顺序扫描 ICP-AES法测定高纯石墨灰分中14种杂质金属元素的方法研究

本文研究了快速测定石墨灰分中14种杂质元素Al,Ca,Cd,Co,Cr,Cu,Fe,Mg,Mn,Mo,Ni,Ti,V,Zn的分析方法,以满足提纯石墨研究工作对快速了解石墨提纯效果的要求.依据测定样品中各元素的含量情况,实验选择14种元素的分析线.运用ICP-AES谱线轮廓图功能,消除常量元素产生的基体背景干扰.运用干扰系数法进行测定结果校正,并对ICP-AES测定灰分中14种元素的检出线、精密度、准确度进行了测定.结果显示,本方法分析石墨灰分中杂质元素能够满足提纯石墨研究工作的要求.     

Further evaluation of the Sim-ReSET model for ET estimation driven by only satellite inputs

Abstract

A simple remote sensing evapotranspiration (ET) model (Sim-ReSET) has been proposed but only tested using field measurements at a site with a semi-arid climate. Its performance for mapping ET using only satellite data remained unknown. In this study, the Sim-ReSET model was further evaluated for ET estimation driven by only MODIS data products. The estimated ET rates were compared with ground-based observational data from a variety of ecosystems and climates across China. The results show that MODIS-based ET estimates are consistent with both the ET measurements from eddy covariance flux towers and those from the Penman-Monteith method combined with micrometeorological data. Evaporation fraction (EF) is indicative of land surface moisture. The derivative EF maps demonstrate that the proposed ET data set obtained from the Sim-ReSET model and MODIS data is capable of capturing the spatio-temporal pattern of land surface moisture for different land covers with different climates.

Editor Z.W. Kundzewicz

Citation Sun, Z.G., Wang, Q.X., Matsushita, B., Fukushima, T., Ouyang, Z., Watanabe, M., and Gebremichael, M., 2013. Further evaluation of the Sim-ReSET model for ET estimation driven by only satellite inputs. Hydrological Sciences Journal, 58 (5), 994–1012.     

湖南省县域乡村反贫困绩效评价与空间分异特征

综合运用熵值法、地理探测器等方法,从基本生存绩效、自身发展绩效,县域扶贫绩效3个方面构建指标体系,对湖南省51个贫困县2017年反贫困绩效空间地域分异特征及其影响因素进行研究。结果表明：① 湖南省贫困农户一般能满足基本的生存需要;自身发展绩效水平得分较高的区域大多处于武陵源区、鹤城区等城市市区周围以及罗霄山片区,而雪峰山脉周围县市则普遍较低;县域扶贫绩效水平高的区域分布较为零散,大致位于各城区周围,而省城或西北的少数民族聚集区以及中南部绩效水平还有待提高。② 反贫困绩效总体上呈现出高、中、低3种绩效水平交替分布的空间特征,愈靠近武陵源区、鹤城区和长株潭地区的贫困县市,综合反贫困绩效水平愈高。③ 县域发展情况是影响湖南省反贫困绩效的决定性因素,农户条件与乡村状况是基础性因素,自然条件是重要因素,各因子间交互作用的影响远大于单因子,不存在独立作用的因素,体现出湖南省反贫困绩效影响因素的复杂性特征。     

广州市表层土壤磁学性质的空间插值方法比较

本文利用广州市范围内的350个表层土壤样品χ_lf、χ_ARM/SIRM、HIRM等14个磁学参数的测试结果，在对各磁学参数分别进行统计特征分析和正态性检验的基础上，对满足正态或近似正态分布的磁学参数进行趋势分析。利用确定性插值法（包括反距离权重法和径向基函数法）和地统计法（包括普通克里金法和泛克里金法）对14个磁学参数进行空间插值并根据交叉验证法（比较不同插值方法的交叉验证参数）的结果，比较地统计法和确定性插值法的预测误差，从而确定14个磁学参数的最优插值方法。结果表明：1）地统计法中，χ_ARM、χ_lf、χ_hf、S₁₀₀、S₃₀₀、S_-100、SIRM和HIRM的普通克里金法插值效果最好；SIRM/χ的泛克里金法插值效果最好；χ_ARM/SIRM和S_-300的普通克里金法（OK）和泛克里金法（UK）的插值效果接近。OK法作为最常用的地统计空间插值方法，在表土磁学参数上也相较于UK适用范围更广。2）确定性插值法中，χ_ARM、χ_lf、χ_hf、χ_fd（%）、χ_ARM/χ、χ_ARM/SIRM、HIRM的径向基函数法插值效果最优；S₁₀₀、S_-100、S_-300和SIRM的反距离权重法插值效果最优；反距离权重法和径向基函数法均可作为χ_fd、SIRM/χ、S₃₀₀的插值方法。3）综合比较地统计法和确定性插值法，发现χ_ARM、χ_lf、χ_hf、χ_fd、χ_fd（%）、χ_ARM/χ、χ_ARM/SIRM、S₃₀₀、HIRM的空间插值应采用径向基函数法；S₁₀₀、S_-100和S_-300的空间插值应选择反距离权重法；而SIRM/χ和SIRM空间插值建议分别采用泛克里金法和普通克里金法。     

从地理1到选择性必修1:联系基础上的进阶

地理1和选择性必修1课程内容要求之间的关系为联系基础上的进阶。整体联系体现在太阳辐射和地球自身特点共同作用下的自然带地域分异规律形成过程,是必修地理1和选择性必修1隐含的学科逻辑线索。这条内容线索也是理解“必修”二字的关键。在“必修”的基础上看“选择性”,地理1和选择性必修1内容要求之间的进阶,体现在内容构成上,从现象到规律、从单一要素到要素综合;在学习水平上,从“识记”、“领会”,提升到“领会”、“分析”水平。地理1和选择性必修1内容要求之间的联系与进阶,要求教师树立教学设计的整体意识,包括课程内容的结构化分析和教学目标的分层设计,从而在整体把握学科知识体系的基础上,有一条清晰的逐级递进、螺旋上升体现学习进阶过程的教学“路线图”。     

Negative differential resistance behaviour in N-doped crossed graphene nanoribbons

By using first-principles calculations and nonequilibrium Green's function technique, we study elastic transport properties of crossed graphene nanoribbons. The results show that the electronic transport properties of molecular junctions can be modulated by doped atoms. Negative differential resistance (NDR) behaviour can be observed in a certain bias region, when crossed graphene nanoribbons are doped with nitrogen atoms at the shoulder, but it cannot be observed for pristine crossed graphene nanoribbons at low biases. A mechanism for the negative differential resistance behaviour is suggested.     

田阳三化螟蛾盛发高峰初日气象预警模型

三化螟为水稻主要害虫之一,单食水稻,在田阳一年发生完全4个世代,开展各世代螟蛾盛发高峰期气象预警,对科学适时防螟灭虫,虫口夺粮意义重大。利用农业植保部门提供的三化螟蛾盛发高峰期虫情资料和气象部门气象观测同期资料,采用逐步回归方法,建立三化螟蛾盛发高峰初日气象预警模型。结果表明:各世代预警模型输出的盛发高峰初日与实况误差3天的拟合正确率为82.2%～92.9%。试报2015—2016年,第1世代预报与实况误差为3天,第2代至第4世代误差为1～2天。三化螟蛾盛发高峰初日气象预警模型的拟合正确率、试报结果误差范围比较理想,可投入日常业务应用。     

芒果嫁接成活气象条件及生产管理措施

利用芒果嫁接成活率多年分期物候观测以及同期的气象观测实况资料进行统计分析。结果表明,芒果嫁接成活率与嫁接后的接口愈合期气温成显著正相关,与光照、降水量、空气相对湿度相关不明显。建立了芒果嫁接成活率与嫁接后6天平均气温、最高气温回归方程,影响芒果嫁接成活的主要气象要素是日均温。个例分析表明芒果嫁接成活关键期即嫁接穗生理脆弱的接口愈合期,气温偏低或异常高温天气对芒果嫁接成活不利影响极大。讨论了依气象条件提高嫁接成活率注意事项,提出了相应的生产管理措施。     

Recent climate trends on the northern slopes of the Tianshan Mountains, Xinjiang, China

In arid regions, mountains fulfill important ecological and economic functions for the surrounding lowlands. In the scenario of global warming, mountain ecosystems change rapidly, especially in the arid region of northwestern China. This paper provides an assessment of the changes in temperature and precipitation in the historical records of climate on the northern slopes of the eastern Tianshan Mountains. A Mann-Kendall nonparametric trend and Sen＇s tests are employed to analyze the interannual changes and innerannual variability in temperature and precipitatiofi in the regions of low to high altitude. The present study finds that the largest increases in annual temperature are observed at stations in the low altitude regions. The significant increasing trends in temperature tend to occur mainly in late winter and early spring at stations from middle to high altitude, but in summer and autumn at stations of low altitudes. The increasing trends in annual precipitation are found from the middle to high altitude areas, but decreasing trends are found in the low altitude areas. The significant increasing trends in precipitation occur mostly in winter and earlier spring at stations from the middle to high altitudes, while the increasing and decreasing trend coexists at stations of low altitude with most of the significant trend changes occurring in March, June and August.     

Talc-beating serpentinized peridotites from the southern Mariana forearc： implications for aseismic character within subduction zones

The serpentinized peridotites overlying the subducted zones in the Izu-Bonin-Mariana (IBM) arc system have been interpret as the cause of the low-velocity layer identified beneath the IBM froearc, in turn few earthquakes occurred along the plate boundary. Chrysotile, which is a low temperature and highly hydrated phase of serpentine with low frictional strength, has been suggested as the low velocity material in the serpentinized peridotites, besides, brucite is inferred to be likely conducive to stable sliding. However, such idea encounters challenging in our serpentinized peridotites from the southern Mariana forearc, which absent both the above minerals. The presence of talc, which characterized by its weak, low-friction and inherently stable sliding behavior, provides new clue. Here we report the occurrence of talc in serpentinized peridotites collected from the landward trench slope of the southern Mariana forearc. We infer that talc is mainly forming as a result of the reaction of serpentine minerals with silica-saturated fluids released from the subducting slab, and talc also occurs as talc veins sometimes. Due to its unique physical properties, talc may therefore play a significant role in aseismic slip in the IBM subduction zone.