluate recharge paths and saltwater intrusion to the groundwater system. Groundwater level and chemistry, and geophysical direct current (DC) resistivity measurements, are used to support the hydrostratigraphical model. Results of this research contribute to the explanation of why the aquifer system of the study area is almost uninfluenced by saltwater intrusion, which is otherwise relatively common in coastal aquifers of Vietnam.     

Public perception of climate change and disaster preparedness: Evidence from the Philippines

The Philippines is highly susceptible to both geophysical and climate-related disasters. This article explores Filipinos knowledge and perception of climate change and their association with what action Filipinos take to prepare for rapid onset natural hazards such as typhoons. Data for this study were collected from a nationally representative random survey of 5,184 adults conducted between March and April of 2017. Filipinos self-report relatively low levels of knowledge of climate change and cited increased temperatures, shifts in seasons, and heavier rains as the most likely consequences. Levels of disaster preparedness in the Philippines differ widely by region. Although most Filipinos perceive that natural hazards are a risk to them, only a third of Filipinos undertake measures to prepare for disasters. Filipinos who perceive climate-related changes directly impacting their households report taking greater action to prepare for disasters. Filipinos who believe they have been directly impacted by climate-related changes are also more likely to prepare for disasters, take planning actions, and undertake material actions to prepare, such as dwelling improvements. Other factors associated with disaster preparedness include gender, membership in an association, wealth, risk perception, and prior exposure to and losses due to disasters. The findings imply that, while posing different challenges and requiring different responses, adaptation to climate change and disaster preparedness are inherently associated and potentially mutually reinforcing. Policies and programs would arguably benefit from a more unified intervention framework that links climate change adaptation and disaster preparedness.     

Using salt intrusion measurements to determine the freshwater discharge distribution over the branches of a multi-channel estuary: The Mekong Delta case

The fresh water discharge is an important parameter for modelling salt intrusion in an estuary. In alluvial converging estuaries during periods of low flow, when salinity is highest, the river discharge is generally small compared to the tidal flow. This makes the determination of the fresh water discharge a challenging task. Even if discharge observations are available during a full tidal cycle, the fresh water discharge is seldom much larger than the measurement error in the tidal discharge. Observations further upstream, outside the tidal region, do not always reflect the actual flow in the saline area due to withdrawals or additional drainage. Discharge computation is even more difficult in a complex system such as the Mekong Delta, which is a multi-channel estuary consisting of many branches, over which the freshwater discharge distribution cannot be measured directly. This paper presents a new approach to determine the freshwater discharge distribution over the branches of the Mekong Delta by means of an analytical salt intrusion model, based on measurements made during the dry season of 2005 and 2006. It appears that the analytical model agrees well with observations and with a hydraulic model. This paper demonstrates that with relatively simple and appropriate salinity measurements and making use of the analytical salt intrusion model, it is possible to obtain an accurate discharge distribution over the branches of a complex estuary system. This makes the analytical model a powerful tool to analyze the water resources in tidal regions.     

Predicting soil erosion hazard in Lattakia Governorate(W Syria)

The main objective of this study is to predict soil erosion in the Lattakia Governorate(WSyria)using the Water Erosion Prediction Project model(WEPP)and to compare the result with that of the RUSLE.Field survey and data collection were carried out,and 44 soil samples were analyzed.In addition,all the necessary input files were prepared for use in the WEPP model and RUSLE.Results show that more than of 80%of the locations studied experience slight to moderate erosion(less than 5 t/ha/y),whereas the rest of the locations experience severe soil erosion hazard.Moreover,the volume of runoff estimated by the WEPP model is in the range of 51e321 mm,and the R^2 between the simulated soil erosion and the predicted runoff reached 0.68.Interestingly,the R^2 between the WEPP model and RUSLE is 0.56,which indicates a good correlation between the two models.     

Influence of phosphate on the oxidation kinetics of nanomolar Fe(II) in aqueous solution at circumneutral pH

The oxygenation kinetics of nanomolar concentrations of Fe(II) in aqueous solution have been studied in the absence and presence of millimolar concentrations of phosphate over the pH range 6.0-7.8. At each phosphate concentration investigated, the overall oxidation rate constant varied linearly with pH, and increased with increasing phosphate concentration. A model based on equilibrium speciation of Fe(II) was found to satisfactorily explain the results obtained. From this model, the rate constants for oxygenation of the Fe(II)-phosphate species FeH₂PO₄⁺, FeHPO₄ and FePO₄⁻ have been determined for the first time. FePO₄⁻ was found to be the most kinetically reactive species at circumneutral pH with an estimated oxygenation rate constant of (2.2 ± 0.2) × 10 M⁻¹ s⁻¹. FeH₂PO₄⁺ and FeHPO₄ were found to be less reactive with oxygen, with rate constants of (3.2 ± 2) × 10⁻² M⁻¹ s⁻¹ and (1.2 ± 0.8) × 10⁻¹ M⁻¹ s⁻¹, respectively.     

Geochemistry of surface waters in the vicinity of open pit mines at the Cay Cham deposit, Thai Nguyen province, northern Vietnam

This study provides an assessment of the environmental impact of open pit mining operations at the Cay Cham titanomagnetite-ilmenite deposit (northern Vietnam). The results of surface water sampling indicate the formation of acid mine drainage and contamination of adjacent areas by heavy metals (Cu, Zn, Ni, and Mn). The acid mine drainage is produced by oxidation leaching of sulfide minerals associated with primary mineralization owing to the low neutralization potential of the natural waters in the humid environment of tropical rainforest. The study showed that alternating dry and wet seasons typical of this climatic region promote the generation of stored acidity leading to a sharp decrease in pH of drainage water during the wet season and result in the negative impacts of this mine on both flowing and stagnant surface waters.     

Application of multimedia methodology for investigation of karst water in highland regions of Ha Giang Province, Vietnam

Ha Giang is one of the largest, northern border provinces of Vietnam, consisting of four districts: Yen Minh, Quan Ba, Dong Van and Meo Vac. This province features varied karst landscape of Carboniferous–Permian limestone. The region has been recognized by UNESCO as one of the 77 geological parks in the world and the second in Southeast Asia on 3 October 2012. In the dry season, little or no rain is recorded; therefore, surface water is very scarce. For this reason, proper delineation and exploitation of the groundwater resource is critical for sustainable water supply. This has been identified as an important challenge under the scientific project KC-08-10 in the national program KC-08. Remote sensing and GIS were used to decipher the signature of karst water in the highland of Ha Giang. Information layers generated were subjected to multi-criteria evaluation using analytic hierarchy process for decision making to identify ideal locations for groundwater prospecting. The study resulted in delineation of ten zones for all regions and 18 ideal drilling sites in Tam Son Town of Quan Ba District. Drilling and resistivity soundings were performed to assess the success of the interpretation. Deep resistivity survey confirmed low resistivity (200–300 Ωm) near the identified potential sites in Tam Son Town of Quan Ba District. Further, successful drilling at site LKTS1 with a discharge of 7–9 l/s is observed, proving the potential of this methodology for rapid exploration of groundwater in water-scare karst terrains of Vietnam.     

Rotenone treatment has a short-term effect on New Zealand stream macroinvertebrate communities

Invasive fish eradication is a key management strategy in aquatic ecosystems, and is often accomplished using piscicides such as rotenone. However, the effects of piscicides on aquatic invertebrate communities are poorly understood, particularly over long time scales. We monitored invertebrate communities in two treatment and two reference streams prior to and for one year following the use of rotenone to eradicate trout in Zealandia wildlife sanctuary, Wellington. Immediately following treatment, invertebrate density and taxonomic richness declined significantly, and community composition diverged markedly relative to reference streams, with pollution sensitive taxa declining greater than more tolerant taxa. Treatment streams recovered to pre-treatment conditions within 4–12 months of rotenone application, indicating minor long-term impacts on invertebrate communities. Speed of recovery of individual taxa appeared to be associated with life history variables, e.g. generation times and dispersal ability. Untreated upstream reaches and nearby water bodies likely facilitated successful invertebrate community recovery. Our results demonstrate that rapid recovery of New Zealand stream invertebrate communities is possible within one year of rotenone application.     

豫西地区秦岭造山带武当群Nd-Hf同位素组成及其物源特征

武当群变质沉积-火山岩组合是南秦岭地体中重要的基底岩石,其形成时代和地球化学特征可以为理解秦岭造山带的构造演化提供重要的证据.本文报道豫西地区武当群上部沉积岩和下部中-酸性火山岩Sm-Nd同位素和锆石Lu-Hf同位素组成,探讨火山岩成因和沉积岩物源的同位素特征.上部沉积岩的碎屑锆石初始ε_(Hf)值变化在-30～+10之间,对应的模式年龄值t_(DM2)在1.0Ga至3.2Ga之间,初始ε_(Nd)值在-4.0至-6.0之间.沉积物源表现为主要与扬子陆块有亲缘关系的地壳物质和近源的下部火山岩混合的特征.火山岩的锆石初始εHf值变化在-35～+15之间,对应的模式年龄值t_(DM2)在0.8Ga至3.5Ga之间,集中于1.5～1.8Ga和2.2～2.4Ga两个峰值.2个变质石英角斑岩样品初始ε_(Nd)值分别为-9.2和-10.7,而报道的湖北武当群的玄武-安山质熔岩的初始ε_(Nd)值以正值为主.因此,武当群不同类型的火山岩可能存在着成因差异.具有低初始ε_(Nd)值和ε_(Hf)值特征的火山岩可能由地壳物质的重熔而形成的;有些火山岩具有初始ε_(Hf)值变化范围较大(-35～+15)或正初始ε_(Nd)值的特点,可能是壳、幔物质混合成因,有显著的幔源或新生地壳物质的贡献.武当群Nd-Hf同位素组成和碎屑锆石年龄分布特征表明,与扬子陆块有亲缘关系的南秦岭地体在元古代期间可能经历多期地壳增生和再造作用.     

Remarkably uniform oxygen isotope systematics for co-existing pairs of gem-spinel and calcite in marble,with special reference to Vietnamese deposits

Oxygen isotope systematics for co-existing pairs of gem-spinel and calcite in marble from Vietnam and other worldwide deposits have been determined in order to characterize the O-isotope fractionation between calcite and spinel. In Vietnam, the Δ¹⁸O_cc–sp (= 3.7 ± 0.1‰ for six samples from the An Phu and Cong Troi deposits) is remarkably constant. The combination of these data with those obtained on calcite–spinel pairs of Paigutan (Nepal, n = 2), Ipanko (Tanzania, n = 1), and Mogok (Myanmar, = 2) are also consistent with an overall Δ¹⁸O_cc–sp of 3.6 ± 0.3‰ for all the spinel samples (n = 11). The straight line correlation δ¹⁸O_cc = 0.96 δ¹⁸O_sp + 4.4 is excellent despite their worldwide geographic spread. The increment method of calculating oxygen isotope fractionation gave a geologically unreasonable temperature of formation for both minerals at 1374 °C when compared to temperatures obtained by mineral assemblage equilibrium of these marble type deposits, between 610 and 750 °C. The constant Δ¹⁸O_cc–sp reflects a constant temperature for this amphibolite facies assemblage, whose current best estimate is calculated at 620 ± 40 °C, but unquantified uncertainties remain.