海水中液-固界面的台阶型动力学曲线 Ⅱ.液膜扩散-递进扩散-界面分级交换反应联合控制的复合模型理论

为定量解释海水中液-固界面的台阶型动力学曲线及其台阶的消长变化规律,在我们已提出的“液膜扩散和递进液膜扩散控制的复合模型”和“海水中液-固界面分级离子/配位子交换理论”基础上,吸取Crank的若干数学处理方法,进而提出适合于非稳态体系的“液膜扩散-递进扩散-界面分级交换反应联合控制的复合模型”。     

有益菌与大型藻类净化集约化养殖废水的展望

随着我国集约化养殖的发展,其废水污染问题日益凸现。国外大多采用生物转盘,生物接触池,生物滤池,机械过滤装置等方法处理,但造价太高,不适合我国国情。微生态制剂和大型藻类以其独特的优势,在水产养殖废水处理方面具有很好的应用前景。本文阐述了光合细菌和芽孢杆菌作用机理,介绍了目前在处理养殖废水中江蓠等大型藻类的应用,并分别对有益菌之间,有益菌与江蓠之间的协同作用前景作了展望。     

Dynamic Response Behaviors of Upright Breakwaters Under Breaking Wave Impact

- The dynamic response behaviors of upright breakwaters under broken wave impact are analysed based on the mass-damper-spring dynamic system model. The effects of the mass, damping, stiffness, natural period, and impulse duration (or oscillation period) on the translation, rotation, sliding force, overturning moment, and corresponding dynamic amplifying factors are studied. It is concluded that the ampli-ying factors only depend on the ratio of the system natural period to impulse duration (or oscillation period) under a certain damping ratio. Moreover, the equivalent static approach to breakwater design is also discussed.     

目标采集技术在西部新区地震勘探中的应用

目标采集技术是根据复杂的地下地质构造提出来的,它是针对诸如小断层、小断块、复杂断裂带、特殊岩性、泥岩裂缝等主要地质构造目标而进行的有针对性的目标观测系统设计及目标采集施工方法设计的技术。针对目标采集的特点,在观测系统设计中提出了以地质模型正演模拟分析为核心的观测系统设计技术;在老资料分析和采集参数论证中提出了细化、量化分析技术。通过目标采集技术在西部探区的应用,有效的解决了西部新区勘探开发中广泛存在的复杂隐蔽油气藏勘探难题。     

细基江蓠脂肪酸组成研究

研究表明,南海细基江蓠Gracilaria tenuistipitata中主要含有C_9—C_(30)一元饱和脂肪酸,其中n-十六酸含量占脂肪酸组分的40％以上。单烯和二烯酸的含量较低,缺乏多烯酸及前列腺素类化合物。此外,还含有少量二元酸类、4-及5-羰基羧酸,其中后两者是首次在红藻中发现。南海细基江蓠的脂肪酸组成特征与南海海域水质较清、光照充足及水温较高等环境因素有关。     

耗散源函数及LAGFD-WAM海浪数值模式的改进

本文是在LAGFD-WAM海浪模式方法基础上,根据破碎波统计理论给出了LAGFD耗散源函数形式。同时对LAGFD-WAM模式进行了改进并与WAM模式作了三种典型风场下的对比实验和实测结果检验,取得了较好的结果。     

广西崇左三合巨猿大洞早更新世小哺乳动物群

最近在广西崇左三合大洞发现了步氏巨猿和似人似猿共生的新层位,与之伴生的有52种小哺乳动物,占三合大洞巨猿动物群总数的62%,其中苏门答腊兔（Nesolagus）是东南亚地区首次发现的化石。小哺乳动物群以南方早更新世常见的偏皮氏毛耳飞鼠（Belomys parapearsoni）、中间猪尾鼠（Typhlomys intermedius）、拟低冠竹鼠（Rhizomys brachyrhizomyoides）、硕豪猪（Hystrix magna）、先社鼠（Niviventer preconfucianus）、拟爱氏巨鼠（Leopoldamysedwardioidesi）等为代表,根据小哺乳动物群性质和与其他动物群对比以及磁性地层年代测定,表明其时代应是早更新世中期（约距今120¹60万年前）。该动物群由树鼩、扁颅蝠、小彩蝠、飞松鼠、笔尾树鼠、猪尾鼠等几乎是旧大陆热带-亚热带森林型动物组成,缺少北方类型,基本上属于热带森林动物群,这表明了当时的自然景观为温暖湿润的热带雨林环境。三合大洞小哺乳动物群是广西地区的首次发现,对华南早更新世巨猿动物群详细划分,探讨步氏巨猿演化和早期人类环境背景等目前科学界关注的问题具有重要的意义。     

高温高压岩石流变仪的围压标定方法

高温高压岩石流变仪围压标定的主要方法为氯化盐类的部分熔融法和矿物相变法。利用氯化盐类进行压力标定时,不仅可以利用单一盐类,也可以使用多种盐类的混合物;常用的压力标定矿物相变及其适用温压范围如下:石英-柯石英,500~1200℃、2.5~3.2GPa;钠长石-硬玉+石英,600~1200℃、1.6~3.2GPa;铁橄榄石+石英-铁辉石,600~1200℃、1~1.7GPa;磷镁石-Mg3(PO4)2-Ⅱ,565~825℃、0.6~0.9GPa;方解石-文石,600~1200℃、0.5~2.5GPa。不同的标定方法具有不同的特征,文中将进行详细介绍。     

ADS40地面数据处理的数据流分析

线阵CCD推扫式数字航测相机ADS40系统的引进为我国数字航空摄影测量提供了新型的数据源。对ADS40数据特点进行分析,在对数据处理软件功能测试的基础上形成了地面数据处理的数据流图,并成功用于指导相应实验测区的测绘任务。完备、正确的数据流图为ADS40作业流程的制订提供了基础和依据。     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.