Effect of the chemical composition of the crust on the metamorphic evolution of orogenic wedges

Petrological data provide a good record of the thermal structure of deeply eroded orogens, and, in principle, might be used to relate the metamorphic structure of an orogen to its deformational history. In this paper, we present two‐dimensional thermal modelling of various subduction models taking into account varying wedge geometry as well as variation of density and topography with metamorphic reactions. The models clearly show that rock type accreted in the wedge has important effects on the thermal regime of orogenic wedges. The thermal regime is dominated by radiogenic heat production. Material having high radioactive heat production, like the granodioritic upper crust, produces high temperature metamorphism (amphibolitic conditions). Material with low radioactive heat production results in low temperature metamorphism of greenschist or blueschist types depending on the thickness of the wedge. Application of this model to seemingly unrelated areas of the Central Alps (Lepontine Dome, Grisons) and Eastern Alps (Tauern Window) explains the coexistence and succession of distinct Barrovian and blueschist facies metamorphic conditions as the result of a single, continuous tectonic process in which the main difference is the composition of the incoming material in the orogenic wedge. Accretion of the European upper continental crust in the Lepontine and Tauern Domes produces Barrovian type metamorphism while accretion of oceanic sediments results in blueschist facies metamorphism in the Valaisan domain.     

Palaeomagnetic results from the ca. 1130 Ma Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, Antarctica, and tectonic implications

Detailed palaeomagnetic and rock magnetic analyses provide improved palaeomagnetic results from 23 sites in the Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, East Antarctica. These intrusions are of similar age to their host, the ca. 1130 Ma Ritscherflya Supergroup (RSG). A mean direction of D=235.4°, I=−7.6° with k=45.9 and α₉₅=4.5° was obtained from this study. When combined with previously reported results from 11 sites in the same region, including sites from the Ritscherflya Supergroup, it gives an overall mean direction for 34 sites from the igneous suite with D=236.5°, I=−3.6°, k=27.9 and α₉₅=4.8°. Isothermal remanent magnetization (IRM) experiments on several specimens suggest magnetite or titanomagnetite as the primary remanence carrier, while high temperature magnetic susceptibility experiments indicate the presence of single domain particles. These observations, together with field evidence and the high coercivities and unblocking temperatures, support a primary origin for the observed characteristic remanence. The Borgmassivet palaeomagnetic pole lies at 54.5°E, 8.3°N with A₉₅=3.3°. If Antarctica is moved to its Gondwanan position adjacent to southeast Africa, the Borgmassivet pole (BM) coincides with that of the African well-established, well-dated (1100 Ma) Umkondo Large Igneous Province pole, supporting the hypothesis that the Grunehogna craton of Dronning Maud Land was part of the Kalahari craton of southern Africa at ca. 1100 Ma.     

Neoproterozoic accretionary and collisional events on the western margin of the Siberian craton: new geological and geochronological evidence from the Yenisey Ridge

The geological, structural and tectonic evolutions of the Yenisey Ridge fold-and-thrust belt are discussed in the context of the western margin of the Siberian craton during the Neoproterozoic. Previous work in the Yenisey Ridge had led to the interpretation that the fold belt is composed of high-grade metamorphic and igneous rocks comprising an Archean and Paleoproterozoic basement with an unconformably overlying Mesoproterozoic–Neoproterozoic cover, which was mainly metamorphosed under greenschist-facies conditions. Based on the existing data and new geological and zircon U–Pb data, we recognize several terranes of different age and composition that were assembled during Neoproterozoic collisional–accretional processes on the western margin of the Siberian craton. We suggest that there were three main Neoproterozoic tectonic events involved in the formation of the Yenisey Ridge fold-and-thrust belt at 880–860 Ma, 760–720 Ma and 700–630 Ma. On the basis of new geochronological and petrological data, we propose that the Yeruda and Teya granites (880–860 Ma) were formed as a result of the first event, which could have occurred in the Central Angara terrane before it collided with Siberia. We also propose that the Cherimba, Ayakhta, Garevka and Glushikha granites (760–720 Ma) were formed as a result of this collision. The third event (700–630 Ma) is fixed by the age of island-arc and ophiolite complexes and their obduction onto the Siberian craton margin. We conclude by discussing correlation of these complexes with those in other belts on the margin of the Siberian craton.     

Neoarchaean magmatism and metamorphism of the western granulites in the central domain of the Mozambique belt, Tanzania: U–Pb shrimp geochronology and PT estimates

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.     

Quantitative charge state analysis of manganese biominerals in aqueous suspension using scanning transmission X-ray microscopy (STXM)

We have applied Scanning Transmission Soft X-ray Microscopy (STXM) to investigate the charge state distribution of Mn in two kinds of Mn-biominerals, Mn nodules collected from Lake Michigan sediments and Mn precipitates formed by spores of a marine bacillus SG-1 under transport limited reaction conditions. A data analysis technique was developed, which allows for extraction of spatially resolved 2-d charge state maps of manganese on a submicron level. We find that the charge state of Mn dominates the spectral shape of L-edge spectra of environmentally important single oxidation state Mn minerals and that spectra of mixed oxidation state oxides can be modelled by a combination of appropriate single oxidation state reference spectra. Two-dimensional maps of charge state distributions clearly reveal domains of different oxidation states within single particles of Mn-micronodules. Spots of preferred accumulation of Mn(II) were found, which indicates biogenic precipitation of Mn(II)-species as a first step of nodule formation. The presence of Mn(III) in the studied sediment samples suggests the involvement of one-electron oxidation processes and reaction conditions which inhibit or slow down the disproportionation of Mn(III)-products. Under transport limited conditions, Mn oxidation products formed by spores of the marine bacillus SG-1 can vary from cell to cell. The presence of significant amounts of Mn(III) containing species points to the involvement of one-electron oxidation reactions as in the case of the micro-nodules. Our technique and the results obtained form a new basis for the mechanistic understanding of the formation of Mn biominerals in the environment.     

Fluxes of Sr into the headwaters of the Ganges

Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, ⁸⁷Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated ⁸⁷Sr/⁸⁶Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the ⁸⁷Sr flux in excess of the seawater ⁸⁷Sr/⁸⁶Sr ratio of 0.709.     

Late Pleistocene and early Holocene rivers and wetlands in the Bonneville basin of western North America

Field investigations at Dugway Proving Ground in western Utah have produced new data on the chronology and human occupation of late Pleistocene and early Holocene lakes, rivers, and wetlands in the Lake Bonneville basin. We have classified paleo-river channels of these ages as “gravel channels” and “sand channels.” Gravel channels are straight to curved, digitate, and have abrupt bulbous ends. They are composed of fine gravel and coarse sand, and are topographically inverted (i.e., they stand higher than the surrounding mudflats). Sand channels are younger and sand filled, with well-developed meander-scroll morphology that is truncated by deflated mudflat surfaces. Gravel channels were formed by a river that originated as overflow from the Sevier basin along the Old River Bed during the late regressive phases of Lake Bonneville (after 12,500 and prior to 11,000 ¹⁴C yr B.P.). Dated samples from sand channels and associated fluvial overbank and wetland deposits range in age from 11,000 to 8800 ¹⁴C yr B.P., and are probably related to continued Sevier-basin overflow and to groundwater discharge. Paleoarchaic foragers occupied numerous sites on gravel-channel landforms and adjacent to sand channels in the extensive early Holocene wetland habitats. Reworking of tools and limited toolstone diversity is consistent with theoretical models suggesting Paleoarchaic foragers in the Old River Bed delta were less mobile than elsewhere in the Great Basin.