Weathering geochronology by (U-Th)/He dating of goethite

Nine samples of supergene goethite (FeOOH) from Brazil and Australia were selected to test the suitability of this mineral for (U-Th)/He dating. Measured He ages ranged from 61 to 8 Ma and were reproducible to better than a few percent despite very large variations in [U] and [Th]. In all samples with internal stratigraphy or independent age constraints, the He ages corroborated the expected relationships. These data demonstrate that internally consistent He ages can be obtained on goethite, but do not prove quantitative ⁴He retention. To assess possible diffusive He loss, stepped-heating experiments were performed on two goethite samples that were subjected to proton irradiation to produce a homogeneous distribution of spallogenic ³He. The ³He release pattern indicates the presence of at least two diffusion domains, one with high helium retentivity and the other with very low retentivity at Earth surface conditions. The low retentivity domain, which accounts for ∼ 5% of ³He, contains no natural ⁴He and may represent poorly crystalline or intergranular material which has lost all radiogenic ⁴He by diffusion in nature. Diffusive loss of ³He from the high retentivity domain is independent of the macroscopic dimensions of the analyzed polycrystalline aggregate, so probably represents diffusion from individual micrometer-size goethite crystals. The ⁴He/³He evolution during the incremental heating experiments shows that the high retentivity domain has retained 90%-95% of its radiogenic helium. This degree of retentivity is in excellent agreement with that independently predicted from the helium diffusion coefficients extrapolated to Earth surface temperature and held for the appropriate duration. Considering both the high and low retentivity domains, these data indicate that one of the samples retained 90% of its radiogenic ⁴He over 47.5 Ma and the other retained 86% over 12.3 Ma. Thus while diffusive-loss corrections to supergene goethite He ages are required, these initial results indicate that the corrections are not extremely large and can be rigorously quantified using the proton-irradiation ⁴He/³He method.     

Hypsometric Curves as a Tool for Paleosurface Mapping

A procedural paleosurface mapping tool, using hypsometric curves and digital elevation models, was developed and applied to three hydrographic basins that erode common areas in the coastal ranges of Brazil, in southeastern South America. The method consists of identifying areas favorable for the occurrence of paleosurfaces and their corresponding surficial formations as correlated to specific erosion events. Attributes from hypsometric curves, and logarithmic functions fitted to proper curve segments, are combined with common morphometric properties of paleosurfaces given a set of criteria. Zones satisfying the criteria are mapped as pertaining to specific paleosurfaces. Field survey confirms the agreement between predicted and observed occurrence and absence of paleosurfaces.     

Bayesian and multivariate methods applied to favorability quantification in Recôncavo Basin and Ribeira Belt, Brazil

A methology to define favorable areas in petroleum and mineral exploration is applied, which consists in weighting the exploratory variables, in order to characterize their importance as exploration guides. The exploration data are spatially integrated in the selected area to establish the association between variables and deposits, and the relationships among distribution, topology, and indicator pattern of all variables. Two methods of statistical analysis were compared. The first one is the Weights of Evidence Modeling, a conditional probability approach (Agterberg, 1989a), and the second one is the Principal Components Analysis (Pan, 1993). In the conditional method, the favorability estimation is based on the probability of deposit and variable joint occurrence, with the weights being defined as natural logarithms of likelihood ratios. In the multivariate analysis, the cells which contain deposits are selected as control cells and the weights are determined by eigendecomposition, being represented by the coefficients of the eigenvector related to the system’s largest eigenvalue. The two techniques of weighting and complementary procedures were tested on two case studies: 1. Recôncavo Basin, Northeast Brazil (for Petroleum) and 2. Itaiacoca Formation of Ribeira Belt, Southeast Brazil (for Pb-Zn Mississippi Valley Type deposits). The applied methdology proved to be easy to use and of great assistance to predict the favorability in large areas, particularly in the initial phase of exploration programs.     

Water and sediment movement around a coastal headland: Portland Bill,southern UK

Numerical simulations of tidal flow and sand transport around a coastal headland (Portland Bill, southern UK) were undertaken to investigate patterns of sand transport during the development of tidally induced transient eddies. Results obtained from a 2-D finite-element hydrodynamic model (TELEMAC-2D) were combined with a sediment transport model (SEDTRANS), to simulate the sand transport processes around the headland. Simulation of the tidal flow around Portland Bill has shown the formation and evolution of tidally induced transient eddies, around the headland. During the evolution of these transient eddies, no current-induced bedload (transport) eddy is formed for either side of the headland. Net bedload sand transport direction, around a coastal headland, is the result of instantaneous gradients in bedload transport rates, during flood and ebb flows, rather than the average (residual) flow. Thus, the use of residual (water) circulation to describe patterns of sediment movement as bedload is not an appropriatedapproach. In the case study presented here, the distinct characteristics of the coastal and seabed morphology around the Isle of Portland (i.e. headland shape and the bathymetry) indicate that these parameters can be influencing tidal (flow) and sediment dispersion around the headland. Such an interpretation has broader implications and applications to headland-associated sandbanks elsewhere.Responsible Editor: Hans Burchard     

Morphology and internal structure of sand shoals and sandbanks off the Dorset coast, English Channel

The morphology and internal structure of sand shoals and sandbanks around a coastal headland (Portland Bill, southern UK) are described on the basis of sidescan sonar and high-resolution seismic data sets. Morphological and architectural evidence, combined with the spatial distribution and nature of the bedrock surface, indicates that the evolution of these deposits, especially the sandbanks, may not only be hydrodynamically controlled but also morphologically controlled. The internal structure of the sand shoals reveals a simple pattern of clinoforms dipping in the same direction as their steeper profile. In contrast, the internal structure of the sandbanks reveals that their lower seismic units consist of a sedimentary core interpreted as the remains of a lowstand deposit or an early stage of the bank development under different prevailing hydrodynamic conditions. The present morphology of the sandbanks is represented by upper seismic units characterized by large-scale sandwave foresets dipping at 6–8°. The nature and morphology of the bedrock surface may also influence the development of sandbanks in some cases. For example, to the west of Portland Bill, the morphology of the bedrock surface (basal reflector) restricts the development of the Portland Bank. This information may explain the asymmetric evolution of sandbanks around Portland Bill.     

The use of GPR for characterizing underground weathered profiles in the sub-humid tropics

Ground penetrating radar (GPR) has been used as a tool to access information about ground subsurface features. Such information is very important for different types of studies, varying from those related to archeological research to those studying geological elements of bedrock. More recently, however, GPR has been increasingly applied to environmental studies, especially for soil research. This paper presents the results of an application of GPR for the study of weathered profiles. GPR was used to discover the degree of trustworthiness of the information on the ground subsurface through the interpretation of the results of the radar sections as well as the data collected from boreholes, which reached until 21 m. The results show a relatively high degree of details obtained by GPR, indicating the possibility of speeding up ground subsurface surveys related to geomorphological, geological, and pedological studies.     

HT-fabrics in a garnet-bearing quartzite from Western Portugal: geodynamic implications for the Iberian Variscan Belt

ABSTRACT The study of a garnet-bearing quartzite from a major suture zone in Iberia reports an unusual high-T fabric. Quartz c -axis patterns were plotted using shaped garnet as reference axis for the finite stretch ( X -axis). The pole figures are characterized by a dominant single maximum around X together with other point maxima along the XY plane (mylonitic foliation). These patterns suggest that dominant < c > prism slip and subordinated < a > prism slip operated during quartz plastic deformation in agreement with P–T conditions for syntectonic garnet growth (4–5 kbar and 700 ± 50 °C) and, pre-dating the well-known (late) Variscan D1 event (<6 kb and 600 ± 30 °C). The geotectonic framework suggests that the fabrics were formed along the western shear margin of the Ossa-Morena Zone during the early stages of the Variscan orogeny.     

Timing and duration of supergene mineralization at the Xinrong manganese deposit,western Guangdong Province,South China: cryptomelane <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating

Supergene Mn-oxide deposits are widely distributed in Guangxi, Guangdong, Yunnan, and Hunan Provinces, South China, accounting for 18% of the total Mn reserves in the country. Direct dating of supergene Mn enrichment, however, is lacking. In this paper, we present high-resolution ⁴⁰Ar/³⁹Ar ages of Mn oxides from the Xinrong Mn deposit, western Guangdong, to place numerical constraints on the timing and duration of supergene Mn enrichment. A total of ten cryptomelane samples, spanning a vertical extent of 67 m, were dated using the ⁴⁰Ar/³⁹Ar laser incremental heating technique, with seven samples yielding well-defined plateau or pseudo-plateau ages ranging from 23.48 ± 0.91 to 2.06 ± 0.05 Ma (2σ). One sample yields a staircase spectrum that does not reach a plateau; the spectrum, however, indicates the presence of two or more generations of Mn oxides in the sample, whose ages are best estimated at 22.34 ± 0.31 and 10.2 ± 0.86 Ma, respectively. The remaining two samples gave meaningless or uninterpretable results due to significant ³⁹Ar recoil and contamination by old phases. The ⁴⁰Ar/³⁹Ar data thus reveal a protracted history of weathering and supergene Mn enrichment that started at least in the end of the Oligocene or beginning of Miocene and extending into the latest Pliocene. Staircase-apparent age spectra, resulting from banded or botryoidal samples, yield an average growth rate of Mn oxides at 0.6–0.7 × 10⁻³ mm kyr⁻¹. The values indicate that a 1-mm grain of Mn oxides may host minerals precipitated during a time span of ca. 1.5 m.y., and accumulation of Mn oxides to form economic deposits under weathering environments may take millions of years. The distribution of weathering ages shows that the oldest Mn oxides occur on the top of the profile, whereas the youngest minerals are found at the bottom, suggesting downward propagation of weathering fronts. However, two samples located at the intermediate depths of the profile yield ages comparable with those occurring at the highest elevations. Such a complexity of age distribution is interpreted in terms of preferential penetration of Mn-rich weathering solutions along more permeable fault zones, or as a result of multi stages of dissolution and re-precipitation of Mn oxides. A synthesis of geochronological and geological data suggests that formation of the Xinrong deposit was a consequence of a combination of favorable lithological, climatic, and structural conditions. Because the climatic and structural conditions are similar among the provinces of South China during the Cenozoic, the geochronological results obtained at Xinrong may also have implications for the timing of supergene Mn enrichment throughout South China.