The Cretaceous-Tertiary fireball layer,ejecta layer and coal seam: Platinum-group element content and mineralogy of size fractions

Abstract— Grain size separates of the Cretaceous-Tertiary (K-T) fireball layer at marine sites and the entire K-T boundary interval at nonmarine sites (fireball layer, ejecta layer, coal seam) were analysed for platinum-group elements (PGE: Ru, Ir, Ft, Pd, Rh) and Au using inductively coupled plasma mass-spectrometry. X-ray diffractometry and scanning electron microscopy were performed on each fraction to establish the mineralogy. It was determined that the most abundant minerals in the finest fraction were a smectite-group mineral at marine K-T sites and illite-smectite mixed layer clay at nonmarine K-T sites. Positive correlation of PGE content and mineralogy indicates that the PGE are presently associated with these clay minerals which were likely formed by alteration of a condensed mafic phase (e.g., olivine or pyroxene). The correlation of clay mineral abundance with PGE content is imperfect because not all of the clay minerals in the fireball layer are derived by alteration of the original condensed ejecta. In addition, undetected PGE host(s), present in trace amounts, are likely also present.     

An Overview of Surface-Based Precipitation Observations at Environment and Climate Change Canada

The objective of this paper is to provide an overview of the present status and procedures related to surface precipitation observations at Environment and Climate Change Canada (ECCC). This work was done to support the ongoing renewal of observation systems and networks at the Meteorological Service of Canada. The paper focusses on selected parameters, namely, accumulated precipitation, precipitation intensity, precipitation type, rainfall, snowfall, and radar reflectivity. Application-specific user needs and requirements are defined and captured by World Meteorological Organization (WMO) Expert Teams at the international level by Observing Systems Capability Analysis and Review (OSCAR) and WMO Integrated Global Observing System (WIGOS), and by ECCC user engagement initiatives within the Canadian context. The precipitation-related networks of ECCC are separated into those containing automatic instruments, those with human (manual) observers, and the radar network. The unique characteristics and data flow for each of these networks, the instrument and installation characteristics, processing steps, and limitations from observation to data distribution and storage are provided. A summary of precipitation instrument-dependent algorithms that are used in ECCC's Data Management System is provided. One outcome of the analysis is the identification of gaps in spatial coverage and data quality that are required to meet user needs. Increased availability of data, including from long-serving manual sites, and an increase in the availability of precipitation type and snowfall amount are identified as improvements that would benefit many users. Other recognized improvements for in situ networks include standardized network procedures, instrument performance adjustments, and improved and sustained access to data and metadata from internal and external networks. Specific to radar, a number of items are recognized that can improve quantitative precipitation estimates. Increased coverage for the radar network and improved methods for assessing and portraying radar data quality would benefit precipitation users.     

Seawater-like trace element signatures (REE + Y) of Eoarchaean chemical sedimentary rocks from southern West Greenland,and their corruption during high-grade metamorphism

Modern chemical sediments display a distinctive rare earth element + yttrium (REE + Y) pattern involving depleted LREE, positive La/La*_SN, Eu/Eu*_SN, and Y_SN anomalies (SN = shale normalised) that is related to precipitation from circumneutral to high pH waters with solution complexation of the REEs dominated by carbonate ions. This is often interpreted as reflecting precipitation from surface waters (usually marine). The oldest broadly accepted chemical sediments are c. 3,700 Ma amphibolite facies banded iron-formation (BIF) units in the Isua supracrustal belt, Greenland. Isua BIFs, including the BIF international reference material IF-G are generally considered to be seawater precipitates, and display these REE + Y patterns (Bolhar et al. in Earth Planet Sci Lett 222:43–60, 2004). Greenland Eoarchaean BIF metamorphosed up to granulite facies from several localities in the vicinity of Akilia (island), display REE + Y patterns identical to Isua BIF, consistent with an origin by chemical sedimentation from seawater and a paucity of clastic input. Furthermore, the much-debated magnetite-bearing siliceous unit of “earliest life” rocks (sample G91/26) from Akilia has the same REE + Y pattern. This suggests that sample G91/26 is also a chemical sediment, contrary to previous assertions (Bolhar et al. in Earth Planet Sci Lett 222:43–60, 2004), and including suggestions that the Akilia unit containing G91/26 consists entirely of silica-penetrated, metasomatised, mafic rock (Fedo and Whitehouse 2002a). Integration of our trace element data with those of Bolhar et al. (Earth Planet Sci Lett 222:43–60, 2004) demonstrates that Eoarchaean siliceous rocks in Greenland, with ages from 3.6 to 3.85 Ga, have diverse trace element signatures. There are now geographically-dispersed, widespread examples with Isua BIF-like REE + Y signatures, that are interpreted as chemically unaltered, albeit metamorphosed, chemical sediments. Other samples retain remnants of LREE depletion but are beginning to lose the distinct La, Eu and Y positive anomalies and are interpreted as metasomatised chemical sediments. Finally there are some siliceous samples with completely different trace element patterns that are interpreted as rocks of non-sedimentary origin, and include metasomatised mafic rocks. The positive La/La*_SN, Eu/Eu*_SN and Y_SN anomalies found in Isua BIFs and other Eoarchaean Greenland samples, such as G91/26 from Akilia, suggests that the processes of carbonate ion complexation controlling the REE − Y patterns were already established in the hydrosphere at the start of the sedimentary record 3,600–3,850 Ma ago. This is in accord with the presence of Eoarchaean siderite-bearing marbles of sedimentary origin, and suggests that CO₂ may have been a significant greenhouse gas at that time.     

Atmospheric Corrections Using MODTRAN for TOA and Surface BRDF Characteristics from High Resolution Spectroradiometric/ Angular Measurements from a Helicopter Platform

l. IntroductionThe cIassicaI definition of bi--directional reflectance--distribution function (BRDF) is aderivative, distribution function, relatlng the irradiance incident from one given direction tolts contribution to the radiance renected in another direct1on (N1codemus et al., l977).f r (0,, rp,; 0,, rp, )= dL, (0,, P,; 0,, 9,; E, )/ dE, (0,, 9,) [sr-- 1 ], (l)where 0 (zenith angle) and 9 (azimuth angle) together indicate a direction, the subscr1pt i indi-cates quantities associated wi…     

Estimating Population Attribute Values in a Table: “Get Me Started in” Iterative Proportional Fitting

Iterative proportional fitting (IPF) is a technique that can be used to adjust a distribution reported in one data set by totals reported in others. IPF is used to revise tables of data where the information is incomplete, inaccurate, outdated, or a sample. Although widely applied, the IPF methodology is rarely presented in a way that is accessible to nonexpert users. This article fills that gap through discussion of how to operationalize the method and argues that IPF is an accessible and transparent tool that can be applied to a range of data situations in population geography and demography. It offers three case study examples where IPF has been applied to geographical data problems; the data and algorithms are made available to users as supplementary material.     

Immune inhibition in marine mussels by polycyclic aromatic hydrocarbons

Polycyclic aromatic pollutants produced by a range of industrial processes and the combustion of fossil fuels. They eventually enter the marine environment, and are bioaccumulated in the tissues of sessile, filter-feeding bivalves, causing a variety of sublethal effects. Few studies, however, have examined immune inhibition in molluscs by these xenobiotics. Here, the immunotoxic effects of PAHs were investigated in marine mussels (Mytilus edulis) by means of in vivo exposure experiments. Animals were exposed to a PAH cocktail of anthracene, fluoranthene and phenanthrene for 2 or 4 weeks. The haemolymph was then extracted, and phagocytosis and lysosomal neutral red retention assays performed to examine the effects of PAHs on particle uptake by haemocytes and lysosome integrity, respectively. PAHs were found to inhibit phagocytosis and damage lysosomes. It is hypothesized that PAHs exert their toxicity directly on the lysosomes. A possible consequence of such lysosomal damage will be immune impairment in mussels leading to reduced resistance to infectious diseases.     

Tropical forests: Present status and future outlook

Tropical forests still cover almost 8 million km² of the humid tropics. But they are being destroyed at ever-more rapid rates. In 1989 the area deforested amounted to 142 200 km², or nearly 90% more than in 1979. So whereas the 1989 total amounted to 1.8% of the remaining biome, the proportion could well continue to rise for the foreseeable future, until there is little forest left in just another few decades.Deforestation patterns are far from even throughout the biome. In much if not most of Southeast and Southern Asia, East and West Africa, and Central America, there is likely to be little forest left by the year 2000 or shortly thereafter. But in the Zaire basin, western Brazilian Amazonia and the Guyana highlands, sizeable expanses of forest could persist a good while longer.The main agent of deforestation is the shifted cultivator or displaced peasant, who, responding to land hunger and general lack of rural development in traditional farming areas of countries concerned, feels there is no alternative but to adopt a slash-and-burn lifestyle in forestlands. This person is now accounting for at least 60% of deforestation, a proportion that is expanding rapidly. Yet he receives far less policy attention than the commercial logger, the cattle rancher and other agents of deforestation.This is a summary review of a report Deforestation Rates in Tropical Forests and Their Climatic Implications, prepared by the author and Richard A. Houghton for Friends of the Earth U.K. (available from 26–28 Underwood St., London N1 7JQ). A similar review, albeit with less updating than is included here, has been published by Myers, 1990a. The original report, being five times longer than the present paper, contains much detail of deforestation assessments on a country-by-country basis, backed by 400 references. It also presents information on research methodologies and reliability of data among other background materials, plus an analysis of carbon emissions from deforestation, as well as some policy appraisal and conservation recommendations.